Amides

Amides refer to compounds derived from the substitution of the hydrogen group on the nitrogen atom of ammonia or an amine with an acyl group. Amides can also be seen as the compound derived from substitution of the hydroxyl group of the carboxylic acid molecules with amino or amino phenyl group. Common includes formamide (HCO-NH2), acetamide [CH3-CO-NH2] and carbonamide [CO- (NH2) 2]. At room temperature, they are all crystal except formamide which is in the form of crystal. Low amide is easily soluble in water. Amides are neutral substances with heating boiling of amide and water resulting in the occurrence of the hydrolysis reaction, producing carboxylic acid and ammonia, RCONH2 + H2O-- (Heating) - RCOOH + NH3. If we supplement alkali upon the hydrolysis, the generated acid will become a salt and the ammonia will escape. Upon heating: RCONH2 + NaOH - (heating) - RCOONa + NH3↑.

Polypeptides, proteins, and synthetic fibers such as nylon 6, nylon 66 and nylon 1010 are all compounds containing amide bonds. The structural formula is the common amide in vivo including glutamine (abbreviated as GLn or Q) and asparagine (abbreviated as Asn or N) and their derivatives. They not only are the composition of protein, but also play the role of nitrogen storage and nitrogen supply in the life activities. For example, part of the nitrogen during the synthesis of purine and pyrimidine nucleotides can be supplied by glutamine. It is often also the bridge linking the protein and carbohydrates in the glycoproteins.

The products derived from substitution of the two hydrogen atoms in the ammonia molecules by acyl groups are called imide. The hydrogen atom attached to the nitrogen atom in the imide molecule can be removed in the form of a proton, and the imide is weakly acidic.

Many Amides have industrial applications. For example, acetamide (CH3CONH2), dimethylformamide [HCON (CH3) 2] is an important solvent. Acetanilide is the intermediates for the preparation of sulfa drugs. Urea is an important raw material for nitrogen and synthetic resins. Amide type with ring structure is called lactam. The important lactam is caprolactam, which is the monomer for the synthesis of nylon 6. Application of cyclohexanone as raw material can be used for preparation of caprolactam.

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Structure Chemical Name CAS MF
3-Amino-2,2-dimethylpropionamide 3-Amino-2,2-dimethylpropionamide 324763-51-1 C5H12N2O
cis-13-Docosenoamide cis-13-Docosenoamide 112-84-5 C22H43NO
N-Ethyl-p-menthane-3-carboxamide N-Ethyl-p-menthane-3-carboxamide 39711-79-0 C13H25NO
4-Methoxybenzamide 4-Methoxybenzamide 3424-93-9 C8H9NO2
2,4-Dihydroxybenzamide 2,4-Dihydroxybenzamide 3147-45-3 C7H7NO3
N,N-Diethylchloroacetamide N,N-Diethylchloroacetamide 2315-36-8 C6H12ClNO
N-n-Butyl benzene sulfonamide N-n-Butyl benzene sulfonamide 3622-84-2 C10H15NO2S
N,N'-Ethylenebis(stearamide) N,N'-Ethylenebis(stearamide) 110-30-5 C38H76N2O2
Pentanamide Pentanamide 626-97-1 C5H11NO
2-Methyl-2-hydroxypropionamide 2-Methyl-2-hydroxypropionamide 13027-88-8 C4H9NO2
Ethopabate Ethopabate 59-06-3 C12H15NO4
N-Methyl-p-toluenesulfonamide N-Methyl-p-toluenesulfonamide 640-61-9 C8H11NO2S
N-Phenylmaleimide N-Phenylmaleimide 941-69-5 C10H7NO2
Cinnamamide Cinnamamide 621-79-4 C9H9NO
Cyclopropanesulfonamide Cyclopropanesulfonamide 154350-29-5 C3H7NO2S
N-Methylacetamide N-Methylacetamide 79-16-3 C3H7NO
(2S)-Bornane-10,2-sultam (2S)-Bornane-10,2-sultam 108448-77-7 C10H17NO2S
Malonamide Malonamide 108-13-4 C3H6N2O2
5-Amino-2-methylbenzenesulfonamide 5-Amino-2-methylbenzenesulfonamide 6973-09-7 C7H10N2O2S
Sulfamide Sulfamide 7803-58-9 H4N2O2S
N,N-Dimethylformamide N,N-Dimethylformamide 68-12-2 C3H7NO
2-Ethylsulfonylimidazo[1,2-a]pyridine-3-sulfonamide 2-Ethylsulfonylimidazo[1,2-a]pyridine-3-sulfonamide 141776-47-8 C9H11N3O4S2
2-Acrylamide-2-methylpropanesulfonic acid 2-Acrylamide-2-methylpropanesulfonic acid 15214-89-8 C7H13NO4S
N-METHYLSUCCINIMIDE N-METHYLSUCCINIMIDE 1121-07-9 C5H7NO2
N,2,3-Trimethyl-2-isopropylbutamide N,2,3-Trimethyl-2-isopropylbutamide 51115-67-4 C10H21NO
N,N-Dimethylpropionamide N,N-Dimethylpropionamide 758-96-3 C5H11NO
N-Vinylcaprolactam N-Vinylcaprolactam 2235-00-9 C8H13NO
2-Iodoacetamide 2-Iodoacetamide 144-48-9 C2H4INO
DL-ALPHA-AMINO-EPSILON-CAPROLACTAM DL-ALPHA-AMINO-EPSILON-CAPROLACTAM 671-42-1 C6H12N2O
Octadecanamide Octadecanamide 124-26-5 C18H37NO
1,1-Cyclohexanediacetic acid mono amide 1,1-Cyclohexanediacetic acid mono amide 99189-60-3 C10H17NO3
CYCLOPROPANECARBOXAMIDE CYCLOPROPANECARBOXAMIDE 6228-73-5 C4H7NO
p-Nitrobenzamide p-Nitrobenzamide 619-80-7 C7H6N2O3
4-(2-Aminoethyl)benzenesulfonamide 4-(2-Aminoethyl)benzenesulfonamide 35303-76-5 C8H12N2O2S
N-Ethylmaleimide N-Ethylmaleimide 128-53-0 C6H7NO2
2,4-Dichloro-5-sulfamoylbenzoic acid 2,4-Dichloro-5-sulfamoylbenzoic acid 2736-23-4 C7H5Cl2NO4S
2-Methyl-5-nitrobenzenesulfonamide 2-Methyl-5-nitrobenzenesulfonamide 6269-91-6 C7H8N2O4S
3,5-Dihydroxybenzamide 3,5-Dihydroxybenzamide 3147-62-4 C7H7NO3
Diethylacetamide Diethylacetamide 685-91-6 C6H13NO
4-Chlorothiobenzamide 4-Chlorothiobenzamide 2521-24-6 C7H6ClNS
N,N'-Dimethyloxalamide N,N'-Dimethyloxalamide 615-35-0 C4H8N2O2
1,3-DIAMINOPROPANE DIHYDROCHLORIDE 1,3-DIAMINOPROPANE DIHYDROCHLORIDE 10517-44-9 C3H12Cl2N2
N-Methoxy-N-methylacetamide N-Methoxy-N-methylacetamide 78191-00-1 C4H9NO2
N-Ethylacetamide N-Ethylacetamide 625-50-3 C4H9NO
Benzamide Benzamide 55-21-0 C7H7NO
N-Methylcaprolactam N-Methylcaprolactam 2556-73-2 C7H13NO
tert-Butanesulfinamide tert-Butanesulfinamide 146374-27-8 C4H11NOS
CHLOROACETAMIDINE HYDROCHLORIDE CHLOROACETAMIDINE HYDROCHLORIDE 10300-69-3 C2H6Cl2N2
3-AMINOBENZOYLMETHYLAMIDE 3-AMINOBENZOYLMETHYLAMIDE 25900-61-2 C8H10N2O
N,N'-Methylenebisacrylamide N,N'-Methylenebisacrylamide 110-26-9 C7H10N2O2
2,2-Dibromo-2-cyanoacetamide 2,2-Dibromo-2-cyanoacetamide 10222-01-2 C3H2Br2N2O
N,N-Diethyldodecanamide N,N-Diethyldodecanamide 3352-87-2 C16H33NO
AMINOGUANIDINE HYDROCHLORIDE AMINOGUANIDINE HYDROCHLORIDE 1937-19-5 CH7ClN4
Thioacetamide Thioacetamide 62-55-5 C2H5NS
N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE N-(TERT-BUTOXYCARBONYL)-P-TOLUENESULFONAMIDE 18303-04-3 C12H17NO4S
(1S,4aS)-7-isopropyl-1,4a-dimethyl-N-(4-methyl-2-oxo-2H-chromen-7-yl)-1,2,3,4,4a,4b,5,6,10,10a-decahydrophenanthrene-1-carboxamide (1S,4aS)-7-isopropyl-1,4a-dimethyl-N-(4-methyl-2-oxo-2H-chromen-7-yl)-1,2,3,4,4a,4b,5,6,10,10a-decahydrophenanthrene-1-carboxamide
4-Amino-N-methylbenzamide 4-Amino-N-methylbenzamide 6274-22-2 C8H10N2O
2-[(3,3-DIPHENYLPROPYL)AMINO]ACETAMIDE HYDROCHLORIDE 2-[(3,3-DIPHENYLPROPYL)AMINO]ACETAMIDE HYDROCHLORIDE 76991-05-4 C17H20N2O
NG-25 NG-25 1315355-93-1 C29H30F3N5O2
2,2-Diphenyl-N-[4-(thiazol-2-ylsulfamoyl)-phenyl]-acetamide 2,2-Diphenyl-N-[4-(thiazol-2-ylsulfamoyl)-phenyl]-acetamide 313254-51-2 C23H19N3O3S2
(1S,3S,6R)-N,N-dimethyl-7-oxabicyclo[4.1.0]heptane-3-carboxamide (1S,3S,6R)-N,N-dimethyl-7-oxabicyclo[4.1.0]heptane-3-carboxamide 929693-35-6 C9H15NO2
SGT-78 SGT-78 1631074-54-8 C22H24N4O
2-Phenylacetamide 2-Phenylacetamide 103-81-1 C8H9NO
N-(3-(4H-1,2,4-triazol-4-yl)phenyl)acetamide N-(3-(4H-1,2,4-triazol-4-yl)phenyl)acetamide 1029769-35-4 C10H10N4O
D-2-AMINO-2-PHENYLACETAMIDE D-2-AMINO-2-PHENYLACETAMIDE 63291-39-4 C8H10N2O.ClH
2,5-Piperazinediacetamide, 3,6-dioxo- 2,5-Piperazinediacetamide, 3,6-dioxo- 98490-54-1 C8H12N4O4
7]decane-1-carboxamide, N-[1-(phenylmethyl)-4-piperidinyl] 7]decane-1-carboxamide, N-[1-(phenylmethyl)-4-piperidinyl] 314030-54-1 C23H32N2O
4-AMINO-3,5-DINITROBENZAMIDE 4-AMINO-3,5-DINITROBENZAMIDE 54321-79-8 C7H6N4O5
N-(4-ethoxy-2-nitrophenyl)acetamide N-(4-ethoxy-2-nitrophenyl)acetamide 885-81-4 C10H12N2O4
AcetaMide, 2,2'-oxybis[N,N-dioctyl- AcetaMide, 2,2'-oxybis[N,N-dioctyl- 342794-43-8 C36H72N2O3
N-(4-ethoxyphenyl)-3-hydroxy-4-[(2,4,5-trichlorophenyl)azo]naphthalene-2-carboxamide N-(4-ethoxyphenyl)-3-hydroxy-4-[(2,4,5-trichlorophenyl)azo]naphthalene-2-carboxamide 5012-29-3 C25H18Cl3N3O3
N-cyclohexylacetoacetamide N-cyclohexylacetoacetamide 1132-42-9 C10H17NO2
1-benzyl-4-(p-toluidino)piperidine-4-carboxamide 1-benzyl-4-(p-toluidino)piperidine-4-carboxamide 1164-72-3 C20H25N3O
5-Amino-N,N'-bis(2,3-dihydroxypropyl)isophthalamide 5-Amino-N,N'-bis(2,3-dihydroxypropyl)isophthalamide 203515-86-0 C14H22ClN3O6
N,N'-(2-hydroxypropane-1,3-diyl)diacetamide N,N'-(2-hydroxypropane-1,3-diyl)diacetamide 261507-87-3 C7H14N2O3
o-Chlorobenzenesulfonamide o-Chlorobenzenesulfonamide 6961-82-6 C6H6ClNO2S
2-AMINOPHENOL-5-(N,N-DIMETHYL)SULFONAMIDE 2-AMINOPHENOL-5-(N,N-DIMETHYL)SULFONAMIDE 41608-75-7 C8H12N2O3S
2-Cyanoacetamide 2-Cyanoacetamide 107-91-5 C3H4N2O
Propionamide Propionamide 79-05-0 C3H7NO
2'-Chloroacetanilide 2'-Chloroacetanilide 533-17-5 C8H8ClNO
BENZAMIDOXIME HYDROCHLORIDE BENZAMIDOXIME HYDROCHLORIDE 613-92-3 C7H8N2O
2-Nitrobenzenesulfonamide 2-Nitrobenzenesulfonamide 5455-59-4 C6H6N2O4S
p-Aminobenzamide p-Aminobenzamide 2835-68-9 C7H8N2O
Isobutyramide Isobutyramide 563-83-7 C4H9NO
BENZYL 2,2,2-TRICHLOROACETIMIDATE BENZYL 2,2,2-TRICHLOROACETIMIDATE 81927-55-1 C9H8Cl3NO
Caprolactam Caprolactam 105-60-2 C6H11NO
2-Carbomethoxybenzenesulfonamide 2-Carbomethoxybenzenesulfonamide 57683-71-3 C8H9NO4S
N,N-Dimethylacetamide N,N-Dimethylacetamide 127-19-5 C4H9NO
N-Methylformamide N-Methylformamide 123-39-7 C2H5NO
4-Amino-6-chlorobenzene-1,3-disulfonamide 4-Amino-6-chlorobenzene-1,3-disulfonamide 121-30-2 C6H8ClN3O4S2
N-TERT-BUTYLACRYLAMIDE N-TERT-BUTYLACRYLAMIDE 107-58-4 C7H13NO
6-METHYLNICOTINAMIDE 6-METHYLNICOTINAMIDE 6960-22-1 C7H8N2O
N,N-Dimethylsulfamide N,N-Dimethylsulfamide 3984-14-3 C2H8N2O2S
2,3-DIBROMOPROPIONAMIDE 2,3-DIBROMOPROPIONAMIDE 15102-42-8 C3H5Br2NO
2-AMINO-5-METHYLBENZAMIDE 2-AMINO-5-METHYLBENZAMIDE 40545-33-3 C8H10N2O
(2R)-Bornane-10,2-sultam (2R)-Bornane-10,2-sultam 94594-90-8 C10H17NO2S
N-Ethyl-p-toluenesulfonamide N-Ethyl-p-toluenesulfonamide 80-39-7 C9H13NO2S
2-Aminobenzenesulfonamide 2-Aminobenzenesulfonamide 3306-62-5 C6H8N2O2S
Formamide Formamide 75-12-7 CH3NO
2-amino-N,N-dimethylacetamide 2-amino-N,N-dimethylacetamide 1857-19-8 C4H10N2O
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