meso-Tetra(4-carboxyphenyl)porphine

meso-Tetra(4-carboxyphenyl)porphine Basic information
Product Name:meso-Tetra(4-carboxyphenyl)porphine
Synonyms:TETRACARBOXYPHENYLPORPHYRIN;TETRAKIS(4-CARBOXYPHENYL)PORPHINE;RARECHEM AS SA 0048;NICKEL IONOPHORE II;MESO-TETRA(4-CARBOXYPHENYL)PORPHINE;MESO-TETRAPHENYLPORPHINE-4,4',4'',4'''-TETRACARBOXYLIC ACID;5,10,15,20-TETRAKIS-(4-CARBOXYPHENYL)-21,23H-PORPHYRIN;4,4',4'',4'''-(21H,23H-PORPHINE-5,10,15,20-TETRAYL)TETRAKIS(BENZOIC ACID)
CAS:14609-54-2
MF:C48H30N4O8
MW:790.77
EINECS:
Product Categories:porphine (porphyrin) ligand;Porphyrins;Synthetic Porphyrins;Analytical Chemistry;Biochemistry;Chelating Reagents;Ligands for Pharmaceutical Research;Magnetic Resonance Imaging (Chelating Reagents);Porphines
Mol File:14609-54-2.mol
meso-Tetra(4-carboxyphenyl)porphine Structure
meso-Tetra(4-carboxyphenyl)porphine Chemical Properties
Melting point >300 °C
density 1.462±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form Powder
color purple
Safety Information
Safety Statements 22-24/25
WGK Germany 3
RTECS DH6488300
HS Code 2933998090
Hazardous Substances Data14609-54-2(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
meso-Tetra(4-carboxyphenyl)porphine Usage And Synthesis
UsesNickel ionophore II is a selective sensor for Ni(II) ions.
Usesmeso-Tetra(4-carboxyphenyl)porphine can be used as organic synthesis intermediates and pharmaceutical intermediates, mainly used in laboratory research and development processes and chemical production processes.
Uses4,4′,4′′, 4′′′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzoic acid) (H2TCPP) can be used to fabricate three dimensional Ru polymer complex. It can be grafted on SiO2/Nb2O5 substrate and subsequently metallized to investigate catalytic oxidation of hydrazine.
General DescriptionVisit our Sensor Applications portal to learn more.
SynthesisSynthesis_14609-54-2
General procedures for the synthesis of porphyrins 1-5A mixture of the appropriate aromatic aldehyde (0.72 mmol) andpyrrole (0.72 mmol) in DMF (15 mL) was placed into a 50 mL threeneckedflask. The mixture was flushed with nitrogen gas for a coupleof minutes and then heated to 100 C for 10 min. P-toluene sulphonicacid (0.72 mmol, dissolved in DMF) was then added to the reactionmixture. The colorless mixture turned red over the next couple of minutesthen heated at 150 C for 1 h. The reaction mixture was thencooled and poured over ice with stirring for 15 min the residue wascollected, dried under vacuum and purified by column chromatographyusing chloroform/hexane (1.5/1) as eluent).
meso-Tetra(4-carboxyphenyl)porphine Preparation Products And Raw materials
Raw materialsMESO-TETRA(4-CARBOXYPHENYL)PORPHINE TETRAMETHYL ESTER-->4-Formylbenzoic acid-->Pyrrole
ACRIFLAVINE Carboxy styrene-butadiene latex PORPHINE ETHYL-BIS-(SODIUMTETRAZOYLAZO)ACETATE Ethyl 2-(Chlorosulfonyl)acetate AQUANTRAAL 5-(4-Carboxyphenyl)-10,15,20-triphenyl-21H,23H-porphine Ascoric Acid palladium-meso-tetra(4-carboxyphenyl)porphine FE(III) MESO-TETRA(4-CARBOXYPHENYL)PORPHINE CHLORIDE (4,4,4,4-(21H,23H-PORPHINE-5,10,15,20-TETRAYL)TETRAKIS(BENZOIC ACID) IRON) TPP 5,10,15,20-TETRA-P-TOLYL-21H,23H-PORPHINE 5,15-DIPHENYL-21H,23H-PORPHINE CU(II) MESO-TETRA(4-CARBOXYPHENYL)PORPHINE TPP meso-Tetra(4-carboxyphenyl)porphine MESO-TETRA(PARA-CARBOXYPHENYL)PORPHINE BENZOICACID

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