Sodium hydrogen difluoride

Sodium hydrogen difluoride Basic information
Product Name:Sodium hydrogen difluoride
Synonyms:Sodium hydrogen fluoride Sodium bifluoride;Sodium hydrogen difl;Sodium bifluoride: (Sodium hydrogen fluoride);sodium bifluoride sodium hydrogen difluoride;Sodium hydrogen fluoride, 97% (metals basis);sodium acid fluride;SODIUMBIFLUORIDE,TECHNICAL(BULK;Natriumhydrogenfluorid
CAS:1333-83-1
MF:F2HNa
MW:61.99
EINECS:215-608-3
Product Categories:Inorganics
Mol File:1333-83-1.mol
Sodium hydrogen difluoride Structure
Sodium hydrogen difluoride Chemical Properties
Melting point >68 °C (dec.)
Boiling point 270℃[at 101 325 Pa]
density 2.08
vapor pressure 0.01Pa at 20℃
form pellets
Water Solubility g/100g solution in H2O: 3.7 (20°C), 16.4 (80°C) [KIR78]
Merck 13,8656
LogP1.26 at 20℃
CAS DataBase Reference1333-83-1(CAS DataBase Reference)
EPA Substance Registry SystemSodium bifluoride (1333-83-1)
Safety Information
Hazard Codes T,C
Risk Statements 25-34
Safety Statements 22-26-37-45
RIDADR UN 2439 8/PG 2
WGK Germany 1
RTECS WB0350010
HazardClass 8
PackingGroup II
HS Code 2826199090
Hazardous Substances Data1333-83-1(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
Sodium hydrogen difluoride Usage And Synthesis
Chemical PropertiesWhite, crystalline powder.Sol- uble in water; decomposes on heating.
UsesAs a "sour" in laundering.
UsesStarting material for solid state preparation of Na3MnF6 for further high pressure structural determination studies.
General DescriptionSodium bifluoride is a white crystalline solid. Sodium hydrogen difluoride is soluble in water. Sodium hydrogen difluoride is corrosive to tissue. Sodium hydrogen difluoride is used as a preservative for anatomical and zoological specimens, in metal plating and for many other uses.
Air & Water ReactionsWater soluble. Reacts with water liberating heat and forming a corrosive solution. The reaction is not violent.
Reactivity ProfileAcidic salts, such as SODIUM BIFLUORIDE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
HazardHighly toxic, strong irritant to tissue.
Health HazardINHALATION OF DUST: Irritating and possibly corrosive to mucous membranes. EYES: Irritating. INGESTION: Salty or soapy taste, salivation, nausea, burning or crampy abdominal pain, vomiting, diarrhea, muscle weakness, tremors. Rare: transient epileptiform convulsions, followed by CNS depression. Shock.
Fire HazardNon-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
Flammability and ExplosibilityNonflammable
Safety ProfileThis material is very toxic to humans by ingestion; between 1 teaspoonful and 1 ounce may be fatal. Inhalation of dust may cause irritation to respiratory tract. Skin contact may result in irritation and ulceration; eye contact may cause burns. To fight fire, use water, foam, CO2, dry chemicals. When heated to decomposition it emits toxic fumes of Fand Na2O. See also FLUORIDES and HYDROFLUORIC ACID.
Sodium hydrogen difluoride Preparation Products And Raw materials
Raw materialsSodium hydroxide-->Sodium carbonate-->Hydrogen fluoride-->Congo red paper-->(2S)-1-(3-Acetylthio-2-methyl-1-oxopropyl)-L-proline
Hydrogen Sulfide Sodium benzoate Sodium hydride Sodium acetate Hydrogen peroxide Sodium sulfate Sodium chloride Diclofenac sodium HYDROGEN CYANIDE Sodium citrate Sodium bicarbonate Hydrogen Sodium hydroxide Hydrogen fluoride Sodium fluoride Sodium chlorite Potassium hydrogen fluoride Pyridine hydrofluoride

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