Borane

Borane,also known as boron hydride, is the ageneraldesignation for a series of compounds formed by two elements of boron and hydrogen. Simple boranes are colorless, unpleasantly odorous and toxic. They are usually very unstable and spontaneous to generate boron oxide in air. With the increase of the number of boron atoms, boranes can be gaseous (e.g., diborane), liquid (e.g. pentaborane) and solid (e.g. decaborane). There have been more than 20 kinds of boranes ever prepared by human so far, which can be divided into two categories. The general formula of one of them is BnHR+4 (n≥2), such as diborane (B2H6), pentaborane-9 (B5H9) and sixteen borane (B16H20); the other is BnHR+6 (n≥3), such as triborane(B3H9), pentaborane-11 (B5H11), nonaborane (B9H15) and so on. Borane all have unpleasant odor. Simple borane (of relatively less boron atoms) is so chemically active that is spontaneous in air and easy for hydrolysis, halogenation and amination. Diborane is of the largest and most important usage. It is prepared from boron trifluoride with lithium hydride in ether in industry.

Other boranes can be prepared from the thermal decomposition of diborane at different temperatures.

Borane release a lot of heat when burned, therefore it can be used as high-energy fuel for rockets and missiles. It can also be used as the treatment agent of a metal or ceramic parts and rubber crosslinking agent. One of the important applications of diborane is reduction agent in the hydroboration reaction.

Borane is highly toxic, inhalation of diborane can cause lung damage, inhalation of decaborane can cause a heart recession, large boranes are toxic to the central nervous system and damaging to the liver and kidneys. Careful attention must be paid when using borane.

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Structure Chemical Name CAS MF
1-Methyl-4-pyrazole boronic acid pinacol ester 1-Methyl-4-pyrazole boronic acid pinacol ester 761446-44-0 C10H17BN2O2
(R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole (R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole 112022-83-0 C18H20BNO
TRIS(PENTAFLUOROPHENYL)BORANE TRIS(PENTAFLUOROPHENYL)BORANE 1109-15-5 C18BF15
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole 112022-81-8 C18H20BNO
2-CHLORO-5-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PYRIDINE 2-CHLORO-5-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PYRIDINE 444120-94-9 C11H15BClNO2
Borane-methyl sulfide complex Borane-methyl sulfide complex 13292-87-0 C2H10BS
(+)-Diisopinocampheyl chloroborane (+)-Diisopinocampheyl chloroborane 112246-73-8 C20H34BCl
o-Carborane o-Carborane 16872-09-6 C2B10
Borane-tetrahydrofuran complex Borane-tetrahydrofuran complex 14044-65-6 C4H11BO
BENZYLBORONIC ACID PINACOL ESTER BENZYLBORONIC ACID PINACOL ESTER 87100-28-5 C13H19BO2
4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)TOLUENE 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)TOLUENE 195062-57-8 C13H19BO2
3-(ISOPROPOXYCARBONYL)PHENYLBORONIC ACID 3-(ISOPROPOXYCARBONYL)PHENYLBORONIC ACID 342002-80-6 C10H13BO4
Diborane Diborane 19287-45-7 B2H6
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)toluene 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)toluene 253342-48-2 C13H19BO2
Borane tert-butylamine complex Borane tert-butylamine complex 7337-45-3 C4H11BN
Methoxydiethylborane Methoxydiethylborane 7397-46-8 C5H13BO
4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)FLUOROBENZENE 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)FLUOROBENZENE 214360-58-4 C12H16BFO2
2-BUTYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE 2-BUTYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE 69190-62-1 C10H21BO2
2-(2-IODOPHENYL)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE 2-(2-IODOPHENYL)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE 857934-82-8 C12H16BIO2
1,2-BIS(TERT-BUTYLTHIO)ETHANE:DIBORANE COMPLEX 1,2-BIS(TERT-BUTYLTHIO)ETHANE:DIBORANE COMPLEX 71522-78-6 C10H26B2S2
B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE 73624-47-2 C18H31B
M-CARBORANE M-CARBORANE 16986-24-6 C2H12B10
DECABORANE DECABORANE 17702-41-9 B10H14
Borane-pyridine complex Borane-pyridine complex 110-51-0 C5H8BN
4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)CHLOROBENZENE 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)CHLOROBENZENE 195062-61-4 C12H16BClO2
TRIBUTYLBORANE TRIBUTYLBORANE 122-56-5 C12H27B
(-)-Diisopinocampheyl borane (-)-Diisopinocampheyl borane 21932-54-7 C20H35B
SODIUM COBALTICARBORANE SODIUM COBALTICARBORANE 99492-72-5 C4B18CoNa
Boron trifluoride-butyl ether complex Boron trifluoride-butyl ether complex 593-04-4 C8H18BF3O
Borane ammonia complex Borane ammonia complex 13774-81-7 BH6N
5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)thiazole 5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)thiazole 1086111-09-2 C9H14BNO2S
B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE 42371-63-1 C18H31B
1-(TERT-BUTYL) 5-METHYL 3-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-1H-INDOLE-1,5-DICARBOXYLATE 1-(TERT-BUTYL) 5-METHYL 3-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-1H-INDOLE-1,5-DICARBOXYLATE 2304634-20-4 C21H28BNO6
4-(1,3,2-DIOXABORINAN-2-YL)BENZALDEHYDE 4-(1,3,2-DIOXABORINAN-2-YL)BENZALDEHYDE 160068-88-2 C10H11BO3
2-(4-CARBOXYPHENYL)-1,3,2-DIOXABORINANE 2-(4-CARBOXYPHENYL)-1,3,2-DIOXABORINANE 126747-13-5 C10H11BO4
4,4,6-TRIMETHYL-2-VINYL-1,3,2-DIOXABORINANE 4,4,6-TRIMETHYL-2-VINYL-1,3,2-DIOXABORINANE 4627-10-5 C8H15BO2
9-BBN DIMER 9-BBN DIMER 21205-91-4 C16H30B2
TRIPHENYLBORANE TRIPHENYLBORANE 960-71-4 C18H15B
Borane morpholine complex Borane morpholine complex 4856-95-5 C4H12BNO
Diisopinocampheylborane Diisopinocampheylborane 21947-87-5 C20H35B
2-ALLENYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE 2-ALLENYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE 865350-17-0 C9H15BO2
DICHLOROMETHYLDIISOPROPOXYBORANE DICHLOROMETHYLDIISOPROPOXYBORANE 62260-99-5 C7H15BCl2O2
1,2-Diphenyl-1,2-dicarba-closo-dodecaborane 1,2-Diphenyl-1,2-dicarba-closo-dodecaborane 17805-19-5 C14H10B10
(S,S)-1,2-BIS[(TERT-BUTYL)METHYLPHOSPHINO]ETHANE BIS(BORANE) (S,S)-1,2-BIS[(TERT-BUTYL)METHYLPHOSPHINO]ETHANE BIS(BORANE) 203000-48-0 C12H30B2P2
TETRAKIS(DIMETHYLAMINO)DIBORON TETRAKIS(DIMETHYLAMINO)DIBORON 1630-79-1 C8H24B2N4
4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde 4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde 128376-65-8 C12H15BO3
(+)-PINANEBORANE (+)-PINANEBORANE 90084-43-8 C10H17BO2
2-(4-BROMOBUTYL)-1 3 2-BENZODIOXABOROLE& 2-(4-BROMOBUTYL)-1 3 2-BENZODIOXABOROLE& 142172-51-8 C10H12BBrO2
(R)-2-METHYL-CBS-OXAZABOROLIDINE (R)-2-METHYL-CBS-OXAZABOROLIDINE 133261-83-3 C18H20BNO
PHENYLBORON DICHLORIDE PHENYLBORON DICHLORIDE 873-51-8 C6H5BCl2
1-BROMO-2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE 1-BROMO-2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE 269410-06-2 C12H16BBrO2
DICYCLOHEXYL(TRIFLUOROMETHANESULFONYLOXY)BORANE DICYCLOHEXYL(TRIFLUOROMETHANESULFONYLOXY)BORANE 145412-54-0 C13H22BF3O3S
2-CHLORO-1,3,2-BENZODIOXABOROLE 2-CHLORO-1,3,2-BENZODIOXABOROLE 55718-76-8 C6H4BClO2
2,2-Difluoro-benzo[1,3]dioxole-5-boronic acid 2,2-Difluoro-benzo[1,3]dioxole-5-boronic acid 190903-71-0 C7H5BF2O4
BUTYLDICHLOROBORANE BUTYLDICHLOROBORANE 14090-22-3 C4H9BCl2
Pentaborane Pentaborane 19624-22-7 B5H9
L-TarB-NO2,  2-(3-Nitrophenyl)-1,3,2-dioxaborolane-4R,5R-dicarboxylic  acid L-TarB-NO2, 2-(3-Nitrophenyl)-1,3,2-dioxaborolane-4R,5R-dicarboxylic acid 467443-01-2 C10H8BNO8
BORANE-DIETHYLAMINE BORANE-DIETHYLAMINE 2670-68-0 C4H14BN
BORANE-ISOAMYL SULFIDE COMPLEX BORANE-ISOAMYL SULFIDE COMPLEX 183118-10-7 C5H15BS
(S)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I& (S)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I& 463941-07-3 C24H24BNO
Dicyclohexylborane Dicyclohexylborane 1568-65-6 C12H23B
Borane-dimethylsulfide Borane-dimethylsulfide
TRIMESITYLBORANE TRIMESITYLBORANE 7297-95-2 C27H33B
BORON MONOCHLORIDE-METHYL SULFIDE COMPLEX BORON MONOCHLORIDE-METHYL SULFIDE COMPLEX 63348-81-2 C2H9BClS
1-ISOPROPYL-O-CARBORANE 1-ISOPROPYL-O-CARBORANE 13569-38-5 C5H18B10
(+)-ISOPINOCAMPHEYLBORANE TMEDA COMPLEX (+)-ISOPINOCAMPHEYLBORANE TMEDA COMPLEX 68297-74-5 2C10H19B.C6H16N2
3,3-diMethylbenzo[c][1,2]oxaborol-1(3H)-ol 3,3-diMethylbenzo[c][1,2]oxaborol-1(3H)-ol 221352-10-9 C9H11BO2
TRIS(DIMETHYLAMINO)BORANE TRIS(DIMETHYLAMINO)BORANE 4375-83-1 C6H18BN3
2,6-dimethylpyridine--borane 2,6-dimethylpyridine--borane 3999-42-6 C7H12BN
Dexsi l300 Dexsi l300
MONOBROMOBORANE-METHYL SULFIDE COMPLEX MONOBROMOBORANE-METHYL SULFIDE COMPLEX 55652-52-3 C2H10BBrS
(R)-Tetrahydro-1,3,3-triphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxaborole, 99%  (R)-Phenyl oxazaborolidine (R)-Tetrahydro-1,3,3-triphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxaborole, 99% (R)-Phenyl oxazaborolidine 145238-45-5 C23H22BNO
DIMETHYLBORON BROMIDE DIMETHYLBORON BROMIDE 5158-50-9 C2H6BBr
DIBROMOBORANE DIMETHYL SULFIDE COMPLEX DIBROMOBORANE DIMETHYL SULFIDE COMPLEX 55671-55-1 C2H10BBr2S
(R)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I& (R)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I& 865812-10-8 C24H24BNO
Potassium tert-butyl N-[2-(trifluoroboranuidyl)ethyl]carbamate Potassium tert-butyl N-[2-(trifluoroboranuidyl)ethyl]carbamate 926280-83-3 C7H14BF3NO2.K
BORANE-DI(TERT-BUTYL)PHOSPHINE COMPLEX BORANE-DI(TERT-BUTYL)PHOSPHINE COMPLEX 128363-76-8 C8H22BP
DIISOPROPOXYMETHYLBORANE DIISOPROPOXYMETHYLBORANE 86595-27-9 C7H17BO2
2-Ethynyl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane 2-Ethynyl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane 347389-74-6 C8H13BO2
4-METHYL-MORPHOLINEBORANE 4-METHYL-MORPHOLINEBORANE 15648-16-5 C5H14BNO
(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE (-)-B-METHOXYDIISOPINOCAMPHEYLBORANE 99438-28-5 C21H37BO
DICHLORO(DIISOPROPYLAMINO)BORANE DICHLORO(DIISOPROPYLAMINO)BORANE 44873-49-6 C6H14BCl2N
BORANE-N,N-DIISOPROPYLETHYLAMINE COMPLEX BORANE-N,N-DIISOPROPYLETHYLAMINE COMPLEX 88996-23-0 C8H22BN
(S)-Tetrahydro-1,3,3-triphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxaborole, 99%  (S)-Phenyl oxazaborolidine (S)-Tetrahydro-1,3,3-triphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxaborole, 99% (S)-Phenyl oxazaborolidine 131180-90-0 C23H22BNO
(-)-N-DODECYL-N-METHYLEPHEDRINIUM BROMIDE (-)-N-DODECYL-N-METHYLEPHEDRINIUM BROMIDE 57155-63-2 C23H42BrNO
(4R)-2-Methyl-4,5,5-triphenyl-1,3,2-oxazaborolidine (4R)-2-Methyl-4,5,5-triphenyl-1,3,2-oxazaborolidine 155268-88-5 C21H20BNO
(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE 85134-98-1 C21H37BO
3-AMINO-3'-CHLOROBENZANILIDE 3-AMINO-3'-CHLOROBENZANILIDE 115175-22-9 C13H11ClN2O
BUTYLDIISOPROPOXYBORANE BUTYLDIISOPROPOXYBORANE 86595-32-6 C10H23BO2
DICHLOROBORANE-DIOXANE COMPLEX  3M SOLU& DICHLOROBORANE-DIOXANE COMPLEX 3M SOLU& 252265-33-1 C4H9BCl2O2
BORON TRIS(TRIFLUOROACETATE) BORON TRIS(TRIFLUOROACETATE) 350-70-9 C6BF9O6
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