Drometrizole

Drometrizole Basic information
Characterization Applications Features/benefits Guidelines for use Physical Properties Safety
Product Name:Drometrizole
Synonyms:(2'-Hydroxy-5mg-methylphenyl) benzotriazole;2-(2H-Benzotriazol-2-yl)-p-cresol(UV-P);TinuvinP/2-(2H-Benzotriazol-2-yl)-p-cresol;LOTSORB UV P;2-(2H-1,2,3-Benzotriazol-2-yl)-4-methylphenol;2-(2h-benzotriazol-2-yl)-4-methyl-pheno;2-(2h-benzotriazol-2-yl)-p-creso;2-(2-hydroxy-5-methyl-phenyl)-2H-benzotriazole
CAS:2440-22-4
MF:C13H11N3O
MW:225.25
EINECS:219-470-5
Product Categories:Uv absorber;C-C Bond Formation;C-C Bond Formation;Others;Synthetic Reagents;Synthetic Reagents;Additives for Plastic
Mol File:2440-22-4.mol
Drometrizole Structure
Drometrizole Chemical Properties
Melting point 125.5-129.5 °C(lit.)
Boiling point bp10 225°
density 1.38
vapor pressure 0Pa at 20℃
refractive index 1.5600 (estimate)
Fp 54°C
storage temp. 15-25°C
solubility DMSO (Slightly), Methanol (Slightly)
pka8.15±0.43(Predicted)
form Solid
color Off-White to Pale Yellow
Water Solubility 173μg/L at 20℃
Merck 14,3447
Stability:Hygroscopic
InChIKeyMCPKSFINULVDNX-UHFFFAOYSA-N
LogP4.2 at 25℃
CAS DataBase Reference2440-22-4(CAS DataBase Reference)
NIST Chemistry ReferencePhenol, 2-(2H-benzotriazol-2-yl)-4-methyl-(2440-22-4)
EPA Substance Registry System2-(2H-Benzotriazol-2-yl)-p-cresol (2440-22-4)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-53-43
Safety Statements 22-24/25-36/37
WGK Germany 1
RTECS GO6860000
HS Code 29339900
ToxicityLD50 oral in mouse: 6500mg/kg
MSDS Information
ProviderLanguage
Benazol P English
SigmaAldrich English
Drometrizole Usage And Synthesis
CharacterizationDrometrizole is an ultraviolet light absorber (UVA) of the hydroxyphenyl benzotriazole class, imparting good light stability to a wide variety of polymers.
ApplicationsDrometrizole provides ultraviolet protection in a wide variety of polymers including styrene homoand copolymers, engineering plastics such as polyesters and acrylic resins, polyvinyl chloride, and other halogen containing polymers and copolymers (e.g. vinylidenes), acetals and cellulose esters. Elastomers, adhesives, polycarbonate blends, polyurethanes, and some cellulose esters and epoxy materials also benefit from the use of Drometrizole.
   Drometrizole
Features/benefitsDrometrizole features a strong absorption of ultraviolet radiation in the 300-400 nm region. It also has a high degree of photostability over long periods of light exposure. The high absorbance combined with photostability and the ability to release absorbed energy in non sensitizing ways make Drometrizole an effective stabilizer against the effects of ultraviolet light.
Guidelines for useThe use levels of Drometrizole range between 0.10% and 0.50%, depending on substrate and performance requirements of the final application. Drometrizole can be used alone or in a variety of blends and combinations with Ciba IRGAFOS®, Ciba IRGANOX® and Ciba CHIMASSORB® stabilizers where often a synergistic performance is observed. Drometrizole may react with various heavy metal ions to form salts or complexes. For example, if Drometrizole comes into contact with iron or cobalt ions, colored complexes are formed. Reducing and oxidizing agents used in polymerization and curing processes have no effect on the stability of Drometrizole.
Physical PropertiesDrometrizole Physical Properties
SafetyIn accordance with good industrial practice, handle with care and avoid unnecessary personal contact. Protect skin. Prevent contamination of the environment. Avoid dust formation and ignition sources.
Chemical PropertiesLight yellow powder
UsesDrometrizole is an intermediate reactant in the synthesis of UV light absorbers for polyester fibers.
UsesAn ultraviolet light absorber for stabilizing plastics and other organic materials against discoloration and deterioration.
Uses2(2-Hydroxy-5-methylphenyl)benzotriazol is an UV adsorber for use in plastics, cosmetics, dental materials, acrylic materials, dyes, etc.
DefinitionDrometrizole is a member of triazoles.
ApplicationIntermediate reactant in the synthesis of UV light absorbers for polyester fibers
Reactant for synthesis of:
Benzotriazole UV absorbers with a blocked hydroxy group for us in UV curable paint
Maleimide-bound benzotriazole monomer to use for emulsion polymerization
Used in:
Microstereophotolithography and shape memory alloy for fabrication of miniaturized actuators
PVS and wood / PVC composites as a stabilizer
Acrylonitrile-butadiene-styrene as a UV absorber.
Flammability and ExplosibilityNotclassified
Drometrizole Preparation Products And Raw materials
Preparation Products[(2-methyl-2-propenyl)oxy]phenyl]--->1-METHALLYL-2-(2-HYDROXY-5-METHYL PHENYL) BENZOTRIAZOLE-->o-Phenylenediamine-->TIMTEC-BB SBB006355
Octabenzone UV-329 Methylparaben Chlorodimethylphenylsilane 5-Methyl-1H-benzotriazole Ultraviolet absorbent 3-Ethylphenol Tolyltriazole Bensulfuron methyl Uv-Absorber p-Cresol Cresol Kresoxim-methyl PHENYL VALERATE Drometrizole Thiophanate-methyl CHLOROPHOSPHONAZO III Diphenylsilanediol

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