SESQUITERPENE

Sesquiterpene having three isoprene units is a kind of terpene , whose general formula is CH, most of them are in line with isoprene rule. Sesquiterpene compounds widely distributed, most abundant in Magnoliales, rue mesh, cornales and asterales (asterales) plants. Generally speaking, sesquiterpene presents in volatile oil in the form of oxygen-containing derivativesthe , such as alcohols, ketones and lactones, the main composition of volatile oil in the high-boiling part , have a strong aroma and biological activity, are pharmaceutical, food, cosmetics important raw material for industry.

Sesquiterpene compounds, in terms of the number or type of structure from the point of view of the skeleton are the largest one in terpenoids. Sesquiterpene are classified by the number of  carbon ring on their structure , for example, acyclic, monocyclic, bicyclic, tricyclic and tetracyclic and so on. Also classified according to the size of the ring, such as five, six, seven till eleven membered ring. If it is classified according to containing group in its structure, it is easy to recognize their physicochemical properties and physiological activities, such as sesquiterpene alcohols, aldehydes, lactones and so on.

The following are some common sesquiterpene compound:
(1) Farnesol ,an open-chain sesquiterpene, presents in aromatic plants volatile oil such as lemongrass, orange blossom, rose and others. Farnesol as a colorless oily liquid, is a valuable spice. having insect juvenile hormone activity. Once the amount of the insect juvenile hormone excess, it will inhibit the insect metamorphosis and maturity.
(2)Germacrone, Aka Big geranylflavanone ketone, presents in the volatile oil of Xing'an azalea (rhododendron) leaves, is a ten-member ring monocyclic sesquiterpene. Rhododendron volatile oil has the effect of treating cough, phlegm, asthma and are useful for the treatment of chronic bronchitis, cuckoo ketone ,whose melting point is 56 ~ 57 ℃,is the main component .
(3) Gguaiazulene. a sesquiterpene ingredients, presents in the tribulus plants guaiac volatile oil, volatile oil Geranium.
guaiazulene. a blue needle crystallization,whose melting point is 31 ℃, has anti-inflammatory effect, promoting wound healing. It is one of the main components of  domestic burn ointment.

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Structure Chemical Name CAS MF
Chlorantholide A Chlorantholide A 1372558-33-2 C15H16O3
Alpiniaterpene A Alpiniaterpene A 1448667-05-7 C16H22O4
Shizukanolide C Shizukanolide C 78749-47-0 C15H18O3
Sarcandrolide D Sarcandrolide D 1207185-03-2 C37H42O12
Sugetriol 6,9-diacetate Sugetriol 6,9-diacetate 17928-63-1 C19H28O5
CryptoMeridiol 11-rhaMnoside CryptoMeridiol 11-rhaMnoside 349112-30-7 C21H38O6
EudesM-4(15)-ene-3α,11-diol EudesM-4(15)-ene-3α,11-diol 113773-90-3 C15H26O2
Guajadial B Guajadial B 1414455-03-0 C30H34O5
ChloraMultilide B ChloraMultilide B 1000995-47-0 C39H42O14
4-Hydroxy-1,10-secocadin-5-ene-1,10-dione 4-Hydroxy-1,10-secocadin-5-ene-1,10-dione 226904-40-1 C15H24O3
Tectoroside Tectoroside 124960-89-0 C30H36O12
4'-Hydroxypiptocarphin A 4'-Hydroxypiptocarphin A 103994-39-4 C21H26O10
8α-Hydroxyhirsutinolide 8α-Hydroxyhirsutinolide 1394156-45-6 C15H20O6
9-Oxonerolidol 9-Oxonerolidol 58865-88-6 C15H24O2
Fukinolide Fukinolide 18455-98-6 C22H30O6
(2Z,4E)-3-Methyl-5-[(1S)-1α-hydroxy-2,6-dimethyl-2α,6α-(epoxymethano)-4β-hydroxycyclohexane-1-yl]-2,4-pentadienoic acid (2Z,4E)-3-Methyl-5-[(1S)-1α-hydroxy-2,6-dimethyl-2α,6α-(epoxymethano)-4β-hydroxycyclohexane-1-yl]-2,4-pentadienoic acid 41756-77-8 C15H22O5
Onitin 2'-O-glucoside Onitin 2'-O-glucoside 76947-60-9 C21H30O8
cis-3,4-Dihydroxy-β-ionone cis-3,4-Dihydroxy-β-ionone 875666-39-0 C13H20O3
Euscaphin B Euscaphin B 956869-95-7 C14H26O4
Psidial A Psidial A 1207181-35-8 C30H34O5
4(15),11-Oppositadien-1-ol 4(15),11-Oppositadien-1-ol 70389-96-7 C15H24O
Arteannuin A Arteannuin A 82442-48-6 C13H18O2
1β-Hydroxy-β-eudesMol 1β-Hydroxy-β-eudesMol 83217-89-4 C15H26O2
Norpterosin B Norpterosin B 1226892-20-1 C13H16O2
8α-(2-Methylacryloyloxy)-
1-O-Methylhirsutinolide 13-O-acetate 8α-(2-Methylacryloyloxy)- 1-O-Methylhirsutinolide 13-O-acetate 883872-71-7 C22H28O8
Breyniaionoside A Breyniaionoside A 823182-23-6 C19H32O9
ChloraMultilide D ChloraMultilide D 1000995-49-2 C35H40O11
Stachybotrolide Stachybotrolide 149691-31-6 C23H30O5
Vernolide B Vernolide B 618860-58-5 C23H30O8
4,5-Epoxyartemisinic acid 4,5-Epoxyartemisinic acid 92466-31-4 C15H22O3
10-O-AcetylisocalaMendiol 10-O-AcetylisocalaMendiol 1432064-69-1 C17H28O3
Fuegin Fuegin 6750-10-3 C15H22O4
MegastigM-7-ene-3,5,6,9-tetraol MegastigM-7-ene-3,5,6,9-tetraol 680617-50-9 C13H24O4
Chlorantholide B Chlorantholide B 1372558-34-3 C15H18O3
Psiguadial D Psiguadial D 1402066-95-8 C30H34O5
3-EudesMene-1β,11-diol 3-EudesMene-1β,11-diol 658062-22-7 C15H26O2
8-Epicrepiside E 8-Epicrepiside E 93395-30-3 C21H28O9
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