Sodium persulfate

Sodium persulfate Basic information
Physical and Chemical Properties Strong oxidants Uses Preparation method storage
Product Name:Sodium persulfate
Synonyms:Formaldehyde Activator Solution, for Purpald Method;SODIUM PEROXYDISULFATE;SODIUM PEROXODISULFATE;SODIUM PERSULFATE;SODIUM PERSULPHATE;Sodium Peroxodisulfate 〔Sodium Persulfate〕;SODIUM PEROXIDISULFATE FOR ANALYSIS EMSURE;FREE SAMPLE NCV SODIUM PERSULFATE
CAS:7775-27-1
MF:Na2O8S2
MW:238.1
EINECS:231-892-1
Product Categories:Inorganics;Inorganic Chemicals
Mol File:7775-27-1.mol
Sodium persulfate Structure
Sodium persulfate Chemical Properties
Melting point 100 °C
density 2,4 g/cm3
vapor pressure 0Pa at 25℃
storage temp. Store at +15°C to +25°C.
solubility H2O: 1 M at 20 °C, clear, colorless
form Solid
Specific Gravity2.4
color White to yellow
OdorOdorless
PH Range2.5 - 4.0
PH3.5-3.8 (100g/l, H2O, 20℃)
Water Solubility 550 g/L (20 ºC)
Merck 14,8656
Exposure limitsACGIH: TWA 0.1 mg/m3
Stability:Stability Unstable. Strong oxidizer. Contact with combustible material may cause fire. Incompatible with combustible material, strong reducing agents, strong bases, alcohols, aluminium, magnesium. Protect from moisture.
InChIKeyCHQMHPLRPQMAMX-UHFFFAOYSA-L
LogP-1 at 20℃
CAS DataBase Reference7775-27-1(CAS DataBase Reference)
EPA Substance Registry SystemSodium persulfate (7775-27-1)
Safety Information
Hazard Codes O,Xn
Risk Statements 8-22-42/43-36/37/38
Safety Statements 22-36/37-45-36/37/39-26-17
RIDADR UN 1505 5.1/PG 3
WGK Germany 1
RTECS SE0525000
TSCA Yes
HS Code 2833 40 00
HazardClass 5.1
PackingGroup III
ToxicityMLD in rabbits (mg/kg): 178 i.v. (DaVal)
MSDS Information
ProviderLanguage
Sodium peroxydisulfate English
ACROS English
SigmaAldrich English
Sodium persulfate Usage And Synthesis
Physical and Chemical PropertiesSodium persulfate, also known as sodium peroxydisulfate is a white crystal or crystalline powder, odorless, tasteless. Formula is Na2S2O8, relative molecular mass is 238.13. Gradual decomposition at room temperature, heating or rapidly decompose in ethanol, decomposition to release oxygen and produce sodium pyrosulfate. Moisture and platinum black, silver, lead, iron, copper, magnesium, nickel, manganese and other metal ions or their alloys can promote the decomposition, it decomposes rapidly and emit hydrogen peroxide at high temperature (about 200 ℃). It is soluble in water (70.4 when 20 ℃).
Sodium persulfate
Sodium persulfate has strong oxidizing. There is a strong irritation to the skin, prolonged contacting with the skin can cause allergies, should pay attention to it when operation. Rat oral LD50 is 895mg/kg. It should be Sealed storage. heat the ammonium persulfate and sodium hydroxide or sodium carbonate solution to remove carbon dioxide and ammonia to obtain sodium persulfate in the Laboratory.

Strong oxidantsWith strong oxidizing, Sodium persulfate can be used as an g agent, which can oxidize Cr3 +, Mn2 + and so on to the corresponding compound of high oxidation state, when there is the presence of Ag +, which can promote the oxidation reaction. Due to its oxidizing properties, it can be used as a bleaching agent, metal surface treatment agent, chemical reagents, pharmaceutical raw materials, accelerator and initiator of battery and emulsion polymerization.
UsesSodium persulfate is used as a bleach, both standalone (particularly in hair cosmetics) and as a detergent component. It is a replacement for ammonium persulfate in etching mixtures for zinc and printed circuit boards, and is used for pickling of copper and some other metals. It is a source of free radicals, making it useful as an initiator for e.g. emulsion polymerization reactions and for accelerated curing of low formaldehyde adhesives. Sodium persulfate is also used as a soil conditioner and in manufacture of dyestuffs, modification of starch, bleach activator, desizing agent for oxidative desizing, etc.
For waste processing in the photographic industry, used as a soft metal surface corrosion agents of the printed circuit board and textile desizing agents, sulfur dyes colorformer.
Preparation method1. The electrolytic oxidation of the aqueous solution of ammonium sulfate is to obtain ammonium persulfate, and then metathesis reaction with sodium hydroxide, after the expulsion of the ammonia by-product, and then concentrated under reduced pressure, crystallization, drying, to obtain sodium sulfate.
(NH4) 2S2O8 + 2NaOH → Na2S2O8 + 2NH3 + 2H2O.
2. Dithionic acid can be prepared by electrolysis of cold sulfuric acid won, which reacts with alkali and then obtain sodium sulfate.
2HSO4--2e → H2S2O8
H2S2O8 + 2NaOH → Na2S2O8 + 2H2O.



storageSodium persulfate is a strong oxidizer and a severe irritant of skin, eyes, and respiratory system. It is almost non-hygroscopic and has particularly good ability to be stored for long time. It is easy and safe to handle. It is not combustible, but releases oxygen easily and assists combustion of other materials.
Conditions/ substances to avoid mixing persulfates with are: moisture, heat, flame, ignition sources, shock, friction, reducing agents, organic material, sodium peroxide, aluminum and powdered metals.
Chemical PropertiesWhite, crystalline powder. Soluble in water; decomposed by alcohol; decomposes in moist air.
UsesBleaching and oxidizing agent; promoter for emulsion polymerization reactions.
UsesSodium peroxydisulfate is used as a radical initiator for emulsion polymerization reactions like acrylonitrile butadiene styrene, detergent component, soil conditioner and soil remediation. It is also used for curing of formaldehyde adhesives. It acts as a bleaching agent and in the production of dyestuffs. It finds application in zinc and printed circuit boards and considered to be a replacement for ammonium persulfate in etching mixtures. Further, it is used in the preparation of diapocynin from apocynin. It plays a role in the conversion of phenols to para-diphenols in alkaline solution and of arylamines to aminophenols. It is actively involved in the Elbs persulfate oxidation and the Boyland-Sims oxidation reactions as an oxidizing agent.
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General DescriptionA white crystalline solid. Very irritating to skin and eyes. May be toxic by skin absorption. Used as a bleaching agent.
Air & Water ReactionsWater soluble. Decomposes slowly in moist air.
Reactivity ProfileSodium persulfate is a strong oxidizing agent. Reacts with many combustible materials and reducing agents, often vigorously enough to start fires or cause explosions [Handling Chemicals Safely 1980 p. 855]. Decomposes gradually under ordinary conditions decomposition is promoted by moisture and heat [Merck]. Decomposed by alcohol and silver ions [Merck].
HazardBy ingestion, strong irritant to tissue.
Health HazardInhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.
Fire HazardThese substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard.
Flammability and ExplosibilityNonflammable
Safety ProfilePoison by intraperitoneal and intravenous routes. A powerful oxidizer; can cause fires. When heated to decomposition it emits toxic fumes of SOx and Na2O. See also SULFATES.
Sodium persulfate Preparation Products And Raw materials
Raw materialsSodium hydroxide-->Ammonium persulfate
Preparation Products2-(Bromomethyl)benzoic acid-->Maleic acid-allyl alcohol copolymer
Sodium bisulfate Potassium persulfate Ammonium persulfate Sodium benzoate Sodium dithionite Sodium persulfate Hydrogen peroxide Sodium sulfate KJELDAHL TABLETS Trans-hydroxy sulfone Sodium bisulfate monohydrate Sulfurous Acid Sodium formate Sodium citrate Sodium bicarbonate Sodium hydroxide Sodium gluconate Sodium carbonate

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