Ammonium hypophosphite

Ammonium hypophosphite Basic information
Product Name:Ammonium hypophosphite
Synonyms:hypophosphorousacid,ammoniumsalt;AMMONIUM HYPOPHOSPHITE;AMMONIUM PHOSPHINATE;Ammonium phosphenite;Ammonium hypophosphi;aMMoniuM phosphonite;AMMONIUM HYPOPHOSPHITE EXTRA PURE;Phosphinic acid, ammonium salt
CAS:7803-65-8
MF:H3N.H3O2P
MW:83.03
EINECS:232-266-0
Product Categories:Chemical Synthesis;Inorganic Salts;Materials Science;Metal and Ceramic Science;Salts;Synthetic Reagents;Ammonium;Ammonium Salts
Mol File:7803-65-8.mol
Ammonium hypophosphite Structure
Ammonium hypophosphite Chemical Properties
Melting point 155-160 °C
density 1.634 [CRC10]
form white hygroscopic crystals
Water Solubility 1000 g/L
Merck 13,530
InChIKeyZRDXIILBYDTYOA-UHFFFAOYSA-N
CAS DataBase Reference7803-65-8(CAS DataBase Reference)
EPA Substance Registry SystemAmmonium hypophosphite (7803-65-8)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 28351000
Hazardous Substances Data7803-65-8(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Ammonium hypophosphite English
ACROS English
SigmaAldrich English
Ammonium hypophosphite Usage And Synthesis
Chemical Propertieswhite crystals
UsesAs catalyst in polyamide manufacture.
General DescriptionWhite crystalline solid. Sinks and mixes with water.
Air & Water ReactionsWater soluble. Ammonium hypophosphite liberates spontaneously flammable phosphine at about 240°C [Mellor 8:880 1946-47].
Reactivity ProfileAmmonium hypophosphite liberates spontaneously flammable phosphine at about 240°C [Mellor 8:880 1946-47]. Some inorganic materials, such as hypophosphites, tend to form explosive mixtures with perchloric acid when hot [Analyst 84:215 1959].
HazardEvolves flammable and toxic fumes on heating.
Health HazardNon-toxic or low toxicity unless heated to decomposition (240°C).
Flammability and ExplosibilityNotclassified
Purification MethodsCrystallise it from hot EtOH.
Ammonium hypophosphite Preparation Products And Raw materials
Preparation Productsammonium hydrogen phosphonate
Tetrabutylammonium phosphate Orthophosphorus acid AMMONIUM MAGNESIUM PHOSPHATE HEXAHYDRATE Ammonium hydroxide Calcium hypophosphite AMMONIUM Ammonium polyphosphate Ammonium formate Phosphinic acidanion Sodium hypophosphite monohydrate Ammonium dihydrogen phosphate TRI-AMMONIUM ORTHOPHOSPHATE Ammonium chloride Diethyl phosphite Ammonium acetate Molybdic acid Dimethyl phosphite Ammonium carbonate

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