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| | CIS-DECAHYDRONAPHTHALENE Basic information |
| Product Name: | CIS-DECAHYDRONAPHTHALENE | | Synonyms: | c-Decahydronaphthalene;c-Decalin;cis-Bicyclo[4.4.0]Decane;cis-decahydronaphthalenen;cis-Decahydronapthalene;cis-naphthalen;decahydronaphthalene(cis-);decahydronaphthalene, cis | | CAS: | 493-01-6 | | MF: | C10H18 | | MW: | 138.25 | | EINECS: | 207-770-9 | | Product Categories: | | | Mol File: | 493-01-6.mol |  |
| | CIS-DECAHYDRONAPHTHALENE Chemical Properties |
| Melting point | −43 °C(lit.) | | Boiling point | 193 °C(lit.) | | density | 0.897 g/mL at 25 °C(lit.) | | vapor density | 4.76 (vs air) | | vapor pressure | 42 mm Hg ( 92 °C) | | refractive index | n20/D 1.481(lit.) | | Fp | 137 °F | | storage temp. | Sealed in dry,Room Temperature | | form | clear liquid | | color | Colorless to Almost colorless | | explosive limit | 0.7-4.9%, 100°F | | Water Solubility | 8.92g/L(300 ºC) | | Merck | 14,2846 | | BRN | 1900822 | | Stability: | Stable. Incompatible with oxidizing agents. May form explosive peroxides. Heat and light accelerate peroxide formation. | | CAS DataBase Reference | 493-01-6(CAS DataBase Reference) | | EPA Substance Registry System | cis-Decahydronaphthalene (493-01-6) |
| | CIS-DECAHYDRONAPHTHALENE Usage And Synthesis |
| Chemical Properties | colourless liquid | | Uses | cis-Decahydronaphthalene is used as a quantitation standard in the determination of sesquiterpanes. | | Definition | ChEBI: Decalin is an ortho-fused bicyclic hydrocarbon that is the decahydro- derivative of naphthalene. It has a role as a solvent. | | Purification Methods | Purification methods described for the mixed isomers are applicable here. The individual isomers can be separated by very efficient fractional distillation, followed by fractional crystallisation by partial freezing. The cis-isomer reacts preferentially with AlCl3 and can be removed from the trans-isomer by stirring the mixture with a limited amount of AlCl3 for 48hours at room temperature, filtering and distilling. [Seyer & Walker J Am Chem Soc 60 2125 1938, Baker & Schuetz J Am Chem Soc 69 1250 1949.] A very pure authentic sample is best obtained by synthesis from cis-1,2-bis-chloroethylcyclohexane [Whitesides & Gutowski J Org Chem 41 2882 1976, Beilstein 5 IV 310.] |
| | CIS-DECAHYDRONAPHTHALENE Preparation Products And Raw materials |
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