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Ruthenium(III) chloride hydrate(1:x)

Ruthenium(III) chloride hydrate(1:x) Basic information
Product Name:Ruthenium(III) chloride hydrate(1:x)
Synonyms:RutheniuM(III) chloride hydrate ReagentPlus(R);RUTHENIUM(III) CHLORIDE HYDRATE14898-67-0;Ruthenium(III)-chlorid-hydrat;Active oxidative aluminum;RUTHENIUM(III) CHLORIDE HYDRATE: 99.9% (36%RU);RUTHENIUM(III) CHLORIDE HYDRATE, (36% RU): 99.9%;Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min;Ruthenium(III) chloride hydrate, Premion(R), 99.99% (metals basis)
CAS:14898-67-0
MF:Cl3H2ORu
MW:225.44
EINECS:604-667-4
Product Categories:Catalysis and Inorganic Chemistry;Ru CatalystsMetal and Ceramic Science;Ruthenium;Ruthenium Salts;Salts;Hematology StainsCatalysis and Inorganic Chemistry;Hematology and Histology;Ru Catalysts;metal halide;Catalysis and Inorganic Chemistry;Chemical Synthesis;Materials Science;Metal and Ceramic Science;chemical reaction,pharm,electronic,materials;straight chain compounds;Ru Catalysts;Ruthenium Salts;Ru;14898-67-0
Mol File:14898-67-0.mol
Ruthenium(III) chloride hydrate(1:x) Structure
Ruthenium(III) chloride hydrate(1:x) Chemical Properties
Melting point >300°C
density 3.11 g/cm3
storage temp. Store at +5°C to +30°C.
solubility Water (Slightly)
form Powder
color Dark brown to black
PH<2 (H2O, 20℃)Aqueous solution
Water Solubility soluble
Sensitive Hygroscopic
Merck 14,8302
Stability:hygroscopic
CAS DataBase Reference14898-67-0(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 34-52/53-22
Safety Statements 26-36/37/39-45-61
RIDADR UN 3260 8/PG 2
WGK Germany 2
RTECS VM2650000
TSCA Yes
HS Code 2843 90 90
HazardClass 8
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Ruthenium(III) chloride hydrate(1:x) Usage And Synthesis
Chemical Propertiesdark brown to black powder
UsesCatalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.1
UsesOxidation.Ruthenium(III) chloride hydrate is used as a catalyst for alkyne functionalization and oxidation reactions. It is used as key raw materials for the preparation of various ruthenium-based catalysts, including Grubbs? catalysts. It is utilized in the preparation of nanoparticulate ruthenium-aluminum oxyhydroxide catalyst, which is efficient for dehydrogenation of alcohols to the corresponding aldehydes. It is also involved in the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.
General Descriptionsoluble form
Purification MethodsDissolve the salt in H2O, filter and concentrate to crystallisation in the absence of air to avoid oxidation. Evaporate the solution in a stream of HCl gas while being heated just below its boiling point until a syrup is formed and finally to dryness at 80-100o and dried in a vacuum over H2SO4. When heated at 700o in the presence of Cl2 the insoluble -form is obtained [Grube in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1598 1965, Carlsen et al. J Org Chem 46 3936 1981].
Ruthenium(III) chloride hydrate(1:x) Preparation Products And Raw materials
Preparation Products3-BROMO-6-METHYL-2-OXO-1(2H)-PYRAZINEACETIC ACID ETHYL ESTER-->ethyl 2-(3,4-dihydro-6-methyl-2,3-dioxopyrazin-1(2H)-yl)acetate-->Tris(triphenylphosphine)ruthenium(II) chloride-->Dichloro(cycloocta-1,5-diene)ruthenium(II)-->TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE
Ruthenium(III) chloride Methylene Chloride Tributyltin chloride Trichlorine nitride Benzyltriethylammonium chloride RUTHENIUM RED Calcium chloride Titanous chloride Choline chloride Ruthenium Ammonium chloride Chromium(III) chloride RUODIUM (Ⅲ) CHLORIDE HYDRATE Polyvinyl chloride Boron trichloride Potassium chloride Ruthenium(III) chloride hydrate(1:x) 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile Ruthenium Chloride Hydrate Ruthenium Trichloride Hydrate
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