Poly(propylene glycol) bis(2-aminopropyl ether)

Poly(propylene glycol) bis(2-aminopropyl ether) Basic information
Product Name:Poly(propylene glycol) bis(2-aminopropyl ether)
Synonyms:POLY(PROPYLENE GLYCOL) BIS(2-AMINOPROPYL ETHER), AVERAGE MN CA. 4,000;POLY(PROPYLENE GLYCOL) BIS(2-AMINOPROPYL ETHER), AVERAGE MN CA. 230;POLY(PROPYLENE GLYCOL) BIS(2-AMINOPROPYL ETHER), AVERAGE MN CA. 2,000;POLY(PROPYLENE GLYCOL) BIS(2-AMINOPROPYL ETHER), AVERAGE MN CA. 400;Polypropylenglycol-bis-(2-aminopropylether);Polyoxy(methyl-1,2-ethanediyl), .alpha.-(2-aminomethylethyl)-.omega.-(2-aminomethylethoxy)-;Poly(oxy(methyl-1,2-ethanediyl)), alpha-(2-aminomethylethyl)-omega-(2-aminomethylethoxy) molare Masse >400 g/mol;Poly(oxy(methyl-1,2-ethanediyl)), alpha-(2-aminomethylethyl)-omega-(2-aminomethylethoxy) molare Masse 230 g/mol
CAS:9046-10-0
MF:CH3CH(NH2)CH2[OCH2CH(CH3)]nNH2
MW:0
EINECS:618-561-0
Product Categories:Hydrophobic Polymers;Materials Science;Ethers;Polymer Science;Polymers;Propylene Glycol;Hydrophobic Polymers;Propylene Glycol
Mol File:Mol File
Poly(propylene glycol) bis(2-aminopropyl ether) Structure
Poly(propylene glycol) bis(2-aminopropyl ether) Chemical Properties
Boiling point 232℃[at 101 325 Pa]
density 0.997 g/mL at 25 °C
vapor pressure 90Pa at 20℃
refractive index n20/D 1.452
RTECS TR3702500
Fp >230 °F
pka9.3[at 20 ℃]
Water Solubility 100g/L at 20℃
LogP1.34 at 25℃
EPA Substance Registry SystemPolypropylene glycol bis(aminopropyl) ether (9046-10-0)
Safety Information
Hazard Codes C,Xi
Risk Statements 34-21/22-41-37/38-52/53-22
Safety Statements 26-39-45-36/37/39-61
RIDADR UN 2922 8/PG 3
WGK Germany 3
10-23
TSCA Yes
HazardClass 8
PackingGroup II
ToxicityLD50 oral in rat: 242mg/kg
MSDS Information
ProviderLanguage
SigmaAldrich English
Poly(propylene glycol) bis(2-aminopropyl ether) Usage And Synthesis
DescriptionAmine-TerminatedPolyether (ATPE) is a class of polyolefin compounds with a soft polyether backbone, capped by primary or secondary amine groups. Because the main chain of the molecule is a soft polyether chain, and the hydrogen on the terminal of polyether amine is more active than the hydrogen on the terminal hydroxyl group of polyether, therefore, polyether amine can be a good substitute for polyether in some material processes, and can improve the application performance of new materials. They are widely used in polyurethane reactive injection molding materials, polyurea spraying, epoxy resin curing agents and gasoline scavengers.
Chemical PropertiesPoly(propylene glycol) bis(2-aminopropyl ether) is a light yellow or colorless transparent liquid at room temperature, with the advantages of low viscosity, low vapor pressure and high primary amine content, and is soluble in solvents such as ethanol, aliphatic hydrocarbons, aromatic hydrocarbons, esters, glycol ethers, ketones and water.
UsesPoly(propylene glycol) bis(2-aminopropyl ether) have good alkali and water resistance and moderate acid resistance. Epoxy resins cured with polyetheramines have good electrical properties. Polyetheramines have unique properties and are used in almost all epoxy applications such as coatings, potting materials, construction materials, composites and adhesives.
Preparationsynthesis of Poly(propylene glycol) bis(2-aminopropyl ether): Firstly, the polyether is attached to the acetoacetate group at both ends by dienone or through the ester exchange reaction of ethyl acetoacetate with polyether polyol, and then the polyether capped by the acetoacetate group is aminated with a mono-primary amine, alkyl alcohol amine or dibasic primary amine to obtain an imine compound with a low viscosity with an aminobutyrate end group.
Flammability and ExplosibilityNotclassified
Poly(propylene glycol) bis(2-aminopropyl ether) Preparation Products And Raw materials
Diethylene glycol Ractopamine PHENYLSELENOL C8E3 Polyethylene-polypropylene glycol DICHLORO(ETHYLENEDIAMINE)PLATINUM(II) Poly(propylene glycol) bis(2-aminopropyl ether) Rafoxanide 1,4-Butanediol YD-1050 polyether polyols for rigid foam Polyethylene Polyether,bicomponent PROPYLENE GLYCOL Ethylene glycol diacetate Ethylene glycol Polypropylene PEEK Dopamine hydrochloride

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