(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE

(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE Basic information
Product Name:(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE
Synonyms:(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE;(+)-DIISOPINOCAMPHEYLMETHOXYBORANE;(-)-B-Methoxydiisopinocampheylborane;)-B-Methoxydiisopinocampheylborane;methoxy-bis[(1R,3S,4R,5R)-4,6,6-trimethyl-3-bicyclo[3.1.1]heptanyl]borane;Borinic acid, B,B-bis[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]-, methyl ester;()-B-Methoxydiisopinocampheylborane;(-)-B-Methoxydiisopinocampheylborane hydrate
CAS:85134-98-1
MF:C21H37BO
MW:316.33
EINECS:
Product Categories:
Mol File:85134-98-1.mol
(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE Structure
(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE Chemical Properties
Boiling point 365.6±9.0 °C(Predicted)
density 0.95±0.1 g/cm3(Predicted)
Fp >230 °F
storage temp. 2-8°C
optical activity[α]20/D 72±3°, c = 1% in diethyl ether
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
10-21
MSDS Information
ProviderLanguage
SigmaAldrich English
(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE Usage And Synthesis
UsesReactant involved in organic synthesis reactions such as:
  • Double allylboration for synthesis of fragments of tetrafibricin
  • Anticancer cytotoxic monorhizopodin synthesis
  • Annulation of cyclic allylsilanes
  • Asymmetric synthesis of β-amino-α-hydroxy acid taxol side chain analogs
General DescriptionB-Methoxydiisopinocampheylborane (Ipc2BOMe) is an organoborane compound, which is prepared from excess α-pinene, borane dimethylsulfide, and methanol via the formation of an intermediate diisocampheylborane. Ipc2BOMe is used as a versatile reagent for the construction of C-C bonds in asymmetric synthesis.
(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE Preparation Products And Raw materials
Methoxydiethylborane ISO-PROPYLCYCLOBUTANE 1-ETHYLCYCLOBUTANE Disiamylborane (1R)-(+)-CIS-PINANE (-)-B-METHOXYDIISOPINOCAMPHEYLBORANE (1R)-(+)-TRANS-PINANE (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE

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