Grela 2nd Generation

Grela 2nd Generation Basic information
Reaction
Product Name:Grela 2nd Generation
Synonyms:RutheniuM, [1,3-bis(2,4,6-triMethylphenyl)-2-iMidazolidinylidene]dichloro[[2-(1-Methylethoxy-κO)-5-nitrophenyl]Methylene-κC]-, (SP-5-41)-;[1,3-bis (2,4,6-trimethylphenyl) -2- imidazolidinylidene] (2-isopropoxy-5-nitrophenyl methylene) ruthenium dichloride;nitro-Grela;(SP-5-41)-[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-kO)-5-nitrophenyl]Methylene-kC]-ruthenium;Grela nitro-Grela;1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[(5-nitro-2-propan-2-yloxyphenyl)methylidene]ruthenium;Grela's catalyst;Grela 2
CAS:502964-52-5
MF:C31H36Cl2N3O3Ru
MW:670.62
EINECS:
Product Categories:
Mol File:502964-52-5.mol
Grela 2nd Generation Structure
Grela 2nd Generation Chemical Properties
Melting point >300 °C
storage temp. 2-8°C
form Powder
color green
CAS DataBase Reference502964-52-5
Safety Information
HS Code 2931.90.6000
MSDS Information
Grela 2nd Generation Usage And Synthesis
Reaction
  1. This catalyst is used for an efficient synthesis of HCV Protease Inhibitor, BILN 2061.
  2. The nitro-Grela catalyst is a stable olefin metathesis initiator active in various ring-closing, cross, and enyne metathesis reactions. Its efficiency has been proven in numerous total syntheses of natural and biologically active compounds, and in material science.
Reactions of 502964-52-5
Usesnitro-Grela is a universal catalyst which provides good results in a wide spectrum of olefin metathesis transformations. The catalyst provides high efficiency in cross metathesis (CM) reactions between type 1 olefins and an electron deficient partner. The catalyst is very good for CM of disubstituted internal olefins.
Grela 2nd Generation Preparation Products And Raw materials
RutheniuM, [1,3-bis(2,4,6-triMethylphenyl)-2-iMidazolidinylidene]dichloro[[2-(1-Methylethoxy-κO)[1,1'-biphenyl]-3-yl]Methylene-κC]-, (SP-5-41)- DOYLE DIRHODIUM CATALYST-RH2(4S-MEOX)4 Grela 1st Generation

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