Strontium peroxide

Strontium peroxide Basic information
Uses
Product Name:Strontium peroxide
Synonyms:Strontium peroxide, 90-95%;strontiumperoxide(sr(o2));StrontiumPeroxides3552;STRONTIUM DIOXIDE;STRONTIUM PEROXIDE;StrontiuM peroxide, 12.3% available oxygen;StrontiuM peroxide 98%
CAS:1314-18-7
MF:O2Sr
MW:119.62
EINECS:215-224-6
Product Categories:Oxides;Strontium;PeroxidesMetal and Ceramic Science;Oxidation;Synthetic Reagents
Mol File:1314-18-7.mol
Strontium peroxide Structure
Strontium peroxide Chemical Properties
Melting point 215 °C
density 4.56 g/mL at 25 °C(lit.)
form Powder
color Pale brown
Water Solubility Insoluble in water and slowly decomposes in water.
Sensitive Moisture Sensitive
Merck 13,8929
CAS DataBase Reference1314-18-7(CAS DataBase Reference)
EPA Substance Registry SystemStrontium peroxide (Sr(O2)) (1314-18-7)
Safety Information
Hazard Codes O,Xi
Risk Statements 8-41-37/38
Safety Statements 17-26-36-36/39
RIDADR UN 1509 5.1/PG 2
WGK Germany 3
TSCA Yes
HazardClass 5.1
PackingGroup II
HS Code 28164000
Hazardous Substances Data1314-18-7(Hazardous Substances Data)
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
Strontium peroxide Usage And Synthesis
UsesStrontium dioxide (SrO2) can cause fires or explode when heated and in contact with organic substances. It is used as both a reducing agent and an oxidizing agent.
Chemical PropertiesStrontium peroxide is a lightcolored solid of good thermal stability. Commercial strontium peroxide contains about 85% SrO2 and 10% active oxygen.
Chemical Propertieswhite to off-white powder
UsesStrontium peroxide or strontium dioxide (SrO2) can cause fires or explode when heated and in contact with organic substances. It is used as both a reducing agent and an oxidizing agent.
UsesStrontium Peroxide is an oxidizing agent that is used for bleaching. It has also been used in some pyrotechnic displays to provide a vivid-red color.
UsesThe only substantial application for this compound is in pyrotechnics. Strontium peroxide produces a red color in flames.
PreparationLike the other alkaline earth peroxides, it can be prepared by reaction of the nitrate and sodium peroxide in a cold solution:
Sr(NO3)2+ Na2O2+xH2O
SrO2·xH2O+2NaNO3
The hydrated form is usually the octahydrate. If the anhydrate is desired, the hydrated peroxide is dried and then sintered at 350°C for 10 min or less:
SrO2·xH2O+ heat→SrO+SrO2+H2O
General DescriptionA white powder. Insoluble in water and slowly decomposed by water. Noncombustible, but accelerates the burning of combustible material.
Air & Water ReactionsInsoluble in water and slowly decomposed by water.
Reactivity ProfileStrontium peroxide may explode from friction, heat or contamination. Accelerates burning when involved in a fire. May ignite combustibles (wood, paper, oil, clothing, etc.). If the combustible material is finely divided the mixture may be explosive.
Health HazardTOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Fire may produce irritating and/or toxic gases. Toxic fumes or dust may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Runoff from fire control or dilution water may cause pollution.
Fire HazardMay explode from friction, heat or contamination. These substances will accelerate burning when involved in a fire. May ignite combustibles (wood, paper, oil, clothing, etc.). Some will react explosively with hydrocarbons (fuels). Containers may explode when heated. Runoff may create fire or explosion hazard.
Flammability and ExplosibilityNotclassified
Safety ProfileA powerful oxidizer. A skin, eye, and mucous membrane irritant. Mixtures with organic materials readily ignite with friction or on contact with moisture. See also PEROXIDES and STRONTIUM COMPOUNDS.
Strontium peroxide Preparation Products And Raw materials
Raw materialsAmmonia-->Strontium hydroxide-->STRONTIUM-->potassium peroxide
STRONTIUM SULFIDE STRONTIUM IODIDE Strontium carbonate Silicon carbide Radium Peroxide Strontium nitrate Calcium peroxide Beryllium Peroxide Barium peroxide Magnesium peroxide Thorium dioxide STRONTIUM ACETATE Strontium hydroxide Zinc peroxide STRONTIUM PEROXIDE OCTAHYDRATE Strontium peroxide Strontium oxide

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