Zirconium silicate

Zirconium silicate Basic information
Product Name:Zirconium silicate
Synonyms:Zirconium silicate: (Zirconium silicon oxide);ZIRCONIUM(+4)SILICATE;ZIRCON;acorite;auerbachite;azorite=acorite;Silicic acid (H4-SiO4), zirconium(4+) salt (1:1);Silicicacid(H4SiO4),zirconium(4+)salt(1:1)
CAS:10101-52-7
MF:O4SiZr
MW:183.3071
EINECS:233-252-7
Product Categories:metal silicate;Inorganics
Mol File:10101-52-7.mol
Zirconium silicate Structure
Zirconium silicate Chemical Properties
Melting point 2550 °C
density 4,56 g/cm3
refractive index 1.78-1.99
form nanopowder
color Yellow to orange
Specific Gravity4.56
OdorOdorless
Water Solubility Insoluble in water, acids, alkali and aqua regia.
Hydrolytic Sensitivity1: no significant reaction with aqueous systems
Merck 14,10181
Exposure limitsACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3
Stability:Stable.
CAS DataBase Reference10101-52-7(CAS DataBase Reference)
NIST Chemistry ReferenceZirconium silicate(10101-52-7)
EPA Substance Registry SystemSilicic acid (H4SiO4), zirconium(4+) salt (1:1) (10101-52-7)
Safety Information
Hazard Codes Xn
Risk Statements 20-36/37/38
Safety Statements 26-36
WGK Germany 3
TSCA Yes
HS Code 28399090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Zirconium silicate Usage And Synthesis
Chemical PropertiesZirconium silicate is a colorless tetragonal crystals (when pure); presence of impurities forms various colors; density 4.56 g/cm3; hardness 7.5 Mohs; dissociates to ZrO2 and SiO2 above 1,540°C; melts at 2,550°C; insoluble in water, acids, aqua regia, and alkalies; inert in most chemicals. Zirconium silicate is used as an additive to glass, in ceramic tiles, in ultrafiltration membranes, and as a dental abrasive.
UsesZirconium silicate (ZrSiO4) is one form of the mineral whose crystals when polished are known as cubic zircons, which resemble diamond gemstones.
DefinitionZirconium silicate is a naturally occurring silicateof zirconium, ZrSiO4, used as a gemstone.The colour depends in smallamounts of other metals and may bered, brown, yellow, or green. Redgem-quality zircon is sometimescalled jacinth; gem-quality zirconswith other colours are called jargoons.There is also a naturally occurringcolourless variety. Zircongems can be given other colours, ormade colourless, by heat treatment.The colourless varieties (either naturalor treated) are sometimes calledMatura diamonds (after Matura in SriLanka). The name 'zircon' is often erroneouslyapplied to a synthetic formof the oxide cubic zircona, which isused as a diamond substitute.
PreparationZirconium silicate occurs in nature as mineral zircon. Ore is mined from natural deposits and concentrated by various techniques (See Zirconium, Recovery). It is separated from sand by electrostatic and electromagnetic methods. Also, the compound can be made by fusion of SiO2 and ZrO2 in an arc furnace, or by reacting a zirconium salt with sodium silicate in aqueous solution.
ApplicationZirconium silicate is used for manufacturing refractory materials for applications where resistance to corrosion by alkali materials is required. It is also used in production of some ceramics, enamels, and ceramic glazes. In enamels and glazes it serves as an opacifier. It can be also present in some cements. Another use of zirconium silicate is as beads for milling and grinding. Thin films of zirconium silicate and hafnium silicate produced by chemical vapor deposition. Potential alternative gate dielectric to silica. In Europe in cosmetic creams and powders.
Zirconium silicate Preparation Products And Raw materials
Raw materialsSILICA
Preparation ProductsZirconium dioxide-->monazite-->ILMENITE
INDIUM SELENIDE ZIRCONIUM BROMIDE Bismuth selenide Zinc sulfide SnSe2 BISMUTH TELLURIDE COPPER (II) TELLURIDE Copper(II) sulfate pentahydrate Vanadium(V) oxide Cobalt oxide SILICIC ACID Zirconium silicate SILICA SILICA SILICA Silicic acid ZIRCONIUM ORE SILICATE

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