Caesium fluoride

Caesium fluoride Basic information
Description
Product Name:Caesium fluoride
Synonyms:Anti-CSF 140 kDa subunit;Anti-Kalinin/nicein/epiligrin 100 kDa subunit;Anti-Ladsin 140 kDa subunit;Anti-Laminin 5 gamma 2 subunit;Anti-Laminin B2t chain;Anti-Laminin subunit gamma-2;CsF, CesiuM fluoride;Cesium fluoride, 99% trace metals basis
CAS:13400-13-0
MF:CsF
MW:151.9
EINECS:236-487-3
Product Categories:Cesium;Cesium Salts;Chemical Synthesis;Inorganic Salts;Materials Science;Metal and Ceramic Science;Protection and Derivatization;Synthetic Reagents;Deprotecting Reagents;Fluoride Sources;metal halide;Pyrimidines;AlphabeticalBiochemicals and Reagents;Biochemicals and Reagents;Density Gradient;Salts of Alkali Metals;CesiumProtection and Derivatization;Crystal Grade Inorganics;Cesium SaltsProtection and Derivatization;Deprotecting Reagents;Fluoride Sources;CesiumMetal and Ceramic Science;Inorganic Salts;Salts;Synthetic Reagents;bc0001
Mol File:13400-13-0.mol
Caesium fluoride Structure
Caesium fluoride Chemical Properties
Melting point 682 °C(lit.)
Boiling point 1251 °C
density 4.115 g/mL at 25 °C(lit.)
vapor pressure 0Pa at 25℃
Fp 1251°C
storage temp. 0-6°C
solubility H2O: 3 M at 20 °C, clear, colorless
form Powder/Lump
Specific Gravity4.115
color White
PH6.5-7.5 (25℃, 3M in H2O)
Water Solubility 369 g/100 mL (18 ºC)
Sensitive Hygroscopic
λmaxλ: 260 nm Amax: 0.05
λ: 280 nm Amax: 0.05
Merck 14,2012
Exposure limitsACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
Stability:hygroscopic
InChIKeyXJHCXCQVJFPJIK-UHFFFAOYSA-M
LogP0.23 at 20℃
CAS DataBase Reference13400-13-0(CAS DataBase Reference)
NIST Chemistry ReferenceCesium fluoride(13400-13-0)
EPA Substance Registry SystemCesium fluoride (CsF) (13400-13-0)
Safety Information
Hazard Codes T,C
Risk Statements 23/24/25-34-62-41-38-32
Safety Statements 26-36/37/39-45
RIDADR UN 2923 8/PG 2
WGK Germany 3
RTECS FK9650000
3-10
Hazard Note Corrosive
TSCA T
HazardClass 6.1
PackingGroup III
HS Code 28261990
MSDS Information
ProviderLanguage
Caesium fluoride English
SigmaAldrich English
ACROS English
ALFA English
Caesium fluoride Usage And Synthesis
DescriptionCaesium fluoride can be used as an analytical reagent, and also for the manufacture of optical crystals
It can be used for the preparation of fluorinated isocyanate.
During the Suzuki cross-coupling synthesis reaction, it can be used as a base for the positive substitution of the biaryls compound; it can also be used as a nucleophile for the fluorination of protic mediate such as the halide and sulfonate contained in tert-butyl alcohol or t-amyl alocohol. It can also be used as catalyst for the Silyl enol ether reaction of carbonyl compounds; used for efficient synthesis of single crystal Dion-Jacobson phase CsLaTa2O7 tto be applied to photocatalytic and superconductivity.

Chemical Propertieswhite crystalline powder
UsesCatalyst in oxidation reactions; as a solid base when adsorbed onto Celite, q.v. Fluoride source in organic synthesis. Inorganic scintillator.
UsesA preperation of building block for synthesis of fluoroallylic compounds.
UsesUsed as a base in a Suzuki cross-coupling synthesis of ortho-substituted biaryls.5 Also employed as a reagent for nucleophilic fluorination of primary halides and sulfonates in protic media such as tert-butyl and tert-pentyl alcohols.6
Uses Cesium fluoride is an inorganic compound with the chemical formula CsF, which is a hygmoscopic white salt. Cesium fluoride can be used as a source of fluoride anion for organic synthesis. Caesium has the highest electropositivity of all non-radioactive elements and fluorine has the highest electronegativity of all elements.
General DescriptionCesium fluoride is an inorganic compound known to be a source of fluoride ion and a catalyst in organic synthesis. It has been used in many organic reactions like 1,4?elimination, desilylation, transesterification, acylation, nucleophilic aromatic substitution, etherification, cross?coupling reactions and so on.
HazardA poison.
Flammability and ExplosibilityNotclassified
Safety ProfileA poison. Incompatible with benzenediazonium tetrafluoroborate and difluoroamine. When heated to decomposition it emits toxic fumes of F-.
Purification MethodsCrystallise it from aqueous solution by adding ethanol.
Caesium fluoride Preparation Products And Raw materials
Preparation ProductsTRIFLUOROMETHYLHYPOFLUORITE-->Fluorotributyltin-->Cesium hexafluorophosphate
Fluorinated carbon Potassium fluoride dihydrate CESIUM 2-ETHYLHEXOXIDE (0.8-1.0M IN OCTANE/TOLUENE) Cesium sulfate CESIUM HYDROXIDE, HYDRATE (99.9%-CS) CESIUM DODECAHYDRODODECABORATE Calcium fluoride Cesium nitrate sodium fluoride Caesium fluoride RHENIUM Aluminum fluoride hydrogen fluoride FLUORIDE STANDARD CESIUM FLUORIDE UN1759- ALUMINUM CESIUM FLUORIDE,aluminium caesium fluoride Aluminium cesium fluoride Cesium

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