2-(TRIMETHYLSILYL)ETHANESULFONAMIDE, 90%

2-(TRIMETHYLSILYL)ETHANESULFONAMIDE, 90% Basic information

Product Name:	2-(TRIMETHYLSILYL)ETHANESULFONAMIDE, 90%
Synonyms:	2-Trimethylsilylethanesulfonyl amide;beta-(Trimethylsilyl)ethanesulfonamide;2-(TRIMETHYLSILYL)ETHANESULFONAMIDE, 90%;Ethanesulfonamide, 2-(trimethylsilyl)-;2-(Trimethylsilyl)ethanesulfonamide 90%;SES-NH2;2-(trimethylsilyl)ethane-1-sulfonamide;2-(TRIMETHYLSILYL)ETHANESULFONAMIDE, 90% ISO 9001：2015 REACH
CAS:	125486-96-6
MF:	C5H15NO2SSi
MW:	181.33
EINECS:
Product Categories:	Building Blocks;Chemical Synthesis;Organic Building Blocks;Sulfonamides/Sulfinamides;Sulfur Compounds
Mol File:	125486-96-6.mol

2-(TRIMETHYLSILYL)ETHANESULFONAMIDE, 90% Chemical Properties

Melting point	81-87 °C
Boiling point	253.0±42.0 °C(Predicted)
density	1.057±0.06 g/cm3(Predicted)
solubility	Soluble in benzene, chloroform, dichloromethane, ether, methanol and toluene.
pka	10.99±0.60(Predicted)

Safety Information

MSDS Information

2-(TRIMETHYLSILYL)ETHANESULFONAMIDE, 90% Usage And Synthesis

Uses	2-Trimethylsilylethanesulfonyl amide is a useful reagent for introduction of a SES-protected nitrogen functionality, which can be cleaved with fluoride ion.
Uses	2-(Trimethylsilyl)ethanesulfonamide is a source of nucleophilic nitrogen that can react in manifold ways with electrophiles prior to removal of SES group with fluoride ion. It participates in the following reactions: Preparation of N-Sulfonylimines, Mitsunobu Reactions, Azaglycosylation Chemistry, Preparation of Sulfodiimides, Preparation of (N-SES-imino)phenyliodinane etc.
Preparation	2-(Trimethylsilyl)ethanesulfonamide is prepared by reaction of 2-(trimethylsilyl) ethanesulfonyl chloride (accessible from the commercially available sodium salt of the corresponding sulfonic acid or starting from vinyl trimethylsilane) with gaseous ammonia (eq 1).

2-(TRIMETHYLSILYL)ETHANESULFONAMIDE, 90% Preparation Products And Raw materials

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