Mercury fulminate

Mercury fulminate Basic information
Product Name:Mercury fulminate
Synonyms:Mercury fulminate,wetted with not less than 20% water,or mixture of alcohol and water,by mass;mercury difulminate;MERCURY FULMINATE;fulminating mercury;mercuric fulminate;Fluminicacid,mercury(2+)satl(R,T);Mercuryfulminate(R,T);mercury difulminate mercuric fulminate fulminate of mercury
CAS:628-86-4
MF:C2HgN2O2
MW:284.6236
EINECS:211-057-8
Product Categories:
Mol File:628-86-4.mol
Mercury fulminate Structure
Mercury fulminate Chemical Properties
Melting point explodes [HAW93]
density 4.4200
form gray crystals
Water Solubility slightly soluble cold H2O, soluble hot H2O; soluble alcohol, NH4OH [HAW93]
EPA Substance Registry SystemMercury fulminate (628-86-4)
Safety Information
Hazard Codes E,T,N
Risk Statements 3-23/24/25-33-50/53
Safety Statements 3-35-45-60-61
RIDADR 0135
HazardClass 1.1A
PackingGroup II
Hazardous Substances Data628-86-4(Hazardous Substances Data)
MSDS Information
Mercury fulminate Usage And Synthesis
Chemical PropertiesGray, crystalline powder.Soluble in alcohol, ammonium hydroxide, and hot water; slightly soluble in cold water.
UsesManufacture of caps and detonators for producing explosions of military, industrial, and sporting purposes.
UsesMercury fulminate is used as a primaryexplosive to initiate boosters.
UsesMercury fulminate [Hg(CNO)2] is very explosive and is used to manufacture blasting caps and detonators.
General DescriptionA slurry or wet mass of white crystals. Contains at least 20% water or water-ethyl alcohol mixture. May explode from shock, heat, flame, or friction when dry. May explode under prolonged exposure to heat. Primary hazard is blast of an instantaneous explosion, not flying projectiles or fragments. A widely used initiating detonator for high explosives.
Reactivity ProfileMERCURY FULMINATE is incompatible with acetylene, ammonia, chlorine dioxide, azides, calcium (amalgam formation), sodium carbide, lithium, rubidium, copper . Contact with sulfuric acid causes explosion, [Urbanski, 1967, vol. 3, 135, 149]. Aqueous ammonia and Hg react to form an explosive solid, likely a fulminate. (Thodos, G. Amer. Inst. Chen. Engrs. J., 1964, 10, 274.).
HazardExplodes readily when dry, keep moist till use, an initiating explosive. Highly toxic.
Health HazardFire may produce irritating, corrosive and/or toxic gases.
Health HazardMercury fulminate is a highly toxic compound,exhibiting the toxicity symptoms ofmercury. No toxicity data are available onthis compound.
Fire HazardMAY EXPLODE AND THROW FRAGMENTS 1600 meters (1 MILE) OR MORE IF FIRE REACHES CARGO.
Safety ProfileAn explosive sensitive to flame, heat, impact, friction, intense radiation, or contact with sulfuric acid. Selfexplodes. Dangerously flammable; should be kept moist until used. Incompatible with sulfuric acid. When heated to decomposition it emits very toxic fumes of Hg and NOx. See also MERCURY COMPOUNDS and FULMINATES.
Mercury fulminate Preparation Products And Raw materials
Mercury(II) sulfide Mercuric Oxide MERCUROUS NITRATE

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