2-Chlorophenothiazine

2-Chlorophenothiazine Basic information

Product Name:	2-Chlorophenothiazine
Synonyms:	2-CHLOROTHIODIPHENYLAMINE;2-CHLOROPHENOTHIAZINE;TIMTEC-BB SBB003255;2-Chlorophenothiazine, 98%+;3-CHLOROPHENOTHIAZINE;10H-Phenothiazine,2-chloro-;Chlorophenothiazine;CyaMeMazine Chloro IMpurity
CAS:	92-39-7
MF:	C12H8ClNS
MW:	233.72
EINECS:	202-152-5
Product Categories:	Sulphur Derivatives;Intermediates & Fine Chemicals;Metabolites & Impurities;Pharmaceuticals;Sulfur & Selenium Compounds;Metabolites & Impurities, Pharmaceuticals, Intermediates & Fine Chemicals, Sulfur & Selenium Compounds;API Intermediate
Mol File:	92-39-7.mol

2-Chlorophenothiazine Chemical Properties

Melting point	195-200 °C (lit.)
Boiling point	395.7±31.0 °C(Predicted)
density	1.2350 (rough estimate)
refractive index	1.6100 (estimate)
storage temp.	2-8°C
solubility	DMSO (Slightly), Methanol (Slightly, Sonicated)
form	neat
pka	-2.28±0.20(Predicted)
color	Pale Beige to Beige
BRN	176587
LogP	3.28
CAS DataBase Reference	92-39-7(CAS DataBase Reference)
EPA Substance Registry System	10H-Phenothiazine, 2-chloro- (92-39-7)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36-37/39
WGK Germany	3
RTECS	SN7580000
TSCA	Yes
HS Code	2934300000

MSDS Information

Provider	Language
2-Chlorophenothiazine	English
SigmaAldrich	English
ACROS	English
ALFA	English

2-Chlorophenothiazine Usage And Synthesis

Chemical Properties	GREYISH TO SLIGHTLY GREEN OR BROWNISH POWDER
Uses	Metabolite of Chloropromazine
Uses	2-Chlorophenothiazine may be used as starting reagent for the synthesis of N-(10H-phenothiazin-1-yl) benzene sulphonamide.
General Description	2-Chlorophenothiazine is an methylene blue (MB) derivative. Transient resonance Raman and absorption spectra of the lowest excited triplet states T₁ and the cation radicals of 2-chlorophenothiazine have been investigated. Molecular semiconductors based on the 1:1 charge-transfer complexes of 2-chlorophenothiazine with 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) have been investigated by X-ray powder diffraction.

2-Chlorophenothiazine Preparation Products And Raw materials

Raw materials	Hydrogen Sulfide-->3-CHLORODIPHENYLAMINE-->Acetamide, N-(5-chloro-2-mercaptophenyl)--->acetamide, N-(2-mercaptophenyl)--->Ethanethioic acid, S-[2-(acetylamino)-4-chlorophenyl] ester-->3-CHLOROCYCLOHEXAN-1-ONE-->3-chloro-10H-phenothiazine-->Ethanethioic acid,S-[2-(acetylamino)phenyl] ester-->2-AMINO-4-CHLOROTHIOPHENOL-->5-CHLORO-2-IODOANILINE-->2-Bromo-4-chloro-1-iodobenzene
Preparation Products	Chlorpromazine hydrochloride-->PERPHENAZINE

Furomazine Nonachlazine PROCHLORPERAZINE EDISYLATE 0-(3-dimethylaminopropyl)-2-chlorophenothiazine monohydrochloride chlorproethazine PROCHLORPERAZINE MALEATE 3-CHLORO-1-(2-CHLORO-PHENOTHIAZIN-10-YL)-PROPAN-1-ONE Imiclopazine Methophenazine CHLORPROMAZINE-D3 spiclomazine gamma-(4-(beta-Hydroxyethyl)piperazin-1-yl)propyl-2-chlorophenothiazine Chloracyzine Azaclorzine N-(gamma-(4'-Methylpiperazinyl-1')propyl)-3-chlorophenothiazine,n-(gamma-(4’-methylpiperazinyl-1’)propyl)-3-chlorophenothiazin thiopropazate pipamazine PROCHLORPERAZINE 2 HCL (D3)

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