Silver oxide

Silver oxide Basic information
Physical Properties Uses Preparation
Product Name:Silver oxide
Synonyms:SILVER (II) OXIDE;SILVER (II) OXIDE, TECHNICALSILVER (II) OXIDE, TECHNICALSILVER (II) OXIDE, TECHNICAL;silveroxide(ago);Argentic oxide;Silver suboxide;Silver(II) oxide, 85.5-88.0% Ag;SILVER (II) OXIDE TECHNICAL;Silver(II)oxide(99.9%-Ag)
CAS:1301-96-8
MF:AgO
MW:123.87
EINECS:215-098-2
Product Categories:metal oxide
Mol File:1301-96-8.mol
Silver oxide Structure
Silver oxide Chemical Properties
Melting point 100 °C
density 7.483 g/mL at 25 °C
form Powder
color Gray to black
Specific Gravity7.483
Water Solubility INSOLUBLE
Sensitive Moisture & Light Sensitive
Merck 14,8522
CAS DataBase Reference1301-96-8(CAS DataBase Reference)
EPA Substance Registry SystemSilver(II) oxide (1301-96-8)
Safety Information
Hazard Codes O,Xi,C
Risk Statements 8-36/37/38-34
Safety Statements 26-45-36/37/39-17
RIDADR UN 1479 5.1/PG 2
WGK Germany 3
TSCA Yes
HazardClass 5.1
PackingGroup II
HS Code 28432900
MSDS Information
ProviderLanguage
Silver(II) oxide English
ACROS English
SigmaAldrich English
ALFA English
Silver oxide Usage And Synthesis
Physical PropertiesGray monoclinic or cubic crystals or powder; diamagnetic; semiconductor; density 7.48 g/cm3; decomposes to its elements above 100°C; insoluble in water (solubility 27 mg/L at 25°C); soluble in alkalis; decomposes in ammonia solution evolving nitrogen; dissolves in dilute acids with decomposition evolving oxygen; forms a brown solution in concentrated nitric acid, and forms intense green coloration in concentrated sulfuric acid.
UsesSilver(II) oxide is used to make silver oxide-zinc alkali batteries. Also, it is an oxidizing agent.
PreparationSilver(II) oxide is prepared by reacting silver nitrate with potassium persulfate in the presence of a base.
Chemical Propertiesgrey to black powder
UsesIn the manufacture of silver oxide-zinc alkali batteries.
UsesSilver(II) oxide is used to make silver oxide-zinc alkali batteries. It is also used as a reagent in laboratory reactions and forms transition metal-carbene complexes. It is also used as a catalyst to prepare silver metal. It acts as an effective carbon dioxide scrubber and used in nuclear submarines, the international space station and space shuttles. Further, it is used in the manufacture of filters for gas sensors and in some infection-resistant surgical fabric materials and fibrous textile articles. In addition to this, it is used in concrete and in some swimming pools to protect the water from undesired microbes.
Purification MethodsSilver (II) oxide [1301-96-8] M 123.9, m > 1 0 0o(dec), 7.22. It is soluble in 40,000 parts of H2O, and should be protected from light. Stir it with an alkaline solution of potassium peroxysulfate (K2S2O8) at 85-90o. The black AgO is collected, washed free from sulfate with H2O made slightly alkaline and dried in air in the dark. [Hammer & Kleinberg Inorg Synth IV 12 1953.]
Silver oxide Preparation Products And Raw materials
Preparation Products2-(5-BROMO-2-PYRIDYLAZO)-5-(DIETHYLAMINO)PHENOL-->METHYL 2,5-DICHLOROTHIOPHENE-3-CARBOXYLATE-->2,5-DICHLOROTHIOPHENE-3-CARBONYL CHLORIDE-->2,5-DICHLOROTHIOPHENE-3-CARBOXYLIC ACID
Silver oxide,SILVER OXIDE pure,SILVER OXIDE EXTRA PURE Magnesium oxide Boron silver oxide (B4Ag2O7) Silver oxide (Ag4O4) SILVER OXIDE (AGO) 99.5% 10G ETHYLENE OXIDE (Diethoxymethyl)diphenylphosphine oxide Iron oxide Zinc oxide NITRIC OXIDE Molybdenum silver oxide Silver oxide(Ag2O2) Silver oxide NITROUS OXIDE Silver SILVER OXIDE (AGO) 99.5% 2G Cuprous oxide Propylene oxide

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