2-Allyloxy-1,3,5-tribromobenzene

2-Allyloxy-1,3,5-tribromobenzene Basic information
Product Name:2-Allyloxy-1,3,5-tribromobenzene
Synonyms:1,3,5-tribromo-2-(2-propenyloxy)-benzen;ALLYL 2,4,6-TRIBROMOPHENYL ETHER;ALLYL TRIBROMOPHENYL ETHER;Benzene,1,3,5-tribromo-2-(2-propenyloxy);TRIBROMOPHENYL ALLYL ETHER;2-allyloxy-1,3,5-tribromobenzene;1,3,5-TribroMo-2-(2-propen-1-yloxy)-benzene;Allyl 2,4,6-tribromophenyl ether 98%
CAS:3278-89-5
MF:C9H7Br3O
MW:370.86
EINECS:221-913-2
Product Categories:Allyl Monomers;Monomers;Polymer Science
Mol File:3278-89-5.mol
2-Allyloxy-1,3,5-tribromobenzene Structure
2-Allyloxy-1,3,5-tribromobenzene Chemical Properties
Melting point 74-76 °C (lit.)
Boiling point 339.5±37.0 °C(Predicted)
density 1.950±0.06 g/cm3(Predicted)
solubility Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form Solid
color Off-White to Beige
EPA Substance Registry SystemAllyl 2,4,6-tribromophenyl ether (3278-89-5)
Safety Information
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
2-Allyloxy-1,3,5-tribromobenzene Usage And Synthesis
Application1,3,5-Tribromo-2-(2-propen-1-yloxy)-benzene is used as a brominated flame retardant.
Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package.
SynthesisSynthesis_3278-89-5
To the ethanol solution of the sodium tribromophenolate salt prepared in the step 1), the dispersing agent sodium stearate 2.5 g is added.And catalyst II phenyl triethyl ammonium chloride 5.6g,The temperature is raised to 75 ?? C to reflux the reaction.Further, 1000 ml of an ethanol solution of chloropropene having a volume ratio of chloropropene to ethanol of 1:5 was slowly added thereto, and then the reaction was kept at 75 ?? C for 6.5 h until the end.Then, the temperature is lowered to 7 ?? C in sequence, and then suction filtration is performed to recover the ethanol solution.After washing the filter cake with water, the filter cake was dried at 60 ?? C.2,4,6-Tribromophenyl allyl ether was obtained as a white powdery solid in a yield of 96.2%.
2-Allyloxy-1,3,5-tribromobenzene Preparation Products And Raw materials
Raw materials2,4,6-TRIBROMOPHENOLSODIUMSALT-->2,4,6-Tribromophenol-->ALLYL IODIDE-->Allyl chloride-->Allyl bromide
AKOS B028925 allyl pentabromophenyl ether 2,4,6-Tribromophenyl acrylate PENTABROMOPHENYL ACRYLATE 2-Allyloxy-1,3,5-tribromobenzene TRIBROMONEOPENTYL METHACRYLATE Tribromobenzene 1,2,3-TRIBROMOBENZENE Allyl ether PENTABROMOPHENYL METHACRYLATE

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