2-(Perfluorobutyl)ethyl acrylate

2-(Perfluorobutyl)ethyl acrylate Basic information
Product Name:2-(Perfluorobutyl)ethyl acrylate
Synonyms:1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with TBC);1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with MEHQ);Perfluorobutylethyl acrylate;2-Propenoic acid 3,3,4,4,5,5,6,6,6-nonafluorohexyl ester;3,3,4,4,5,5,6,6,6-Nonafluorohexyl acrylate;3,3,4,4,5,5,6,6,6-Nonafluorohexylacrylate;Acrylic acid 2-(nonafluorobutyl)ethyl ester;Acrylic acid 3,3,4,4,5,5,6,6,6-nonafluorohexyl ester
CAS:52591-27-2
MF:C9H7F9O2
MW:318.14
EINECS:
Product Categories:Halogenated Heterocycles ,Isoquinolines ,Quinolines ,Quinaldines
Mol File:52591-27-2.mol
2-(Perfluorobutyl)ethyl acrylate Structure
2-(Perfluorobutyl)ethyl acrylate Chemical Properties
Boiling point 164 °C
density 1.414
refractive index 1.310
Fp 52 °C
solubility Chloroform (Soluble), Ethyl Acetate (Slightly)
form clear liquid
Specific Gravity1.440
color Colorless to Light yellow
EPA Substance Registry System1,1,2,2-Tetrahydroperfluorohexyl acrylate (52591-27-2)
Safety Information
RIDADR UN 3272 3/PG III
HazardClass 3
PackingGroup III
HS Code 2916120090
MSDS Information
2-(Perfluorobutyl)ethyl acrylate Usage And Synthesis
Uses2-(Perfluorobutyl)ethyl Acrylate can be used as an acrylic resin surface modifier with high water repellency and oil repellency for coating agents. It can also be used in a super concentrated emulsion method to prepare a solid sheet polycarboxylic acid water reducing agent.
SynthesisSynthesis_52591-27-2
1H,1H,2H,2H-nonafluoro-1-hexanol (52.8 g) as fluoro alcohol and triethylamine (50 g) were dissolved in 500 ml of tetrahydrofuran. A solution of 18.1 g of acryloyl chloride as acid chloride in 100 ml of tetrahydrofuran was dropped in this solution over 2 hours while the mixture was being cooled in ice and stirred. After the completion of the dropping, the resulting white precipitate was filtrated and tetrahydrofuran and triethylamine were removed from the filtrate using a rotary evaporator. NMR measurement revealed that the resulting compound was 1H,1H,2H,2H-nonafluorohexyl acrylate.
2-(Perfluorobutyl)ethyl acrylate Preparation Products And Raw materials
1H,1H,2H,2H-Perfluorohexan-1-ol URETHANE ACRYLATE 2-(Perfluorobutyl)ethyl acrylate,2-(PERFLUOROBUTYL)ETHYL ACRYLATE 97% Ethanol 4,4,5,5,6,6,6-HEPTAFLUOROHEXAN-1-OL Methyl propiolate 2-(Perfluorobutyl)ethyl methacrylate Ethylparaben Perfluoroalkylethyl acrylate ISOXADIFEN-ETHYL 6-Benzylaminopurine Ethyl acetate Acrylic acid Polyacrylate rubber Ethyl acrylate Methyl acrylate 2-(Perfluorobutyl)ethyl acrylate Ethyl cyanoacetate

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