4-Chlorobiphenyl

4-Chlorobiphenyl Basic information
Product Name:4-Chlorobiphenyl
Synonyms:4-Chlorobiphenyl, 4-PCB;4-Chlorobiphenyl 50mg [2051-62-9];1,1'-Biphenyl-4-yl Chloride;4-Biphenylyl Chloride;NSC 37066;1,1'-Biphenyl,4-chloro-;1’-Biphenyl,4-chloro-1;1-Chloro-4-phenylbenzene
CAS:2051-62-9
MF:C12H9Cl
MW:188.65
EINECS:218-127-7
Product Categories:Aromatics
Mol File:2051-62-9.mol
4-Chlorobiphenyl Structure
4-Chlorobiphenyl Chemical Properties
Melting point 32 °C(lit.)
Boiling point 130°C/1mm
density 1.1320 (estimate)
refractive index 1.5830 (estimate)
storage temp. Refrigerator
solubility Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form Solid
color White to Off-White
Water Solubility <0.1 g/100 mL at 22 ºC
CAS DataBase Reference2051-62-9(CAS DataBase Reference)
NIST Chemistry Reference1,1'-Biphenyl, 4-chloro-(2051-62-9)
EPA Substance Registry System4-Chlorobiphenyl (2051-62-9)
Safety Information
Hazard Codes N,Xi
Risk Statements 33-50/53-36/37/38
Safety Statements 35-60-61-36-26
RIDADR UN 3432 9/PG 2
WGK Germany 3
RTECS DV2080000
Hazard Note Irritant
HazardClass 9
PackingGroup III
HS Code 2903998090
Toxicitymammal (species unspecified),LDLo,oral,3500mg/kg (3500mg/kg),Journal of Industrial Hygiene. Vol. 13, Pg. 87, 1931.
MSDS Information
ProviderLanguage
4-Chloro-1,1'-biphenyl English
4-Chlorobiphenyl Usage And Synthesis
Chemical PropertiesWhite Solid
Uses4-Chloro-1,1’-biphenyl (cas# 2051-62-9) is a compound useful in organic synthesis.
DefinitionChEBI: A monochlorobiphenyl carrying a chloro substituent at position 4.
Synthesis Reference(s)Synthetic Communications, 11, p. 513, 1981 DOI: 10.1080/00397918108063618
Tetrahedron Letters, 30, p. 963, 1989
General DescriptionColorless crystals or shiny off-white flakes.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileSimple aromatic halogenated organic compounds, such as 4-Chlorobiphenyl, are very unreactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group may be incompatible with strong oxidizing and reducing agents. Also, they may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
Fire HazardFlash point data for 4-Chlorobiphenyl are not available. 4-Chlorobiphenyl is probably combustible.
2,4,5-TRICHLOROBIPHENYL 2,7-Dichlorofluorene 2,4,7-TRICHLOROFLUORENE, 95 3,4-Dichlorobiphenyl Bifendate Bifenthrin 2,4-DICHLOROBIPHENYL 3,3',4,4'-TETRACHLOROBIPHENYL 2,2',4,4',5,5'-HEXACHLOROBIPHENYL Biphenyl trans-Bifenthtin 2,3,3',4,4',5-HEXACHLOROBIPHENYL Difluorochloromethane Bifonazole p-Terphenyl 4,4'-DICHLOROBIPHENYL 2,4,4'-TRICHLOROBIPHENYL 4-Chlorobiphenyl

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