PERIODIC ACID

PERIODIC ACID Basic information
Product Name:PERIODIC ACID
Synonyms:Periodic acid, ACS, 99.01-101.0%;Periodate;Periodic Acid, ACS;PERIODIC ACID FOR ANALYSIS EMSURE;Periodic acid SynonyMs Orthoperiodic acid;Periodic acid 99.999% trace metals basis;Periodic acid puriss. p.a., ACS reagent, for oxidimetric titration, crystallized, >=99.0% (RT);Periodic acid ReagentPlus(R), >=99.0%
CAS:10450-60-9
MF:H5IO6
MW:227.94057
EINECS:233-937-0
Product Categories:Halogenated Heterocycles ,Quinolines;Hypervalent IodineEssential Chemicals;Acids&Bases;Reagent Grade;ACS GradeSynthetic Reagents;Essential Chemicals;Inorganics;AcidsSynthetic Reagents;Electronic Chemicals;Analytical Reagents for General Use;O-P, Puriss p.a. ACS;Puriss p.a. ACS;Synthetic Reagents;In the determination of K, as oxidant;Hypervalent Iodine;Micro/Nanoelectronics;Oxidation;K00001
Mol File:10450-60-9.mol
PERIODIC ACID Structure
PERIODIC ACID Chemical Properties
Melting point 122 °C (lit.)
Boiling point 140°C
density d417 1.3875; d 1.42
vapor pressure 7.6Pa at 25℃
RTECS NN1269700
Fp 140°C
storage temp. Store at +15°C to +25°C.
solubility soluble in Methanol, Water
form Solid
color White to slightly yellow
PH1.2 (100g/l, H2O, 20℃)
Water Solubility Soluble in water and alcohols.
Sensitive Moisture & Light Sensitive
Merck 14,7171
Stability:Stable, but strong oxidizer. Contact with combustible material may cause fire. Hygroscopic. Incompatible with organic materials, strong reducing agents.
InChIKeyTWLXDPFBEPBAQB-UHFFFAOYSA-N
CAS DataBase Reference10450-60-9(CAS DataBase Reference)
EPA Substance Registry SystemPeriodic acid (H5IO6) (10450-60-9)
Safety Information
Hazard Codes C,O
Risk Statements 8-34
Safety Statements 26-27-36/37/39-45-17-36
RIDADR UN 3264 8/PG 2
WGK Germany 3
3-8
TSCA Yes
HS Code 2811 19 80
HazardClass 5.1
PackingGroup II
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
PERIODIC ACID Usage And Synthesis
Chemical PropertiesPERIODIC ACID is colourless crystals
Physical propertiesIn dilute solution, periodic acid exists as H+ and IO4-. When more concentrated, orthoperiodic acid, H5IO6, is formed. Note that this compound is essentially a dihydrate, HIO4·2H2O. This can be obtained as a crystalline solid. O-periodic acid can be dehydrated to metaperiodic acid, m-HIO4. Further heating gives di-iodine pentoxide (I2O5) and O2. The anhydride di-iodine heptoxide, i.e. I2O7, does not exist in nature but can be formed synthetically.
UsesPERIODIC ACID is used as an oxidiser and in the determination of manganese.
UsesIn organic synthesis.
UsesPeriodic acid is used as a component for glycoprotein stains. It serves as a pharmaceutical and synthetic intermediate and is used in silk screen printing. It acts as an oxidizing agent especially the cleavage of 1,2 diols to prepare dialdehydes. It has selective oxidation powers which makes it an ideal reagent for the reclamation of silk screens in the printing industry. It finds application in life sciences for the analysis of intracellular polysaccharides like glycogen, starch and cellulose. Furthermore, it is used in the oxidation reactions converting sulfides into sulfones, catalyzed by chromium(VI) oxide and oxidation reactions converting alcohols to aldehydes and ketones.
DefinitionChEBI: Orthoperiodic acid is an iodine oxoacid. It is a conjugate acid of an orthoperiodate(1-).
ReactionsParaperiodic acid H5IO6, is obtained from sodium paraperiodate, formed by action of chlorine upon a NaOH solution containing I2. On vacuum drying, paraperiodic acid yields metaperiodic acid, HIO4, and dimesoperiodic acid, H4I2O9; which form heteropoly acids with a number of oxides and acids. The periodic acids and their salts are strong oxidizing agents both with inorganic and organic compounds.
General DescriptionPeriodic acid (H5IO6) is an oxoacid of iodine. It is commonly used as an oxidizing agent in organic synthesis for the preparation of useful chemical intermediates. Periodic acid is also used in oxidative cleavage reactions.
Flammability and ExplosibilityNotclassified
Sodium iodate Iodic acid SODIUM BISMUTHATE Sodium periodate Sodium fluoride Lead dioxide SILVER PERIODATE SODIUM PARAPERIODATE PERIODIC ACID Potassium paraperiodate Tetrabutylammonium periodate Ammonium periodate PERIODIC ACID POTASSIUM NICKEL(IV) PARAPERIODATE BARIUM PERIODATE Potassium periodate TRIS[TRINITRATOCERIUM(IV)] PARAPERIODATE LITHIUM PERIODATE

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