Pentabromodiphenyl ether

Pentabromodiphenyl ether Basic information
Product Name:Pentabromodiphenyl ether
Synonyms:PENTABROMODIPHENYL ETHER;PENTABROMOPHENYL ETHER;diphenyl ether, pentabromo derivative;Benzene, 1,1-oxybis-, pentabromo deriv.;pentabromodiphenylether (technical mixture);PENTABROMOBIPHENYLETHER;PBDECONGENER99;PENTA-BROMINATEDDIPHENYLETHER
CAS:32534-81-9
MF:C12H5Br5O
MW:564.69
EINECS:251-084-2
Product Categories:Organics
Mol File:32534-81-9.mol
Pentabromodiphenyl ether Structure
Pentabromodiphenyl ether Chemical Properties
density 2.25-2.28 g/cm3
Water Solubility Insoluble (<0.1 g/100 mLat 20.5 ºC)
Stability:Incompatible with strong oxidizing agents.
CAS DataBase Reference32534-81-9
EPA Substance Registry SystemPentabromodiphenyl ether (32534-81-9)
Safety Information
Hazard Codes Xn,N
Risk Statements 48/21/22-50/53-64
Safety Statements 36/37-45-60-61
RIDADR 3152
HazardClass 9
PackingGroup II
Hazardous Substances Data32534-81-9(Hazardous Substances Data)
ToxicityLD50 orl-rat: 5 g/kg NTIS** OTS0522287
MSDS Information
ProviderLanguage
Pentabromodiphenyl ether English
Pentabromodiphenyl ether Usage And Synthesis
DescriptionPentabromodiphenyl ether (PBDE-99) is an amber coloured solid, and insoluble in water. It is a halogenated organic compound and is very unreactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group are incompatible with strong oxidising and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. 2,2′,4,4′,5-Pentabromodiphenyl ether (PBDE-99) was in use as a component of many commonly used flame retardants, including DE-71, Bromkal G1, and other popular mixtures. DE-71 was sold as a flame retardant for unsaturated polyester, rigid and flexible polyurethane foams, epoxies, laminates, adhesives, and coatings. The PBDEs are used in paint, high-impact plastic, foam, and textiles, as well as in electronic, building, automotive, furniture, and household plastic products. The U.S. manufacturers and the EU have banned the use of PBDE since 2004.
Chemical Propertiesamber solid
General DescriptionAmber solid.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileSimple aromatic halogenated organic compounds are very unreactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
Fire HazardFlash point data for Pentabromodiphenyl ether are not available, but Pentabromodiphenyl ether is probably combustible.
Safety ProfileA poison by ingestion. Moderately toxic by inhalation. Low toxicity by skin contact. A moderate skin irritant. When heated to decomposition it emits toxic vapors of Brí
Pentabromodiphenyl ether Preparation Products And Raw materials
Raw materialsGovernment regulation-->Diphenyl ether
2,2',3,4,4',5,5',6'-OCTABROMODIPHENYL ETHER TETRADECABROMO-1,4-DIPHENOXYBENZENE NONABROMODIPHENYLETHER C8E3 2,2',3,4,4',5,6-HEPTABROMODIPHENYL ETHER 2,2',4,6,6'-PENTABROMODIPHENYL ETHER 2,3,3',4,4',5,5',6-OCTABROMODIPHENYL ETHER 2,2?4,5,5?PENTABROMODIPHENYL ETHER 2,3?4,5,5?PENTABROMODIPHENYL ETHER 2?3,4,5,6?PENTABROMODIPHENYL ETHER 6-HYDROXY-2,2',3,3',4-PENTABROMODIPHENYL ETHER 2,3,4,5,6-PENTABROMODIPHENYL ETHER 2,3,3?4,4?PENTABROMODIPHENYL ETHER 2,2?3,3',4,4?6,6'-OCTABROMODIPHENYL ETHER 2-Bromobiphenyl 2,2',3,3',4,4',5,6-OCTABROMODIPHENYL ETHER 4'-FLUORO-2,3,3',4,5,6-HEXABROMODIPHENYL ETHER 2,2',3,3',4,4',5,6,6'-nonabde

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