4-Hydroxybutyl acrylate glycidyl ether

4-Hydroxybutyl acrylate glycidyl ether Basic information
Product Name:4-Hydroxybutyl acrylate glycidyl ether
Synonyms:4-Hydroxybutyl acrylate glycidyl ether;4-(2,3-EPOXYPROPOXY)BUTYLACRYLATE;4-(oxiran-2-ylmethoxy)butyl prop-2-enoate;4-(Oxiran-2-ylmethoxy)butyl Acrylate;2-Propenoic acid, 4-(2-oxiranylmethoxy)butyl ester;4-Hydroxybutyl acrylate glycidyl ether ISO 9001:2015 REACH;4-(oxiran-2-ylmethoxy)butyl prop-2-enoate / in stock 119692-59-0 / 98%
CAS:119692-59-0
MF:C10H16O4
MW:200.23
EINECS:
Product Categories:Crosslinking monomer
Mol File:119692-59-0.mol
4-Hydroxybutyl acrylate glycidyl ether Structure
4-Hydroxybutyl acrylate glycidyl ether Chemical Properties
Boiling point 287.5±20.0 °C(Predicted)
density 1.077±0.06 g/cm3(Predicted)
InChIInChI=1S/C10H16O4/c1-2-10(11)13-6-4-3-5-12-7-9-8-14-9/h2,9H,1,3-8H2
InChIKeyUSWANRSZMQLWTG-UHFFFAOYSA-N
SMILESC(OCCCCOCC1CO1)(=O)C=C
EPA Substance Registry System2-Propenoic acid, 4-(oxiranylmethoxy)butyl ester (119692-59-0)
Safety Information
MSDS Information
4-Hydroxybutyl acrylate glycidyl ether Usage And Synthesis
Description4-Hydroxybutyl Acryrate Glycidyl Ether with a glycidylether group at the end of a longer alkyl chain, gives excellent scratch resistance due to its high crosslinking ratio and unique flexibility.This copolymer has good acid rain resistance.It is used in Paint and coating materials,UV/EB curable composition.
Chemical Properties4HBAGE has a glycidylether functional group and a double bond group in the molecule.Various vinyl monomers can be copolymerized with 4HBAGE.The co-polymerized polymer with 4HBAGE achieves a higher crosslinking ratio with curing agents.This is because the glycidylether is further away from the copolymer backbone chain.This copolymer has good acid rain resistance.
ApplicationPaint and coating materials (excellent scratch resistance, mechanical properties, and chemical properties)
Powder coatings
UV/EB curable composition.
Epoxy acrylate
Adhesives
SynthesisThe flask was charged with 144 g of 4-hydroxybutyl acrylate and 0.7 g of boron trifluoride ether complex as a catalyst, heated to 55 ° C., and then 92.5 g of epichlorohydrin was added dropwise over 2 hours with stirring. After completion of the dropwise addition, analysis by gas chromatography revealed that the conversion rate of 4-hydroxybutyl acrylate was about 70%, and most of it was converted to a chloroether form.
4-Hydroxybutyl acrylate glycidyl ether Preparation Products And Raw materials
tert-Butylhydroquinone Acrylic acid 4-Hydroxybutyl acrylate

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