TITANIUM HYDRIDE

TITANIUM HYDRIDE Basic information
Product Name:TITANIUM HYDRIDE
Synonyms:TiH2;Titanium hydride (TiH2);titaniumdihydride;titaniumhydride(tih2);um 99.8%Titanium(II hydride;TITANIUM HYDRIDE, 98%TITANIUM HYDRIDE, 98%TITANIUM HYDRIDE, 98%;TITANIUM(II)HYDRIDE,MIN.95%(99+%-TI);itanium hydride
CAS:7704-98-5
MF:Ti
MW:47.87
EINECS:231-726-8
Product Categories:Materials for Hydrogen Storage;Metal Hydrides;Metal HydridesAlternative Energy;Reduction;Synthetic Reagents;Catalysis and Inorganic Chemistry;Metal HydridesChemical Synthesis;Titanium;metal hydrides;Alternative Energy;Chemical Synthesis;Materials for Hydrogen Storage;Materials Science;Synthetic Reagents
Mol File:7704-98-5.mol
TITANIUM HYDRIDE Structure
TITANIUM HYDRIDE Chemical Properties
Melting point >400 °C (dec.)
density 3.91 g/mL at 25 °C (lit.)
Fp >400°C
storage temp. no restrictions.
form Powder
Specific Gravity3.91
color Gray to black
Water Solubility Soluble in water.
Sensitive Moisture Sensitive
Merck 14,9473
InChIKeyRTAQQCXQSZGOHL-UHFFFAOYSA-N
CAS DataBase Reference7704-98-5(CAS DataBase Reference)
EPA Substance Registry SystemTitanium hydride (TiH2) (7704-98-5)
Safety Information
Hazard Codes F
Risk Statements 15-11
Safety Statements 7/8-43A-24/25-36/37/39-33-16-43
RIDADR 1871
WGK Germany 3
RTECS XR2130000
Autoignition Temperature437 °F
TSCA Yes
HS Code 2850 00 20
HazardClass 4.1
PackingGroup II
MSDS Information
ProviderLanguage
ACROS English
ALFA English
TITANIUM HYDRIDE Usage And Synthesis
Chemical Propertiesgrey to black powder
Chemical PropertiesTitanium Hydride, TiH2, is a brittle, metallic-gray solid, density 3.8 g/cm3, which produces 448 mL H2 at STP per gram TiH2. Titanium hydride powder is stable at room temperature and inert to water and most chemical reagents. Titanium hydride is used as a source for Ti powder, alloys, and coatings; as a getter in vacuum systems and electronic tubes; as a sealer of metals; and as a hydrogen source.
Physical propertiesGrayish-black metallic powder; stable in air; density 3.75 g/cm3; decomposes at 450°C with evolution of hydrogen; insoluble in water.
UsesAdditive in powder metallurgy; getter for oxygen and nitrogen in electronic tubes; wetting agent for ceramic to metal seals; source of pure hydrogen.
UsesTitanium(II) hydride is widely utilized as an additive in the manufacturing of Alnico sintered magnets and in sintered powdered metals. It is used in the production of metal foam, powdered titanium metal and in pyrotechnics. It is involved in various applications such as ceramics, pyrotechnics and sports equipment. It is also used as a laboratory reagent and as a blowing agent.
PreparationTitanium hydride is prepared by heating titanium dioxide with calcium hydride at 600°C in the presence of hydrogen
Also, the hydride may be prepared by heating tianium metal with hydrogen at elevated temperatures.
General DescriptionA white to light colored solid. Insoluble in water and denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. May ignite and burn with an intense flame if exposed to high temperatures or flame.
Air & Water ReactionsHighly flammable. Pyrophoric in dust form [Bretherick 1979. p. 104]. Insoluble in water.
Reactivity ProfileHydrides, such as TITANIUM HYDRIDE, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols. Hydrides are incompatible with acids, alcohols, amines, and aldehydes.
HazardFlammable, dangerous fire risk, dust may explode in presence of oxidizing agents.
Health HazardOxides from metallic fires are a severe health hazard. Inhalation or contact with substance or decomposition products may cause severe injury or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.
Fire HazardMay react violently or explosively on contact with water. Some are transported in flammable liquids. May be ignited by friction, heat, sparks or flames. Some of these materials will burn with intense heat. Dusts or fumes may form explosive mixtures in air. Containers may explode when heated. May re-ignite after fire is extinguished.
Flammability and ExplosibilityNotclassified
TITANIUM HYDRIDE Preparation Products And Raw materials
Titanium(IV)oxide acetylacetonate Barium titanate CYCLOPENTADIENYLTITANIUM TRICHLORIDE LEAD TITANIUM OXIDE Potassium hexafluorotitanate TITANIUM TITANIUM(III) CHLORIDE-ALUMINUM(III) CHLORIDE Titanium tetraisopropanolate Titanocene dichloride CHLOROTITANIUM TRIISOPROPOXIDE TITANIUM DIOXIDE Titanium ethoxide Tetrabutyl titanate TITANIUM OXYSULFATE Titanium tetrachloride Titanium propoxide Titanium diisopropoxide bis(acetylacetonate) Titanium nitride

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