ChemicalBook Product Catalog Inorganic chemistry Inorganic salts Metal halide and Halogen salt Metal chlorides and salt Ytterbium(III) chloride

Ytterbium(III) chloride

Ytterbium(III) chloride Basic information
Product Name:Ytterbium(III) chloride
Synonyms:YbCl3;Yiterbium chloride;Ytterbium chloride (YbCl3);ytterbiumchloride(ybcl3);ytterbiumtrichloride;YTTERBIUM CHLORIDE;YTTERBIUM(III) CHLORIDE;YTTERBIUM(III) CHLORIDE, ANHYDROUS, BEAD S, -10 MESH, 99.99%
CAS:10361-91-8
MF:Cl3Yb
MW:279.4
EINECS:233-800-5
Product Categories:Other Metal;Catalysis and Inorganic Chemistry;Chemical Synthesis;Crystal Grade Inorganics;Salts;Ytterbium Salts;YtterbiumMetal and Ceramic Science;metal halide
Mol File:10361-91-8.mol
Ytterbium(III) chloride Structure
Ytterbium(III) chloride Chemical Properties
Melting point 875 °C(lit.)
density 1.48^3^0
storage temp. Inert atmosphere,Room Temperature
form powder
color Off-white
Water Solubility Soluble in water.
Sensitive Hygroscopic
Merck 14,10105
Stability:hygroscopic
CAS DataBase Reference10361-91-8(CAS DataBase Reference)
EPA Substance Registry SystemYtterbium chloride (YbCl3) (10361-91-8)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 2
RTECS ZG2100000
TSCA Yes
HS Code 28273985
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Ytterbium(III) chloride Usage And Synthesis
Chemical PropertiesYtterbium(III) chloride (YbCl3) is a white powdery monoclinic crystals. It reacts with NiCl2 to form a very effective catalyst for the reductive dehalogenation of aryl halides. It is used in catalysis and as a NMR shift reagent in biology. It can also be used to track the digestion process in all animals.
Ytterbium(III) Chloride is a typical starting material for the production of Yb metal. It is also used a a source of Yb3+ ion for doping into laser host materials.
UsesUsed as laboratory reagent, optical glasses, structural ceramics, catalysts, electrical components and photo-optical material. Applied with NiCl2 to form a very effective catalyst for the reductive dehalogenation of aryl halides. Ytterbium(III) chloride is a powerful catalyst for the formation of acetals using trimethyl orthoformate and also used to track digestion in animals.
DefinitionChEBI: Ytterbium(III) chloride is the trichloride salt of ytterbium(III). It has a role as a NMR shift reagent. It contains a ytterbium(3+).
PreparationAnhydrous ytterbium(III) chloride can be produced by the ammonium chloride route. In the first step, ytterbium oxide is heated with ammonium chloride to produce the ammonium salt of the pentachloride:
Yb2O3 + 10NH4Cl → 2(NH4)2YbCl5 + 6H2O + 6NH3
In the second step, the ammonium chloride salt is converted to the trichlorides by heating in a vacuum at 350-400°C:
(NH4)2YbCl5 → YbCl3 + 2HCl + 2NH3
Safety ProfilePoison by intraperitoneal route. Mtldly toxic by ingestion. An experimental teratogen. A skin and eye irritant. When heated to SYN: YTTERBIUM TRICHLORIDE decomposition it emits toxic fumes of Cl-. See also YITERBIUM, RARE EARTHS, and CHLORIDES.
Ytterbium(III) chloride Preparation Products And Raw materials
Raw materialsYTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE-->Hydrochloric acid-->Chlorine
Preparation ProductsChlorotrimethylsilane
YTTERBIUM OXALATE YTTERBIUM OXIDE YTTERBIUM YTTERBIUM(III) OXALATE YTTERBIUM NITRATE YTTERBIUM HYDROXIDE YTTERBIUM CARBONATE YTTERBIUM SULFATE YTTERBIUM FLUORIDE YTTERBIUM CARBONATE YTTERBIUM(III) ACETATE HYDRATE YTTERBIUM SULFATE YTTERBIUM HYDRIDE YTTERBIUM(III) CHLORIDE HYDRATE Ytterbium(Ⅲ)chloride hexahydrate YTTERBIUM CHLORIDE, ANHYDROUS, 99.9% Ytterbium(III) chloride hexahydrate Ytterbium(III) chloride
Email:[email protected] [email protected]
Copyright © 2024 Mywellwork.com All rights reserved.