Cobaltous nitrate hexahydrate

Cobaltous nitrate hexahydrate Basic information
Description Resources
Product Name:Cobaltous nitrate hexahydrate
Synonyms:cobaltdinitratehexahydrate;cobaltousnitrate,aqueoussolution;cobaltousnitratehexahydratenitratehexahydrate;t nitrate hexahydrate;Cobalt(II) nitrate hexahydrate, for analysis, 99+%;Cobalt(II) nitrate hexahydrate, pure, 99%;COBALT NITRATE, HEXAHYDRATE REAGENT (ACS);Cobalt(II) nitrate hexahydrate Ni <0.001%
CAS:10026-22-9
MF:CoH12N2O12
MW:291.03
EINECS:600-049-3
Product Categories:Co;Cobalt Salts;Materials Science;Metal and Ceramic Science;Salts;Ultra-High Purity Materials;metal nitrate salts
Mol File:10026-22-9.mol
Cobaltous nitrate hexahydrate Structure
Cobaltous nitrate hexahydrate Chemical Properties
Melting point 55 °C(lit.)
density 1.88
refractive index 1.52
storage temp. Store at +5°C to +30°C.
solubility 2170g/l
form Wet Crystalline Aggregates
color Red to pinkish-brown
Specific Gravity1.87
PH4.0 (100g/l, H2O, 20℃)
Water Solubility 134 g/100 mL
Merck 14,2444
Exposure limitsACGIH: TWA 0.02 mg/m3
Stability:Stable. Strong oxidizer - incompatible with reducing agents.
InChIKeyQGUAJWGNOXCYJF-UHFFFAOYSA-N
CAS DataBase Reference10026-22-9(CAS DataBase Reference)
EPA Substance Registry SystemCobalt nitrate hexahydrate (10026-22-9)
Safety Information
Hazard Codes O,Xn,N,T
Risk Statements 8-22-40-43-50/53-42/43-36/37/38-68-20-60-49
Safety Statements 17-36/37-60-61-45-36/37/39-26-22-53
RIDADR UN 1477 5.1/PG 2
WGK Germany 2
RTECS QU7355500
TSCA Yes
HazardClass 5.1
PackingGroup III
HS Code 28342920
ToxicityLD50 orally in rats: 691 mg/kg (Speijers)
MSDS Information
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Cobaltous nitrate hexahydrate English
ACROS English
SigmaAldrich English
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Cobaltous nitrate hexahydrate Usage And Synthesis
DescriptionCobalt Nitrate is the cobalt salt form of nitrate, usually existing in the form of hexahydrate. It is used in manufacture of cobalt pigments and invisible inks; decorating stoneware and porcelain; preparation of catalysts; production of vitamin B12 supplements; a battery additive. It is commonly reduced, acting as the source of metallic high purity cobalt for use in the electronics and related industries. It can be absorbed on to various catalyst supports for use in Fischer-Tropsch catalysis. It also finds application in the synthesis of benzimidazole and benzothiazole compounds, which show significant and promising activities against various viruses such as HIV and HCMV-1.
Resourceshttps://www.alfa.com/en/catalog/036418/
https://en.wikipedia.org/wiki/Cobalt(II)_nitrate
Chandrachood, P. S., et al. Acta Chimica Slovenica 58.2(2011):367-371.
https://www.google.com/patents/US2595499


Chemical PropertiesRed crystal, deliquescent in most air
UsesPreparation of cobalt standard solutions.
Usesmanufacture of cobalt pigments and invisible inks; decorating stoneware and porcelain; preparation of catalysts; production of vitamin B12 supplements.
UsesCobaltous nitrate [Co(NO3)2·6H2O], also known as cobalt nitrate, is a red crystal that absorbs moisture. It is used in inks, pigments, animal feed, soil enhancers, and hair dyes.
PreparationThe red hygroscopic hexahydrate Cu(NO3)2.6H2O crystallizes from aqueous solutions of cobalt bases in dilute nitric acid at room temperature. It becomes the trihydrate when heated at 56° ; at higher temperatures decomposition occurs.
DefinitionChEBI: A hydrate that is the hexahydrate form of cobalt dinitrate.
General DescriptionCobalt(II) nitrate hexahydrate (Co(NO3)2·6H2O) is the hydrated cobalt salt. Its step-wise thermal degradation has been investigated. It affords anhydrous cobalt(II)nitrate as decomposition product.
Purification MethodsCrystallise the nitrate from water (1mL/g), or ethanol (1mL/g), by partial evaporation. After 3 crystallisations from H2O it contains: metal (ppm) As (8), Fe (1.2), K (1), Mg (4), Mn (4), Mo (4), Na (0.6), Ni (18), Zn (1.6). The hexahydrate gives the pink anhydrous salt by the action of HNO3 and N2O5. The hexahydrate melts at ~55o to give a red liquid which decomposes on further heating at 100-105o to form Co3O4.
Cobaltous nitrate hexahydrate Preparation Products And Raw materials
Raw materialsSulfuric acid-->Nitric acid-->Extractant-->Cobalt
Preparation ProductsPropionamidine hydrochloride-->PROPIONAMIDINE
Miconazole Nitrate Thiamine nitrate Econazole nitrate Nickel chloride Pralmorelin Diphenolic acid Cobaltous nitrate hexahydrate 4-(Diethylamino)salicylaldehyde Ammonium nitrate Nitrite DL-α-Tocopherol 5-Chlorovaleric acid Sodium nitrite Iron chloride hexahydrate Cobalt chloride hexahydrate Sodium nitrate Aluminium chloride hexahydrate Calcium chloride hexahydrate

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