Sodium metaborate

Sodium metaborate Basic information
Description Reference
Product Name:Sodium metaborate
Synonyms:Boric acid (HBO2), sodium salt;Boric acid, monosodium salt;Monosodium metaborate;NaBO2;Rasorite;Sodium dioxoborate;SODIUM MONOBORATE;SODIUM METABORATE
CAS:7775-19-1
MF:BNaO2
MW:65.8
EINECS:231-891-6
Product Categories:Inorganics
Mol File:7775-19-1.mol
Sodium metaborate Structure
Sodium metaborate Chemical Properties
Melting point 966 °C
Boiling point 1434 °C
density 2.464
pka8.94[at 20 ℃]
form white hexagonal crystals
Water Solubility g/100g solution H2O: 14.10 (0°C), 22.00 (25°C), 55.60 (100°C); solid phase, NaBO2 ·4H2O (0°C, 25°C), NaBO2 · 2H2O (100°C) [KRU93]
NIST Chemistry ReferenceSodium metaborate(7775-19-1)
EPA Substance Registry SystemSodium metaborate (7775-19-1)
Safety Information
RIDADR UN3077(solid)
Hazardous Substances Data7775-19-1(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Monosodium metaborate English
Sodium metaborate Usage And Synthesis
DescriptionSodium Metaborate is the sodium salt of Metaborate. Sodium metaborate is used in the manufacturing of borosilicate glasses. It is also a component of herbicides and antifreeze1. It can also be used as an oil additive with anti-wear properties2. Sodium metaborate electroreduction in the alkaline system can act as a novel desulphurization process of coal water slurry3. It also has role in hydrolysis of sodium borohydride to minimize the water utilization4. It can also act as a novel alkali in alkali/surfactant/polymer flooding5. It is also useful in the thermo-chemical production of sodium borohydride6, which is a safe and practical hydrogen storage material for on-board hydrogen production.
Reference
  1. https://en.wikipedia.org/wiki/Sodium_metaborate
  2. Liu, Weimin. "The Antiwear Properties of Sodium Metaborate as an Oil Additive” Tribology 48.4(1990):290-293.
  3. Shen, Yafei, T. Sun, and J. Jia. "A novel desulphurization process of coal water slurry via sodium metaborate electroreduction in the alkaline system." Fuel 96.7(2012):250-256.
  4. Marrero-Alfonso, Eyma Y., et al. "Minimizing water utilization in hydrolysis of sodium borohydride: The role of sodium metaborate hydrates." International Journal of Hydrogen Energy 32.18(2007):4723-4730.
  5. Chen, Fuzhen, et al. "Evaluation the performance of sodium metaborate as a novel alkali in alkali/surfactant/polymer flooding." Journal of Industrial & Engineering Chemistry 19.2(2013):450-457.
  6. Eom, Kwang Sup, et al. "Thermochemical production of sodium borohydride from sodium metaborate in a scaled-up reactor." International Journal of Hydrogen Energy 38.6(2013):2804-2809.
Chemical PropertiesWhite lumps.Soluble in water. Noncombustible.
UsesHerbicide. Also available commercially as octahydrate and tetrahydrate.
DefinitionChEBI: An inorganic sodium salt having metaborate as the counterion.
Agricultural UsesHerbicide, Insecticide, Fungicide, Nematocid: Not listed for use in EU countries. Registered for use in the U.S
Agricultural UsesRasorite is one of the sources of borax which is produced by re-crystallizing the ores. Borax (Na2B407?10H2O) is a source of the boron micronutrient and has many uses.
Trade nameALLPRO BARACIDE®; ATRATOL®[C]; BAREGROUND®; MONOBOR-CHLORATE®; PRAMITOL®; TRI-KILL®; UREABOR®
Sodium metaborate Preparation Products And Raw materials
Preparation ProductsSodium perborate tetrahydrate-->SODIUM METABORATE TETRAHYDRATE-->MAGNESIUM BORATE
SODIUM TETRAETHYLBORATE Sodium benzoate METABORIC ACID sodium Sodium tetrafluoroborate Sodium metaborate Sodium tetraphenylboron Sodium tetraborate Barium boron oxide Sodium perborate Sodium formate STANDARD BUFFER Sodium citrate Sodium bicarbonate SODIUM METABORATE DIHYDRATE,Sodium metaborate 4 mol Sodium hydroxide Sodium gluconate Sodium carbonate

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