ChemicalBook Product Catalog Chemical Reagents Organic reagents Borane TRIS(PENTAFLUOROPHENYL)BORANE

TRIS(PENTAFLUOROPHENYL)BORANE

TRIS(PENTAFLUOROPHENYL)BORANE Basic information
Uses
Product Name:TRIS(PENTAFLUOROPHENYL)BORANE
Synonyms:PERFLUOROTRIPHENYLBORANE;TRIS(PENTAFLUOROPHENYL)BORANE;TRIS(PENTAFLUOROPHENYL)BORON;Tris(2,3,4,5,6-pentafluorophenyl)borane;TRIS(PENTAFLUOROPHENYL)BORANE SOLUTION, ~3% IN ISOPAR;TRIS(PENTAFLUOROPHENYL)BORON, 97+%;Tris(Pentafluorophenyl)Borate;Tris(pentafluorophenyl)boron,min.97%
CAS:1109-15-5
MF:C18BF15
MW:511.98
EINECS:000-000-0
Product Categories:organoboron compound;BoronAlphabetic;B (Classes of Boron Compounds);Precursors by Metal;TP - TZ;Vapor Deposition Precursors;Boranes
Mol File:1109-15-5.mol
TRIS(PENTAFLUOROPHENYL)BORANE Structure
TRIS(PENTAFLUOROPHENYL)BORANE Chemical Properties
Melting point 126-131 °C (lit.)
Boiling point 327.3±42.0 °C(Predicted)
density 0.73 g/mL at 20 °C
refractive index n20/D 1.41
Fp 7 °C
storage temp. Inert atmosphere,Store in freezer, under -20°C
solubility Soluble in hexane, chloroform, dichloromethane, toluene, and polar solvents.
form Powder
color White to light yellow-beige
Specific Gravity1.7
λmax306nm(Toluene)(lit.)
Sensitive Moisture Sensitive
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
Merck 14,9755
BRN 2931347
InChIKeyOBAJXDYVZBHCGT-UHFFFAOYSA-N
CAS DataBase Reference1109-15-5(CAS DataBase Reference)
EPA Substance Registry SystemBorane, tris(2,3,4,5,6-pentafluorophenyl)- (1109-15-5)
Safety Information
Hazard Codes Xi,T,N,Xn,F
Risk Statements 36/37/38-25-67-65-50/53-38-11
Safety Statements 60-61-62-45-37/39-26-36
RIDADR UN 1268 3/PG 2
WGK Germany 3
TSCA No
HazardClass 6.1
PackingGroup III
HS Code 29039990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
TRIS(PENTAFLUOROPHENYL)BORANE Usage And Synthesis
UsesTris(pentafluorophenyl)borane (CAS# 1109-15-5) is a useful research chemical, used as a catalyst in the metal-free catalytic reductive cleavage of enol ethers via proposed mechanism of tandem hydrosilylation and silicon-​assisted β-​elimination. Tris(pentafluorophenyl)borane also appears as an ancillary ligand in luminescent isocyano Rh(I) complexes.
Chemical Propertieswhite powder
UsesCatalyst in organic transformations; cocatalyst with group IV metallocene alkyls in olefin polymerization.
UsesTris(pentafluorophenyl)borane is used as an excellent activator component in homogeneous Ziegler-Natta chemistry. It is also used as a catalyst for reductions, alkylations, hydrometallation reactions and catalyzed aldol-type reactions. It is a useful Lewis acid and catalyzes hydrosilylation of aldehydes. Further, it is used in olefin polymerization catalysis. It serves as a reagent in the preparation of organometallic complexes. In addition to this, it is useful as polymerization catalysts and used to study the heterolytic cleavage of dihydrogen in associated with tri-tert-butylphosphine.
General DescriptionB(C6F5)3 is a Lewis acid, stronger than the inorganic parent molecule BF3. In contrast to the prominent Lewis acids, the pentafluorides of the heavier elements of group 15, B(C6F5)3 has no oxidizing properties. B(C6F5)3 forms adducts with neutral and weaker Lewis bases. B(C6F5)3 has the capability to easily accept anionic ligands bonded to metals.
TRIS(PENTAFLUOROPHENYL)BORANE Preparation Products And Raw materials
Raw materialsPETROLEUM ETHER-->n-Butyllithium-->Boron tribromide-->Bromopentafluorobenzene
Preparation Products9-BBN DIMER-->[BIS(TRIFLUOROACETOXY)IODO]PENTAFLUOROBENZENE
BISMUTH TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE) TRIS(TETRAMETHYLCYCLOPENTADIENYL)CERIUM BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)LEAD(II) Iridium(III) acetylacetonate Tris(triphenylphosphine)ruthenium(II) chloride TRIS(METHYLCYCLOPENTADIENYL)ERBIUM (TERT-BUTYLIMIDO)TRIS(ETHYLMETHYLAMINO)TANTALUM TRIS(METHYLCYCLOPENTADIENYL)YTTRIUM (III) Boron Trityl tetrakis(pentafluorophenyl)borate TRIS(PENTAFLUOROPHENYL)BORANE Pentafluorobenzene TCPB LITHIUM TETRAKIS(PENTAFLUOROPHENYL)BORATE-ETHYL ETHER COMPLEX 4-ISOPROPYL-4'-METHYLDIPHENYLIODONIUM TETRAKIS(PENTAFLUOROPHENYL)BORATE Dimethylanilinium tetrakis(pentafluorophenyl)borate POTASSIUM TETRAKIS(PENTAFLUOROPHENYL)BORATE LITHIUM TETRAKIS(PENTAFLUOROPHENYL)BORATE-ETHYL ETHER COMPLEX
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