1-(2-(TRIMETHYLSILYL)ETHOXYCARBONYLOXY)&

1-(2-(TRIMETHYLSILYL)ETHOXYCARBONYLOXY)& Basic information
Product Name:1-(2-(TRIMETHYLSILYL)ETHOXYCARBONYLOXY)&
Synonyms:1-({[2-(trimethylsilyl)ethoxy]carbonyl}oxy)pyrrolidine-2,5-dione;N-[2-(trimethylsilyl)ethoxycarbonyloxy]succinimide(Teoc-Osu);1-(2-(TRIMETHYLSILYL)ETHOXYCARBONYLOXY)&;N-[2-(Trimethylsilyl)ethoxycarbonyloxy]succinimide;Teoc-OSu;(TriMethylsilyl)ethoxycarbonyloxy]succiniMide;2,5-Dioxopyrrolidin-1-yl (2-(trimethylsilyl)-ethyl) carbonate;1-[[[2-(Trimethylsilyl)ethoxy]carbonyl]oxy]-2,5-pyrrolidinedione
CAS:78269-85-9
MF:C10H17NO5Si
MW:259.33
EINECS:
Product Categories:Building Blocks;Heterocyclic Building Blocks;Pyrrolidines
Mol File:78269-85-9.mol
1-(2-(TRIMETHYLSILYL)ETHOXYCARBONYLOXY)& Structure
1-(2-(TRIMETHYLSILYL)ETHOXYCARBONYLOXY)& Chemical Properties
Melting point 83-88 °C(lit.)
Boiling point 308.6±44.0 °C(Predicted)
density 1.17±0.1 g/cm3(Predicted)
storage temp. 2-8°C
solubility soluble in Methanol
form powder to crystal
color White to Almost white
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 2931.90.9010
MSDS Information
1-(2-(TRIMETHYLSILYL)ETHOXYCARBONYLOXY)& Usage And Synthesis
Chemical PropertiesWhite to off-white powder
Uses1-[2-(Trimethylsilyl)ethoxycarbonyloxy]pyrrolidin-2,5-dione (Teoc-OSu) may be used as an acylating reagent to produce Teoc-amino acid derivatives.
General Description1-[2-(Trimethylsilyl)ethoxycarbonyloxy]pyrrolidin-2,5-dione (Teoc-OSu) is a silicon-based reagent that can be prepared from 2-trimethylsilylethyl carbonochloridite and N-hydroxysuccinimide.
1-(2-(TRIMETHYLSILYL)ETHOXYCARBONYLOXY)& Preparation Products And Raw materials
Raw materials(2-[(CHLOROCARBONYL)OXY]ETHYL)TRIMETHYLSILANE-->2-(Trimethylsilyl)ethanol-->N,N'-Disuccinimidyl carbonate-->N-Hydroxysuccinimide-->Triphosgene
1-(2-(TRIMETHYLSILYL)ETHOXYCARBONYLOXY)& 2-(Trimethylsilyl)ethanol 1-[(2-TRIMETHYLSILYL)ETHOXYCARBONYLOXY]PYRROLIDIN-2,5-DIONE 1-[2-(Trimethylsilyl)ethoxycarbonyloxy]benzotriazole

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