|
| | rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Basic information | | Stability Storage |
| Product Name: | rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride | | Synonyms: | RAC-DICHLOROETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV);RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM(IV) DICHLORIDE;RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE;RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM;(R)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE;(S)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE;DICHLORO[RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)]ZIRCONIUM(IV);DICHLORO-(S,S)-ETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV) | | CAS: | 100163-29-9 | | MF: | C20H24Cl2Zr10* | | MW: | 426.53 | | EINECS: | | | Product Categories: | metallocene;Zr;Catalysis and Inorganic Chemistry;Chemical Synthesis;Zirconium | | Mol File: | 100163-29-9.mol | ![rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Structure](CAS/GIF/100163-29-9.gif) |
| | rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Chemical Properties |
| Melting point | 267-271 °C(lit.) | | form | Powder | | color | white to pale yellow | | Sensitive | moisture sensitive |
| | rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Usage And Synthesis |
| Stability | Stable under normal temperature and pressure, avoid contact with water and oxidants. | | Storage | sealed storage, stored in a cool, dry warehouse. Keep away from oxidants, water sources. | | Chemical Properties | White to pale yellow powder,it can carry out catalytic reaction. | | Uses | Rac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride is a catalyst for enantioselective methylalumination of monosubstituted alkenes.The Kaminsky catalyst with co-catalyst methylaluminoxane (MAO) is a type of Ziegler-Natta catalyst, showing extremely high activity for polymerization of olefins such as ethylene, propylene, and styrene. | | Uses | Catalyst for:
Regiochemistry in Negishi carboaluminations
Polymerization of olefins
Diastereoselective intramolecular olefin alkylations
Asymmetric carbomagnesiation
Reduction of esters to alcohols
Enantioselective synthesis of allylic amines |
| | rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Preparation Products And Raw materials |
|
