4'-CHLORO-2,2':6',2''-TERPYRIDINE

4'-CHLORO-2,2':6',2''-TERPYRIDINE Basic information
Product Name:4'-CHLORO-2,2':6',2''-TERPYRIDINE
Synonyms:4'-CHLORO-2,2':6',2''-TERPYRIDINE;4'-CHLORO-2,2'6'2''-TERPYRIDINE;4-Chloro-2,6-di(pyridin-2-yl)pyridine ,99%;4''-CHLORO-2,2'':6'',2''-TERPYRIDINE 99%;4'-Chloro-2,2':6',2''-terpyridine,99%;4-Chloro-2,6-di(pyridin-2-yl)pyridine;2,2':6',2''-Terpyridine,4'-chloro-;4'-Chloro-2,2,2':6',2''-terpyridine
CAS:128143-89-5
MF:C15H10ClN3
MW:267.71
EINECS:626-940-7
Product Categories:C9 to C46Heterocyclic Building Blocks;Halogenated Heterocycles;Heterocyclic Building Blocks;Pyridines;Building Blocks;C13 to C40;C7 to C18;Chemical Synthesis;Halogenated Heterocycles;Heterocyclic Building Blocks
Mol File:128143-89-5.mol
4'-CHLORO-2,2':6',2''-TERPYRIDINE Structure
4'-CHLORO-2,2':6',2''-TERPYRIDINE Chemical Properties
Melting point 148-150 °C(lit.)
Boiling point 416.73°C (rough estimate)
density 1.2245 (rough estimate)
refractive index 1.6010 (estimate)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form Crystalline Powder
pka4.22±0.22(Predicted)
color Brown
Water Solubility Slightly soluble in water.
λmax278nm(CH3CN)(lit.)
BRN 3613386
InChIKeyAHEMFMCEBIJRMU-UHFFFAOYSA-N
Safety Information
Hazard Codes Xn
Risk Statements 22-37/38-41
Safety Statements 26-39
RIDADR UN 2811 6.1 / PGIII
WGK Germany 3
HS Code 29333990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
4'-CHLORO-2,2':6',2''-TERPYRIDINE Usage And Synthesis
Chemical Propertiesbrown crystalline powder
Uses4'-Chloro-2,2':6',2''-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture double helicates, dendrimers, micelles and metallo-supramolecular polymers. It is used to synthesize the mono- and bis-terpyridines. It is actively involved in Williamson type ether reactions alpha,μ-bishydroxy-functionalized poly(propylene oxide).
General Description4′-Chloro-2,2′:6′,2′′-terpyridine (4′-Cltpy, Cltpy, Cl-terpy) is a tridentate ligand that contains a terpyridine (tpy) site with a Cl site at the 4 -position. It coordinates with various metal ions through these two sites to form different coordination polymers. Crystal structure study shows terpyridine unit of Cltpy adopts a trans, trans conformation. Mol-ecules assemble themselves into stacked columns along the b axis, with an inter-planar distance of 3.51?. It undergoes Williamson type ether reactions with α,ω-bishydroxy-functionalized poly(propylene oxide). It undergoes Williamson type reaction with α-hydroxy-ω-carboxy-functionalized poly(ethylen-oxide) to afford monoterpyridine terminated telechelics.
4'-CHLORO-2,2':6',2''-TERPYRIDINE Preparation Products And Raw materials
Raw materialsTetrahydrofuran-->Phosphorus oxychloride-->Acetone-->Sodium hydride-->Phosphorus pentachloride-->Ammonium acetate-->Ethyl picolinate
Preparation Products4'-AMINO-2,2':6',2''-TERPYRIDINE-->4'-(4-AMINOPHENYL)-2,2':6',2''-TERPYRIDINE
6-BROMO-2,2'-BIPYRIDINE 4-Methyl-4'-(3-carboxypropyl)-2,2'-bipyridine 4'-BROMO-2,2':6',2''-TERPYRIDINE 1,3,5-Tris(m-iodophenyl)benzene 4‘-(4-hydroxyphenyl)-2, 2':6‘, 2“-terpyridine 4,4'-Dimethyl-2,2'-bipyridyl 2,2':6',2''-TERPYRIDINE-4,4',4''-TRICARBOXYLIC ACID 2,2'-DIPYRIDYL N,N'-DIOXIDE 2,2'-BIPYRIDINE-5-CARBOXYLIC ACID 2,2':6',2''-TERPYRIDINE 6''-CHLORO-[3,2':5',3'']-TERPYRIDINE 2,6-Lutidinehydrochloride 2,2'-BIPYRIDINE HYDROCHLORIDE 4-Chloro-2,6-dimethylpyridine 4-Chloro-2,2'-bipyridine 4'-CHLORO-2,2':6',2''-TERPYRIDINE 6-METHYL-2,2'-BIPYRIDINE CHLORO(2,2':6',2''-TERPYRIDINE)PLATINUM(II) CHLORIDE DIHYDRATE

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