Platinum(IV) oxide

Platinum(IV) oxide Basic information
Product Name:Platinum(IV) oxide
Synonyms:PLATINUM(IV) OXIDE HYDRATE (80% PT) HYDR;PlatinuM(Ⅳ) oxide hydrate, 81% Pt, Product of UMicore;Platinum(IV) oxide xhydrate;Platinum(IV) oxide hydrate crystalline, 99.5%;Platinum(IV) oxide hydrate, 99.9% trace metals basis;Platinum(IV) oxide hydrate (80% Pt) hydrogenation catalyst for synthesis;PLATINUM OXIDE HYDRATE;PLATINUM(IV) OXIDE HYDRATE
CAS:52785-06-5
MF:H2O3Pt
MW:245.1
EINECS:627-714-0
Product Categories:Metal and Ceramic Science;Oxides;Platinum;Alternative Energy;Catalysis and Inorganic Chemistry;Electrode MaterialsChemical Synthesis;Materials Science;chemical reaction,pharm,electronic,materials;bc0001
Mol File:52785-06-5.mol
Platinum(IV) oxide Structure
Platinum(IV) oxide Chemical Properties
Melting point 450 °C(lit.)
density 10.2
RTECS TP2506020
storage temp. Store below +30°C.
form Powder
color Dark brown
OdorOdorless
PH Range10 - 11
Water Solubility INSOLUBLE
Merck 14,7527
CAS DataBase Reference52785-06-5(CAS DataBase Reference)
Safety Information
Hazard Codes O,Xi
Risk Statements 8-36-41-38
Safety Statements 26-36/37/39-28A-22-17
RIDADR UN 1479 5.1/PG 2
WGK Germany 2
TSCA Yes
HazardClass 5.1
PackingGroup II
HS Code 28439000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Platinum(IV) oxide Usage And Synthesis
Chemical Propertiesbrown to black powder
UsesPlatinum (IV) oxide (Pt4+ + 2O2- → Pt O2) is also known as platinum dioxide. It is a darkbrown to black powder known as Adams catalyst that is used as a hydrogenation catalyst.
UsesPlatinum(IV) oxide hydrate is used in the conversion of ketones to methylenes by hydrogenolysis of enol triflates under neutral conditions. It is used as a catalyst for hydrosilylation of olefins with various alkyl dialkoxy silanes.
UsesCatalyst for hydrogenation and hydrogenolysis of various functional groups; used as dehydrogenation catalyst; used for selective oxidation of primary alcohols.
Platinum(IV) oxide Preparation Products And Raw materials
Magnesium oxide Aluminum oxide Platinum Platinum dioxide Boron oxide Dibutyltin oxide ETHYLENE OXIDE (Diethoxymethyl)diphenylphosphine oxide Molybdenum(IV) oxide Iron oxide Hydrogen peroxide CATALYST NITRIC OXIDE Lithium acetoacetate ANTIOXIDANT 765 Lithium oxide NITROUS OXIDE Calcium hydroxide

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