Xantphos Pd G3

Xantphos Pd G3 Basic information
Reaction
Product Name:Xantphos Pd G3
Synonyms:METHANESULFONATO[9,9-DIMETHYL-4,5-BIS(DIPHENYLPHOSPHINO)XANTHENE][2'-AMINO-1,1'-BIPHENYL]PALLADIUM(II)DICHLOROMETHANEADDUCT,MIN.98%[XANTPHOSPALLADACYCLEGEN.3];Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(I;Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladium(II);Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladiuM(II) dichloroMethane adduct, Min. 98%;[(4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate/XantPhosPdG3;Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene](2'-amino-1,1'-biphenyl-2-yl)palladium(II) (Xantphos Pd G3) ;Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xant...;Pd Catalysts XantPhos-Pd-G3
CAS:1445085-97-1
MF:C52H46NO4P2PdS-
MW:949.358462
EINECS:
Product Categories:Buchwald Ligands&Precatalysts;Buchwald Precatalysts Series;Pd
Mol File:1445085-97-1.mol
Xantphos Pd G3 Structure
Xantphos Pd G3 Chemical Properties
Melting point 164-167 °C (decomposition)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form Powder
color pale yellow
Safety Information
MSDS Information
Xantphos Pd G3 Usage And Synthesis
Reaction
  1. Catalyst for the Negishi coupling of aryl halides and alkylzinc reagents.
  2. Catalyst for the synthesis of tetraacetylated p-tolyl thioglucose.
  3. Cooperative catalyst for the direct asymmetric α-allylation of acyclic esters.
Reactions of 1445085-97-1
UsesXantphos Pd G3 is used as a catalyst in many reactions. It is a third generation (G3) Buchwald precatalyst. XantPhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions.
General DescriptionXantPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XantPhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.
RuPhos Pd G3 Methanesulfonato(triphenylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) (PPH3 PD G3) XPhos Pd G1 tBuXPhos Pd G1 RuPhos Pd G2 SPhos Pd G1, Methyl t-Butyl Ether Adduct t-BuBrettPhos Palladacycle Gen. 3 RuPhos Palladacycle Gen. 4 t-BuXphos Palladacycle Gen. 4 Palladacycle Gen. 3 BrettPhosPalladacycle SPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct XPhos Pd G2 BrettPhos Pd G3 SPhos Palladacycle Gen. 4 XantPhos-Pd-G2 tBuXPhos-Pd-G3

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