Catalyst and Auxiliary

The catalyst can change the reaction rate in the chemical reaction, and the composition and the quality of the catalyst can be kept constant after the reaction. The catalyst that accelerates the reaction is called the positive catalyst, slows down called Negative Catalyst or slow agent. It said catalyst is a positive catalyst for the general correction. This kind of catalyst in the industry, especially the organic chemical industry used more, and has great significance, Such as sulfuric acid prepared by contacting, ammonia, hydrolysis of the ester and polysaccharide, Oil Hydrogenation, etc. Commonly used catalysts are mainly metal, metal oxide and inorganic acid. If the catalyst is solid, the substance of the reaction is gas, to form a multi-phase catalytic reaction, this catalyst, sometimes called catalyst or contact agent. The catalyst is generally selective, it can only make a reaction or a certain type of reaction to speed up. But some reaction can be used for a variety of catalysts, such as the hydrogenation reaction can often be platinum, palladium, nickel, should be carefully chosen. In the catalytic reaction, the catalyst is often added cocatalyst known to enhance catalytic action of the catalyst. For example, iron is a catalyst in ammonia industry, adding a small amount of potassium and aluminum can enhance the catalytic effect of iron. The composition and weight of the catalyst and cocatalyst cannot change before and after the reaction. All of the above are inorganic catalysts. The enzyme is a protein, is very important organic catalyst.

There are many kinds of catalyst, catalyst and reaction system according to the phase of the classification, there are two types of homogeneous and heterogeneous catalysts. Heterogeneous catalysts most widely used, there are 3 kinds of gas, liquid and solid state, the variety and application of solid catalyst. The solid catalyst, which is made of metal (nickel, platinum, palladium, chromium, cobalt, titanium, vanadium, etc.) or metal oxide (copper oxide, vanadium pentoxide, lead oxide), is dispersed and deposited on the carrier in order to obtain a good dispersion effect and increase the specific surface area. The catalyst requires reliable activity, stability, selectivity, long working life, not easy to poisoning and over-burning, easy to regenerate. In order to improve the catalytic efficiency, the pure metal catalysts are made into alloy catalysts (such as nickel aluminium alloy) and composite catalysts (ZieglerNatta). The composite catalyst is composed of main catalyst and co-catalyst. In the new efficient catalysts also add other components. The production and development of high efficiency catalyst have promoted the development of polymer materials, and produced much polymer function and structure material ,which is new generation of high performance and high added value.

With the extensive application of catalyst and a number of new catalysts, we can make a lot of new chemical reactions to achieve industrialization, in order to provide an increasing number of chemical products; also can make some of the original chemical reaction conditions have been improved, in order to improve the production efficiency and product quality, make full use of resources. The important subject in the field of modern chemistry and chemical research is to select and develop more and better catalyst for the new generation. But the role of a catalyst is not beneficial to humans, such as combustion products of supersonic jet fuel as a catalyst can cause the stratosphere (10 to 50 km altitude) decomposition of ozone in the atmosphere, to the sun's ultraviolet absorption decreased, resulting in some areas of skin cancer patients increased. Is developing a new supersonic jet fuel, its combustion products will not become a catalyst,which will cause the ozone decomposition catalyst in the stratosphere.

Additives are added in the industrial and agricultural production, especially in the chemical production of some of the auxiliary chemicals, its role is to improve the production process, improve product quality and yield, or to give the product a unique application performance.

Additive are large class of important chemical in the production of auxiliary raw materials, they can give a special performance to product, improve use of finished products; and can accelerate the chemical reaction rate, improve product yield; they can save raw materials, improve processing efficiency. Additives are widely used in the chemical industry, especially organic synthesis, synthetic material processing and petroleum refining, pesticide, medicine, dye, paint and other industrial sectors. Additives can be divided into synthesized additives and processing additives. Synthetic additives are used in monomer synthesis and polymerization of a variety of auxiliary agents in resin, fiber, rubber, etc. They include catalysts, initiators, solvents, dispersants, emulsifiers, polymerization inhibitors, regulators, termination agents, etc. Processing aid refers to the auxiliary chemicals used in the manufacture of raw rubber, plastics processing, chemical fiber spinning and spinning process, including plasticizers, heat stabilizers, antioxidants, light stabilizers , flame retardants, blowing agents, lubricants, mold release agents, curing agents, accelerators, softeners, anti-scorching agents, surfactants, oils, fillers, etc. In these additives, many of them are dangerous chemicals, Such as benzoyl peroxide, azobisisobutyronitrile, hydrogen peroxide - ferrous blue, alkyl aluminum chloride, titanium and other initiators, catalysts are inflammable and explosive materials, should be required to "chemical Dangerous Goods Safety Management Regulations", for storage, transportation, operation and use.

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Structure Chemical Name CAS MF
Diphenylmethylidene(cyclopentadienyl)(9-fluorenyl)zirconium dichloride Diphenylmethylidene(cyclopentadienyl)(9-fluorenyl)zirconium dichloride 132510-07-7 C31H22.Cl2Zr
Carbomer 956 Carbomer 956
1,2-DISTEAROYL-PHOSPHATIDYLETHANOLAMINE-METHYL-POLYETHYLENEGLYCOL CONJUGATE 1,2-DISTEAROYL-PHOSPHATIDYLETHANOLAMINE-METHYL-POLYETHYLENEGLYCOL CONJUGATE
SA-PEG-FITC SA-PEG-FITC
ROYCO 64 ADVANCED SYNTHETIC MULTI-PURPOSE AIRCRAFT GREASE ROYCO 64 ADVANCED SYNTHETIC MULTI-PURPOSE AIRCRAFT GREASE
Silane-PEG6-Biotin Silane-PEG6-Biotin
SH-(CH2)11-PEG3-COOH SH-(CH2)11-PEG3-COOH
SH-PEG7-SH SH-PEG7-SH
OH-PEG-SS OH-PEG-SS
Alkene-PEG-PLA(3K) Alkene-PEG-PLA(3K)
PLGA(10K)-PEG-Mal PLGA(10K)-PEG-Mal
Benzyl-PEG-OH Benzyl-PEG-OH
PLL-PEG-OH PLL-PEG-OH
PLGA(2K)-PEG-SC PLGA(2K)-PEG-SC
Phosphoric acid-PEG-COOH Phosphoric acid-PEG-COOH
ASP-PEG-ASP ASP-PEG-ASP
8-ArmPEG-(6Arm-Mal,2Arm-Biotin) 8-ArmPEG-(6Arm-Mal,2Arm-Biotin)
Cy3.5-PEG-Mal Cy3.5-PEG-Mal
DMPE PEG NHS DMPE PEG NHS
Monoethoxylsilane-PEG-COOH Monoethoxylsilane-PEG-COOH
Retinoic acid PEG azide Retinoic acid PEG azide
Cysteine PEG Cysteine Cysteine PEG Cysteine
Retinoic acid PEG Maleimide Retinoic acid PEG Maleimide
Tetraamminepalladium(II) dichloride Tetraamminepalladium(II) dichloride 13815-17-3 ClH8N4Pd+
2,2-BIS(2-HYDROXY-5-BIPHENYLYL)PROPANE 2,2-BIS(2-HYDROXY-5-BIPHENYLYL)PROPANE 24038-68-4 C27H24O2
Pomalidomide-PEG4-CO2H Pomalidomide-PEG4-CO2H 2138440-81-8 C24H31N3O10
4-((2-(2-(2-(2-aminoethoxy)ethoxy)ethoxy)ethyl)amino)-2-(2,6-dioxopiperidin-3-yl)isoindoline-1,3-dione 4-((2-(2-(2-(2-aminoethoxy)ethoxy)ethoxy)ethyl)amino)-2-(2,6-dioxopiperidin-3-yl)isoindoline-1,3-dione 2093416-31-8 C21H28N4O7
2-(2H-Benzothiazol-2-yl)-6-(dodecyl)-4-methylphenol 2-(2H-Benzothiazol-2-yl)-6-(dodecyl)-4-methylphenol 125304-04-3 C25H35N3O
Hydrogen transfer palladium carbon catalyst Hydrogen transfer palladium carbon catalyst
Palladium hydroxide carbon catalyst Palladium hydroxide carbon catalyst
Gold bond alloy silver bond alloy palladium bond alloy copper bond alloy Gold bond alloy silver bond alloy palladium bond alloy copper bond alloy
Dsixty five Dsixty five
NA NA
2-Allyloxy-1,3,5-tribromobenzene 2-Allyloxy-1,3,5-tribromobenzene 3278-89-5 C9H7Br3O
DBCO-PEG8-amine DBCO-PEG8-amine
DBCO-PEG12-O-NH2 DBCO-PEG12-O-NH2
Benzyl-PEG18-Br Benzyl-PEG18-Br
Fmoc-NH-PEG4-ACA Fmoc-NH-PEG4-ACA
4-ArmPEG-NTA 4-ArmPEG-NTA
4-ArmPEG-(3Alkyne-1NHS) 4-ArmPEG-(3Alkyne-1NHS)
SH-PEG-SS SH-PEG-SS
CHO-PEG-SCM CHO-PEG-SCM
COOH-PEG-HZ COOH-PEG-HZ
Biotin-PEG-Tretinoin Biotin-PEG-Tretinoin
BOC-NH-PEG-SG BOC-NH-PEG-SG
MTX-PEG-Mal MTX-PEG-Mal
diamminebis(cyano-C)palladium diamminebis(cyano-C)palladium 15020-94-7 C2H6N4Pd
Ruthenium target Ruthenium target
Alcohols, C9-11, ethoxylated Alcohols, C9-11, ethoxylated 68439-46-3
TEREPHTHALYLIDENE DICAMPHOR SULFONIC ACID TEREPHTHALYLIDENE DICAMPHOR SULFONIC ACID 90457-82-2 C28H34O8S2
mPEG-DMPE(ammonium salt) mPEG-DMPE(ammonium salt)
PLA(2K)-PEG-NH2 PLA(2K)-PEG-NH2
cRGD-PEG-NH2 cRGD-PEG-NH2
Ultrafine Ruthenium Powder Ultrafine Ruthenium Powder
SG-PEG-SG SG-PEG-SG
4-arm-PEG-OPSS 4-arm-PEG-OPSS
Alkyne-PEG-FITC Alkyne-PEG-FITC
mPEG-PLGA mPEG-PLGA
Acetylthio-PEG-Mal Acetylthio-PEG-Mal
Biotin-PEG-CHO Biotin-PEG-CHO
CLS-PEG-Biotin CLS-PEG-Biotin
Boron trifluoride acetonitrile complex Boron trifluoride acetonitrile complex 420-16-6 C2H3BF3N
2,3,4,5-TETRAMETHYLCYCLOPENTADIENEDIMETHYLSILYL-TERT-BUTYLAMIDO TITANIUM DICHLORIDE 2,3,4,5-TETRAMETHYLCYCLOPENTADIENEDIMETHYLSILYL-TERT-BUTYLAMIDO TITANIUM DICHLORIDE 135072-61-6 C15H27Cl2NSiTi
HEXAFLUOROPROPYLENE OXIDE DIMER HEXAFLUOROPROPYLENE OXIDE DIMER C6F12O2
Cellulose diacetate Cellulose diacetate 9035-69-2 C2H4O2
Polyethylenglykoldiallylether Polyethylenglykoldiallylether 59788-01-1
POTASSIUM TETRABROMOPALLADATE(II) POTASSIUM TETRABROMOPALLADATE(II) 13826-93-2 Br4H4KPd-
Alkyne-PEG-Mal Alkyne-PEG-Mal
TETRAAMMINEPALLADIUM(II) TETRACHLOROPALLADATE(II) TETRAAMMINEPALLADIUM(II) TETRACHLOROPALLADATE(II) 13820-44-5 Cl4H8N4Pd2
mPEG-SS-NHS mPEG-SS-NHS
Iodoacetyl-PEG-Mal Iodoacetyl-PEG-Mal
8-Arm PEG-SA 8-Arm PEG-SA
DSPE-PEG-COOH DSPE-PEG-COOH C48H90NO14P
CY5.5-PEG-SH CY5.5-PEG-SH
Tetrakis(tri-o-tolylphosphine)palladium(0) Tetrakis(tri-o-tolylphosphine)palladium(0) 175164-86-0 C84H84P4Pd
Dopamine-PEG-Dopamine Dopamine-PEG-Dopamine
8-arm-PEG-OPSS 8-arm-PEG-OPSS
FA-PEG-OH FA-PEG-OH
mPEG-FITC mPEG-FITC
OPSS-PEG-MAL OPSS-PEG-MAL
PLGA-COOH PLGA-COOH
8-ArmPEG-(7Arm-COOH,1ARrm-NH2) 8-ArmPEG-(7Arm-COOH,1ARrm-NH2)
ACA-PEG-NH-Mal ACA-PEG-NH-Mal
Benzyl-PEG40-OH Benzyl-PEG40-OH
CLS-PEG-NBD CLS-PEG-NBD
COOH-PEG-NH2.HCl COOH-PEG-NH2.HCl
DMPE-PEG-SC DMPE-PEG-SC
DPPE-PEG-SC DPPE-PEG-SC
FA-PEG4-Alkyne FA-PEG4-Alkyne
mPEG-Anilin mPEG-Anilin
N3-PEG-PAA(1.8K)-DA N3-PEG-PAA(1.8K)-DA
PLGA(12K)-PEG-NH2 PLGA(12K)-PEG-NH2
PLGA(2K)-PEG-COOH PLGA(2K)-PEG-COOH
STA-PEG-SC STA-PEG-SC
c(RGDyk)-PEG-SH c(RGDyk)-PEG-SH
HZ-PEG-N3 HZ-PEG-N3
Cy3.5-PEG-SH Cy3.5-PEG-SH
NH2.HCl-PEG-NH2.HCl NH2.HCl-PEG-NH2.HCl
Diethoxylsilane-PEG-NH2 Diethoxylsilane-PEG-NH2
DSPE(Sodium salt)-PEG-OH DSPE(Sodium salt)-PEG-OH
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