2,2'-(1,2-Ethenediyldi-4,1-phenylene)bisbenzoxazole

2,2'-(1,2-Ethenediyldi-4,1-phenylene)bisbenzoxazole Basic information
Product Name:2,2'-(1,2-Ethenediyldi-4,1-phenylene)bisbenzoxazole
Synonyms:4,4'-BIS(2-BENZOXAZOLYL)STILBENE;2,2'-(1,2-ETHENEDIYLDI-4,1-PHENYLENE)BISBENZOXAZOLE;2,2'-(vinylenedi-p-phenylene)bisbenzoxazole;2,2’-(1,2-ethenediyldi-4,1-phenylene)bis-benzoxazol;OB-C;Fluorescent Brightener OB-1 C.I. 393;1,2-Bis(4-(benzo[d]oxazol-2-yl)phenyl)ethene;ptical Brightening Agent OB-1
CAS:1533-45-5
MF:C28H18N2O2
MW:414.45
EINECS:216-245-3
Product Categories:Industrial/Fine Chemicals;Building Blocks;Stilbenes;Heterocyclic Building Blocks;Oxazoles;brightener;1533-45-5
Mol File:1533-45-5.mol
2,2'-(1,2-Ethenediyldi-4,1-phenylene)bisbenzoxazole Structure
2,2'-(1,2-Ethenediyldi-4,1-phenylene)bisbenzoxazole Chemical Properties
Melting point >300 °C(lit.)
Boiling point 533.34°C (rough estimate)
density 1.2151 (rough estimate)
vapor pressure 0Pa at 25℃
refractive index 1.5800 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility DMSO (Slightly, Heated)
pka1.45±0.10(Predicted)
form Solid
color Yellow
Water Solubility 10μg/L at 25℃
Stability:Stable. Incompatible with strong oxidizing agents.
InChIKeyORACIQIJMCYPHQ-KTKRTIGZSA-N
LogP5.499 at 25℃
CAS DataBase Reference1533-45-5(CAS DataBase Reference)
EPA Substance Registry SystemBenzoxazole, 2,2'-(1,2-ethenediyldi-4,1-phenylene)bis- (1533-45-5)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39-24/25
WGK Germany 1
HS Code 29349990
MSDS Information
ProviderLanguage
2,2'-(Vinylenedi-p-phenylene)bisbenzoxazole English
SigmaAldrich English
ACROS English
2,2'-(1,2-Ethenediyldi-4,1-phenylene)bisbenzoxazole Usage And Synthesis
Chemical Propertiessolid
Uses4,4′-Bis(2-benzoxazolyl)stilbene (BBS) is suitable for use in the preparation of poly(propylene) (PP) films containing different concentrations of BBS. BBS may be employed as a viscosity-sensitive fluorophore to investigate the curing parameters in fabrication of UV-cured automotive organic protective coatings. BBS may be used in the preparation of polymeric film sensors based on excimer luminescence and responsive to both mechanical and temperature stress, by its dispersion into a thermoplastic aliphatic biodegradable polyester [poly(1,4-butylene succinate).
General Description4,4′-Bis(2-benzoxazolyl)stilbene (BBS) is reported to exhibit consistently high absolute fluorescence quantum yields and a monoexponential lifetime in solutions. The photophysics of BBS dispersed in poly(propylene) (PP) films has been investigated. BBS is reported as a food-grade dye. BBS is also reported as excimer-forming, photoluminescent chromophore.
Flammability and ExplosibilityNotclassified
Properties and Applications

TEST ITEMS

SPECIFICATION

APPEARANCE

BRIGHT YELLOW CRYSTALS POWDER

SHADE

GREENISH

METLING POINT

355-360 ° C

PURITY

98.5% min

FINENESS

300 mesh min

2,2'-(1,2-Ethenediyldi-4,1-phenylene)bisbenzoxazole Preparation Products And Raw materials
Raw materialsDiethyl phosphite
4,4'-Bis(5-methyl-2-benzoxazolyl)stilbene 5-METHYL-2,2'-(1,2-ETHENEDIYLDI-4,1-PHENYLENE)-BISBENZOXAZOLE 2,5-Bis(5-tert-butyl-2-benzoxazolyl)thiophene Fluorescent brightener OB-C Fluorescent Brightener 367 Fluorescent brightener 85 2,2'-(Vinylenedi-p-phenylene)bis[5-tert-butylbenzoxazole] C.I. 482200 FLUORESCENT BRIGHTENER 28 Fluorescent Brightener 28 2-Mercapto-5-methyl-1,3,4-thiadiazole Fluorescent brightener OB-1 aldehyde 2,2'-(1,2-Ethenediyldi-4,1-phenylene)bisbenzoxazole 2,2'-(Vinylenedi-p-phenylene)bis[5-tert-octylbenzoxazole] Benzoxazole Fluorescent whitening agent for plastic Fluorescent brightener OB-P 1,2-Diphenylethylenediamine

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