Magnesium nitride

Magnesium nitride Basic information
Product Name:Magnesium nitride
Synonyms:trimagnesium dinitride;MAGNESIUM NITRIDE, -325 MESH, 99.5+%;MAGNESIUM NITRIDE 99.6% (METALS BASIS), -325 MESH POWDER;Magnesiumnitride,99.6%(metalsbasis);MAGNESIUM NITRIDE;magnesiumnitride(mg3n2);Magnesium nitride, 99% (metals basis);Magnesium nitride cubic phase, -325 mesh, >=99.5% trace metals basis
CAS:12057-71-5
MF:Mg3N2
MW:100.93
EINECS:235-022-1
Product Categories:Ceramics;Metal and Ceramic Science;Nitrides
Mol File:12057-71-5.mol
Magnesium nitride Structure
Magnesium nitride Chemical Properties
Melting point 800°C
density 2.71 g/mL at 25 °C(lit.)
form Powder
Specific Gravity2.71
Water Solubility Reacts with water.
Sensitive Moisture Sensitive
Stability:Air sensitive. Incompatible with moisture, strong acids, strong bases.
EPA Substance Registry SystemMagnesium nitride (Mg3N2) (12057-71-5)
Safety Information
Hazard Codes Xi,F
Risk Statements 36/37/38-14/15
Safety Statements 26-36-Neverusewater.
RIDADR UN 2813 4.3/PG 1
WGK Germany 3
TSCA Yes
HazardClass 4.1
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Magnesium nitride Usage And Synthesis
DescriptionMagnesium nitride has the molecular formula of Mg3N2 and the molecular weight of 100.9494 g/mol. It can be prepared by the reaction of Mg metal in a pure stream of nitrogen gas:
3Mg + 2N2→Mg3N2
At room temperature and pressure, it is a greenish yellow powder. Its density is 2.712 g/cm3 and it melts at about 1500 °C. Its CAS number is 12057-71-5. It reacts with water to produce ammonia gas, as do many metal nitrides: Mg3N2 + 6H2O→3Mg(OH)2 + 2NH3 In fact, when magnesium is burned in air, some magnesium nitride is formed in addition to the principal product, MgO. Where two Mg2+ ions are directly linked together. The lattice parameter and coordinates of Mg3N2 were obtained. It is a cubic anti-bixbyite structure with lattice parameter a = 9:9528 . The metal (Mg) atoms are in general positions 48 e of space group Ia3 (x; y; z). There are two crystallographically different kinds of N atoms: N1 is in positions 8b (1/4, 1/4, 1/4), and N2 in positions 24d (x, 0,1/4). In this structure, the N-arrays are fairly close to ideal cubic close packing. The 12 shortest N–N distances are in the range from 3.31 to 3.72?. Each nitrogen atom is coordinated by six Mg atoms. N1 has six Mg neighbors with a distance of 2.14?, while N2 is coordinated by six Mg with different N–Mg distances ranging from 2.084 to 2.179. The Mg–Mg distances are 2.72.
Chemical PropertiesMagnesium nitride is an inorganic compound composed of nitrogen and magnesium and belongs to the cubic crystal system. It is a green-yellow to yellow-orange loose powder. The relative density is 2.71225. Soluble in acid, insoluble in ethanol. It decomposes at 800°C and in water. It sublimates at 700°C in a vacuum. When exposed to air, it immediately breaks down into Mg(OH)2 and NH3.
UsesThe use of magnesium nitride as a convenient source of ammonia allows a direct transformation of esters to primary amides. Methyl, ethyl, isopropyl, and tert-butyl esters are converted to the corresponding carboxamides in good yields.
ReactionsMagnesium nitride react with water to produce magnesium hydroxide and ammonia. The reaction takes place in a boiling solution.
Mg3N2 + 6 H2O === 3 Mg(OH)2 + 2 NH3↑.
Like many metal nitrides, magnesium nitride reacts with acids or hydrated non-metal oxides to produce ammonium salts and magnesium salts.
Magnesium nitride Preparation Products And Raw materials
TITANIUM NITRIDE DYSPROSIUM NITRIDE CHROMIUM(III) NITRIDE -325MESH STRONTIUM NITRIDE ERBIUM NITRIDE Aluminum nitride GALLIUM NITRIDE CALCIUM NITRIDE cerium nitride EUROPIUM NITRIDE LITHIUM NITRIDE YTTRIUM NITRIDE FERROUS SULFATE PRASEODYMIUM(III) NITRIDE Magnesium fluoride YTTERBIUM NITRIDE LANTHANUM(III) NITRIDE Magnesium nitride

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