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| | Tin(iv) Fluoride Basic information |
| | Tin(iv) Fluoride Chemical Properties |
| Melting point | 705°C (subl.) | | Boiling point | 705°C | | density | 4,78 g/cm3 | | form | Powder | | color | white | | Specific Gravity | 4.78 | | Water Solubility | hydrolyzes in H2O [MER06] | | Sensitive | Moisture Sensitive | | Merck | 14,8776 | | Exposure limits | ACGIH: TWA 2 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 2 mg/m3 | | CAS DataBase Reference | 7783-62-2(CAS DataBase Reference) |
| Hazard Codes | Xn,C | | Risk Statements | 20/21/22 | | Safety Statements | 26-27-36-36/39 | | RIDADR | UN2923 | | WGK Germany | 3 | | Hazard Note | Corrosive | | HazardClass | 8 | | PackingGroup | II | | HS Code | 2826199090 |
| | Tin(iv) Fluoride Usage And Synthesis |
| Chemical Properties | Stannic Fluoride or tin(iv) fluoride, is an inorganic tin fluoride compound, and generally a off-white powder. It is hygroscopic and has a melting point of 700 C or higher, well above the melting points of other tin(iv) halides. | | Uses | Friedel-Crafts catalyst. | | Uses | It is used as Friedel-Crafts catalyst. | | Preparation | Stannic fluoride can be prepared from the reaction of fluorine, chlorine trifluoride, or bromine trifluoride with tin(II) or tin(IV) compounds. It acts as a Lewis acid to form many complexes. It is used in the manufacture of glasses. | | Reactions | Stannic fluoride combines with ammonia and other bases, and also with alkali and other fluorides to form stannifluorides of the type M2SnF6. Stannic fluoride forms with ammonia at 43° C. the white solid SnF4.NH3, which can be heated to 400° C. with loss of very little ammonia; the compound SnF4.2NH3 is formed when stannic fluoride and ammonia are heated in a sealed tube at 120°-130° C. Both compounds dissolve in water, but their solutions gradually decompose. Aniline, pyridine, and quinoline also form additive compounds with stannic fluoride. |
| | Tin(iv) Fluoride Preparation Products And Raw materials |
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