B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE

B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Basic information
Product Name:B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE
Synonyms:R-ALPINE-BORANE(R);B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE;(R)-B-isopinocampheyl-9-borabicyclo[3.3.1]nonane;R-2,7,7-trimethylnorpinanborabicyclo(3.3.1)nonane;R-alpine-borane (0.5M soln. in thf);R-Alpine-Borane? (R)-2,6,6-trimethyl-4-(9-borabicyclo[3.3.1]nonan-9-yl)bicyclo[3.1.1]heptane;R-ALPINE-BORANE;R-ALPINE-BORANE 97%
CAS:73624-47-2
MF:C18H31B
MW:258.25
EINECS:
Product Categories:API intermediates
Mol File:73624-47-2.mol
B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Structure
B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Chemical Properties
Boiling point >55 °C(lit.)
alpha -3 º (NEAT)
density 0.896 g/mL at 25 °C
Fp 1 °F
optical activity[α]21/D -22°, c = 12 in THF
Safety Information
Hazard Codes F,Xn
Risk Statements 11-19-22-36/37/38-17-40-36/37
Safety Statements 16-26-27-36/37/39-24-6-36/37
RIDADR UN 1993 3/PG 2
WGK Germany 3
HazardClass 4.3
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Usage And Synthesis
UsesR-Alpine-Borane? solution may be used to prepare:
  • (R)-5-(Benzyloxy)pent-3-y-2-ol, an intermediate for the stereoselective total synthesis of (-)-stagonolide D.
  • (R)-1-(p-Tolyl)-1-pentyn-3-ol, an intermediate for the enatioselective synthesis of (R)-incrustoporin.
  • N-(tert-Butyloxycarbonyl)-(4S)-[4-2H]-1-L-homoserine tert-butyl ester, an intermediate for synthesizing (4S)-[4-2H]-L-homoserine.
General DescriptionR-Alpine-Borane? is a chiral reducing agent, synthesized from (+)-α-pinene via hydroboration.
B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE Preparation Products And Raw materials
Triethylborane B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE TRIBUTYLBORANE LITHIUM B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONYL HYDRIDE B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE,S-B-isopinocampheyl-9-borabicyclo(3.3.1)nonane 9-Borabicyclo[3.3.1]nonane TRI-SEC-BUTYLBORANE (1R)-(+)-CIS-PINANE

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