SILVER NITRITE

SILVER NITRITE Basic information
Product Name:SILVER NITRITE
Synonyms:Nitrousacid,silver(1+)salt;nitrousacid,silver(1++)salt;SILVER NITRITE;SILVER NITRITE, 99.98%;Silver nitrite, 99% (metals basis);Silver nitrite: (Silver(I) nitrite);Silvernitrite,99%;Nitrous acid silver(I) salt
CAS:7783-99-5
MF:AgNO2
MW:153.87
EINECS:232-041-7
Product Categories:inorganic compound;Metal and Ceramic Science;Salts;Silver Salts
Mol File:7783-99-5.mol
SILVER NITRITE Structure
SILVER NITRITE Chemical Properties
Melting point 140 °C (lit.)
density 4.453 g/mL at 25 °C (lit.)
form Powder and Agglomerates
color Yellow-green
Specific Gravity4.453
Water Solubility Soluble in hot water.Insoluble in ethanol.
Sensitive Light Sensitive
Merck 14,8519
Solubility Product Constant (Ksp)pKsp: 3.22
Exposure limitsACGIH: TWA 0.01 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.01 mg/m3
Stability:Stable. Oxidizer - contact with combustible material may cause fire.
CAS DataBase Reference7783-99-5(CAS DataBase Reference)
EPA Substance Registry SystemNitrous acid, silver(1+) salt (7783-99-5)
Safety Information
Hazard Codes O,Xn,N
Risk Statements 8-22-36/38-50/53
Safety Statements 26-45-60-61
RIDADR UN 2627 5.1/PG 2
WGK Germany 3
8
TSCA Yes
HazardClass 5.1
PackingGroup III
HS Code 28432900
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
SILVER NITRITE Usage And Synthesis
Chemical Propertiespowder
UsesFor preparation of standard NaNO2 solution for water analysis; preparation of aliphatic nitro-compounds; as reagent for primary, secondary, and tertiary alcohols.
UsesSilver nitrite is used in the silver plating process, hair dye, inks, permanent marker pens and determination of chloride ions in water and drilling fluids. It is used as Tollen?s reagent and used in the formation of aniline and nitro compounds in victor mayer reactions.
HazardHighly toxic.
Purification MethodsCrystallise the salt from hot conductivity water (70mL/g) in the dark. Dry it in the dark under vacuum. [Glemser & Sauer in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 1048 1963.]
SILVER NITRITE Preparation Products And Raw materials
Preparation ProductsPyridoxal hydrochloride
AMMONIUM NITRITE, 20% SOLN Sodium sulfite Silver carbonate SILVER(I) SULFITE BARIUM NITRITE Silver sulfate Rubidium carbonate Sodium nitrite Cesium nitrate Cadmium nitrate Barite Barium sulfate Silver nitrate SILVER NITRATE-NITRIC ACID REAGENT SILVER NITRITE Nitric acid Silver diamminesilver(1+) nitrate

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