(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL

(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL Basic information
Product Name:(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL
Synonyms:(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL;(R)-(-)-1-PHENYL-2,2,2-TRIFLUOROETHANOL;(R)-(-)-2,2,2-TRIFLUORO-1-PHENYLETHANOL;(-)-PHENYL(TRIFLUOROMETHYL)CARBINOL;(-)-Phenyl(trifluoromethyl)carbinol, (R)-(-)-1-Phenyl-2,2,2-trifluoroethanol;(1R)-1-Phenyl-2,2,2-trifluoroethanol;(αR)-α-(Trifluoromethyl)benzenemethanol;(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL AL COHOL, 99% (97% EE/GLC)
CAS:10531-50-7
MF:C8H7F3O
MW:176.14
EINECS:234-094-1
Product Categories:
Mol File:10531-50-7.mol
(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL Structure
(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL Chemical Properties
Melting point 20 °C(lit.)
Boiling point 73-76 °C9 mm Hg(lit.)
density 1.300 g/mL at 20 °C(lit.)
refractive index n20/D 1.459(lit.)
Fp 189 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka11.91±0.10(Predicted)
form clear liquid
color Colorless to Almost colorless
CAS DataBase Reference10531-50-7(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,C
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR NA 1993 / PGIII
WGK Germany 3
10-23
HS Code 29062990
MSDS Information
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SigmaAldrich English
(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL Usage And Synthesis
Uses(R)?-?2,?2,?2-?Trifluoro-?1-?phenylethanol is a building block used in the synthesis of mesoporous metal-organic frameworks.
Purification MethodsPurify the chiral alcohols by fractional distillation preferably in a vacuum. [Morrison & Ridgeway Tetrahedron Lett 573 1969, NMR: Pirkle & Beare J Am Chem Soc 90 6250 1968.] The racemate [340-05-6] has b 52-54o/2mm,57-59o/2mm, 64-65o/5mm, d 4 20 1.293, n D 20 1.457, and the 2-carbobenzoyl derivative has m 137-138o [Mosher et al. J Am Chem Soc 78 4374 1956]. [Beilstein 6 IV 3043.]
4-CHLORO-(2-HYDROXYHEXAFLUOROISOPROPYL)BENZENE 1,4-BIS(2-HYDROXYHEXAFLUOROISOPROPYL)BENZENE 2-(2,5-Dimethylphenyl)-1,1,1,3,3,3-hexafluoropropan-2-ol ALPHA-(TRIFLUOROMETHYL)BENZHYDROL p-Fluoro-(2-hydroxyhexafluoroisopropyl)benzene BIS(4-FLUOROPHENYL)TRIFLUOROMETHYL CARBINOL (R)-(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)ETHANOL 1,1-BIS(4-DIMETHYLAMINOPHENYL)-2,2,2-TRIFLUOROETHANOL 4-(HEXAFLUORO-2-HYDROXYISOPROPYL)ANILINE HEXAFLUORO-2-(P-TOLYL)ISOPROPANOL 4-(2-HYDROXYHEXAFLUOROISOPROPYL)BENZOIC ACID (R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL (S)-(+)-ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETYL CHLORIDE ALPHA,ALPHA,ALPHA',ALPHA'-TETRAKIS(TRIFLUOROMETHYL)-1,4-BENZENEDIMETHANOL HYDRATE 1,1,1,3,3,3-HEXAFLUORO-2-PHENYL-2-PROPANOL (S)-(-)-alpha-Methoxy-alpha-(trifluoromethyl)phenylacetic acid 1,3-BIS(2-HYDROXYHEXAFLUOROISOPROPYL)BENZENE BIS[ALPHA,ALPHA-BIS(TRIFLUOROMETHYL)BENZENEMETHANOLATO]DIPHENYLSULFUR

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