Antioxidant 245

Antioxidant 245 Basic information
Characterization Physical Properties Applications Features/benefits Guidelines for use Uses Health & Safety
Product Name:Antioxidant 245
Synonyms:(oxy-2,1-ethanediyl)ester;benzenepropanoicacid,3-(1,1-dimethylethyl)-4-hydroxy-5-methyl-,1,2-ethanediy;Benzenepropanoicacid,3-(1,1-dimethylethyl)-4-hydroxy-5-methyl-,1,2-ethanediylbis(oxy-2,1-ethanediyl)ester;Ethylenbis(oxyethylen)bis[3-(5-tert.-butyl-4-hydroxy-m-tolyl)propionat];triethylene glycol bis-3-(3-t-butyl-4-hydroxy-5-methylphenyl) propionate;3-tert-Butyl-4-hydroxy-5-methylphenylpropionic acid triethyleneglycol ester;Irganox 245(Ciba SC);Ciba Irganox 245
CAS:36443-68-2
MF:C34H50O8
MW:586.77
EINECS:253-039-2
Product Categories:Organics
Mol File:36443-68-2.mol
Antioxidant 245 Structure
Antioxidant 245 Chemical Properties
Melting point 79-81oC
Boiling point 602.88°C (rough estimate)
density 1.0397 (rough estimate)
refractive index 1.6000 (estimate)
Fp >150 °C
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), Methanol (Slightly)
pka11.44±0.25(Predicted)
form Solid
color White to Off-White
Water Solubility 104μg/L at 23℃
LogP4.7 at 23℃
CAS DataBase Reference36443-68-2(CAS DataBase Reference)
EPA Substance Registry SystemBenzenepropanoic acid, 3-(1,1-dimethylethyl)-4-hydroxy-5-methyl-, 1,2-ethanediylbis(oxy-2,1-ethanediyl) ester (36443-68-2)
Safety Information
Risk Statements 52/53
Safety Statements 61
MSDS Information
Antioxidant 245 Usage And Synthesis
CharacterizationAntioxidant 245 is a sterically hindered phenolic antioxidant particularly suitable for organic substrates. It protects the substrates against thermo-oxidative degradation during manufacturing, processing and end-use. Antioxidant 245 is odorless, of low volatility, has a good color stability and exhibits high extraction resistance.
Physical PropertiesPhysical Properties of 36443-68-2
ApplicationsAntioxidant 245 is effective in styrene polymers, particularly impact modified polystyrenes, ABS, MBS, SB and SBR-latices as well as in POM homo- and copolymers. It is also very useful for the stabilization of polyurethanes, polyamides, thermoplastic polyesters, PVC and other polymers. In addition to imparting thermostability to the finished polymer Antioxidant 245 is effective as chain stopper during PVC polymerization.
Features/benefitsAntioxidant 245 can be used in combination with other additives such as costabilizers (e.g. thioesters, phosphites, phosphonites, lactones), light stabilizers, and other functional stabilizers. The effectiveness of the blends of Antioxidant 245 with IRGAFOS 168 (Irganox B-blends) is noteworthy.
Guidelines for useAlready 0.05 – 0.1 % of Antioxidant 245 provides long-term thermal stability tothe polymer. Concentrations up to 1.0 % can be used depending on the substrate and the requirements of the end application.
UsesAntioxidant 245 is an ethylenebis (oxyethylene) bis-(3-(5-tert-butyl-4-hydroxy-m-tolyl)-propionate). It is an antioxidant for processing and long-term thermal stabilization. It has low volatility, good color stability and is odorless. Exhibits high extraction resistance. Antioxidant 245 protects the substrates against thermo-oxidative degradation during manufacturing, processing and end use. It is compatible with styrene polymers including polystyrenes, ABS, MBS, SB and SBR as well as POM homo-and copolymers. Also compatible with polyurethanes, polyamides, thermoplastic polyesters, PVC and other polymers. It is effective as chain stopper during PVC polymerization. Its recommended dosage level is 0.05-0.1% for long-term thermal stability. Concentrations up to 1.0% can be used depending on the substrate and the requirements of the end application.
Health & SafetyAntioxidant 245 exhibits a very low order of oral toxicity and does not presentany abnormal problems in its handling or general use.
Detailed information on handling and any precautions to be observed in theuse of the product(s) described in this leaflet can be found in our relevanthealth and safety information sheet.
UsesTriethylene Glycol Bis(3-?tert-?butyl-?4-?hydroxy-?5-?methylphenyl)?propionate is used as a polymer antioxidant stabilizer in adhesives and polymers for food contact. Generally functions as an antioxidant in the chemistry of plastics.
Flammability and ExplosibilityNotclassified
Safety ProfileQuestionable carcinogen withexperimental tumorigenic data. When heated todecomposition it emits acrid smoke and irritating vapors.
Antioxidant 245 Preparation Products And Raw materials
Raw materialsZDYUUBIMAGBMPY-UHFFFAOYSA-N-->Methyl-3-(3-tert.-butyl-4-hydroxy-5-methylphenyl)propionat-->Monobutyltin oxide
Antioxidant 1330 Diethylene glycol Triethylene glycol 3-(4-Hydroxyphenyl)propionic acid (2-METHYL-1H-INDOL-3-YL)-OXO-ACETIC ACID ETHYL ESTER O,O'-Dioctadecylpentaerythritol bis(phosphite) Butylated hydroxyanisole Antioxidant 1520 Complex antioxidant Antioxidant 168 Calcium Propionate ANTIOXIDANT Triton X-100 Ethylene glycol diacetate Ethylene glycol Butylated Hydroxytoluene Antioxidant 1010 CHLOROPHOSPHONAZO III

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