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Dibenzyl dicarbonate

Dibenzyl dicarbonate Basic information
Product Name:Dibenzyl dicarbonate
Synonyms:DIBENZYL PYROCARBONATE;DIBENZYL OXYDIFORMATE;DIBENZYL DICARBONATE;PYROCARBONIC ACID DIBENZYL ESTER;Z2O;Dibenzyl dicarbonate 97%;Dibenzyl pyrocarbonate, Z2O;Dibenzyl Pyrocarbonate Pyrocarbonic Acid Dibenzyl Ester
CAS:31139-36-3
MF:C16H14O5
MW:286.28
EINECS:
Product Categories:Biochemistry;Peptide Synthesis;Protection & Derivatization Reagents (for Synthesis);Protective Reagents (Peptide Synthesis);Synthetic Organic Chemistry
Mol File:31139-36-3.mol
Dibenzyl dicarbonate Structure
Dibenzyl dicarbonate Chemical Properties
Melting point 29-32 °C (lit.)
Boiling point 388.65°C (rough estimate)
density 1.17 g/mL at 25 °C (lit.)
refractive index 1.5000 (estimate)
Fp >230 °F
storage temp. -20°C
form powder to crystal
color White to Almost white
BRN 4324796
CAS DataBase Reference31139-36-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
F 4.4-10-21
HS Code 29209090
MSDS Information
ProviderLanguage
SigmaAldrich English
Dibenzyl dicarbonate Usage And Synthesis
UsesDibenzyl Dicarbonate is a chemical reagent used in the chemical modification of histidine residues in horseradish peroxidase.
Synthesis Reference(s)Tetrahedron Letters, 27, p. 5375, 1986 DOI: 10.1016/S0040-4039(00)85214-4
Dibenzyl dicarbonate Preparation Products And Raw materials
Preparation ProductsBENZYL N-(3-HYDROXYPROPYL)CARBAMATE-->Benzyl N-[4-(cyanomethyl)phenyl]carbamate-->TERT-BUTYL-(2S,4R)-N'-(BENZYLOXYCARBONYL)-N'-(BENZYLOXYCARBONYL)-4-HYDROXYORNITHINATE
Dicarbonate Trimethoprim 4-Methoxybenzylchloride Dibenzyl phosphate Ethylene carbonate Diphenyl carbonate Tris(trimethylsilyl)phosphate N-Carbobenzyloxyglycine Levofloxacin Methylate DIBENZYL CARBONATE formic anhydride Polycarbonate BUTYL OLEATE Methyl acrylate Propylene carbonate Dimethyl carbonate Vinylene carbonate Dimethyl succinate
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