4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL

4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL Basic information
Product Name:4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL
Synonyms:4-Methoxy-2,2,6,6-tetramethylpiperidine 1-Oxyl ;4-Methoxy-2,2,6,6-tetramethylpiperidinyloxy,freeradical;4-methoxy-2,2,6,6-tetramethylpiperidinyl-1-oxy;4-METHOXY-2,2,6,6-TETRAMETHYL-1-PIPERIDINYLOXY, FREE RADICAL;4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL;4-METHOXY-TEMPO;4-METHOXY-TEMPO, FREE RADICAL;(2,2,6,6-Tetramethyl-4-methoxypiperidinooxy)radical
CAS:95407-69-5
MF:C10H20NO2*
MW:186.27
EINECS:619-125-2
Product Categories:Analytical Chemistry;ESR Spectrometry;Oxidation;Spin Labels;Synthetic Organic Chemistry
Mol File:95407-69-5.mol
4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL Structure
4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL Chemical Properties
Melting point 40.5-44 °C (lit.)
storage temp. 2-8°C
form powder to crystal
color Orange to Amber to Dark red
BRN 4740399
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 2933399990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL Usage And Synthesis
Uses4-Methoxy-TEMPO may be employed as catalyst for the synthesis of 2-substituted benzoxazoles, via aerobic oxidation reaction.
General Description4-Methoxy-TEMPO (4-methoxy-2,2,6,6-tetramethyl-1-piperidinyloxy) is an aminoxyl free radical commonly employed for the oxidation reaction of alcohols (primary/secondary). It has been proposed as hindered amine light stabiliser (HALS) model compound. Its reaction with irradiated dilute aqueous suspensions of photocatalytic nanoparticulate titanium dioxide was investigated by electron spin resonance (ESR) and electrospray ionization mass-spectrometry (ESI-MS).
4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL Preparation Products And Raw materials
Diisopropylamine Dimethyl sebacate 4-Amino-TEMPO, free radical 4-(4-NITROBENZOYLOXY)-2,2,6,6-TETRAMETHYL-1-PIPERIDINYLOXY 2,2,6,6-Tetramethylpiperidine 4-METHOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL 4-Hydroxy-2,2,6,6-tetramethyl-piperidinooxy 2,2,6,6-Tetramethylpiperidinooxy 4-BENZOYLOXY-TEMPO 2,2,6,6-Tetramethyl-4-piperidinol

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