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Zirconium fluoride

Zirconium fluoride Basic information
Product Name:Zirconium fluoride
Synonyms:ZirconiuM(IV) fluoride, low hafniuM, 99%, Hf <0.1%;(beta-4)-zirconiumfluoride(zrf4;Zirconium(IV) Fluoride, Low Hafnium, Hf <0.1%;ZirconiuM(IV) fluoride 99.9% trace Metals basis;Zirconium fluoride, Zirconium(IV) fluoride;Zirconium(2+) fluoride (1:2);(T-4)-Zirconiumfluoride;Zirconium fluoride (ZrF4), (T-4)-
CAS:7783-64-4
MF:F4Zr
MW:167.22
EINECS:232-018-1
Product Categories:Catalysis and Inorganic Chemistry;Chemical Synthesis;Crystal Grade Inorganics;Materials Science;Metal and Ceramic Science;Zirconium;Catalysis and Inorganic Chemistry;Chemical Synthesis;Crystal Grade Inorganics;Salts;Zirconium Salts;ZirconiumMetal and Ceramic Science;metal halide;Zirconium Salts;Inorganics
Mol File:7783-64-4.mol
Zirconium fluoride Structure
Zirconium fluoride Chemical Properties
Melting point 640 °C
Boiling point 905 °C
density 4,43 g/cm3
refractive index 1.59
solubility 1.388 g/100 mL
form Powder
Specific Gravity4.43
color White
Water Solubility 1.388 g/100 mL
Sensitive Moisture Sensitive
Merck 14,10175
Exposure limitsACGIH: TWA 5 mg/m3; TWA 2.5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; IDLH 250 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3
CAS DataBase Reference7783-64-4(CAS DataBase Reference)
NIST Chemistry ReferenceZirconium tetrafluoride(7783-64-4)
EPA Substance Registry SystemZirconium fluoride (ZrF4), (T-4)- (7783-64-4)
Safety Information
Hazard Codes C,Xi
Risk Statements 34-36/37/38
Safety Statements 26-27-28-36/37/39-45
RIDADR UN 3260 8/PG 2
WGK Germany 3
RTECS ZH7875000
Hazard Note Corrosive
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 28261990
MSDS Information
ProviderLanguage
Zirconium tetrafluoride English
SigmaAldrich English
ACROS English
ALFA English
Zirconium fluoride Usage And Synthesis
Chemical PropertiesWhite powder. Slightly soluble in water and hydrogen fluoride.
UsesZirconium tetrafluoride is used in some fluoridebased glasses. These glasses are the first chemically and mechanically stable bulk glasses to have continuous high transparency from the near uv to the mid-ir (0.3–6 μm).
UsesZirconium fluoride is used as a zirconium source in oxygen-sensitive applications such as metal production.
UsesComponent of molten salts for nuclear reactors.
HazardStrong irritant. TLV: 2.5 mg(F)/m3.
Safety ProfilePoison by intravenous route. When heated to decomposition it emits toxic fumes of F-. See also ZIRCONIUM COMPOUNDS and FLUORIDES.
Zirconium fluoride Preparation Products And Raw materials
Zirconium tetrachloride Ammonium hydrogen difluoride Sulfur tetrafluoride SODIUM ZIRCONIUM FLUORIDE Zirconium dioxide Boron trifluoride sodium fluoride Titanium tetrafluoride Silicon Tetrafluoride Uranium tetrafluoride Aluminum fluoride Zirconium sulphate Zirconium fluoride FLUORIDE STANDARD Hydrogen fluoride Tetrabutylammonium fluoride Zirconium Boride Sodium fluoride
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