TRIETHYLENE GLYCOL MONOMETHYL ETHER

TRIETHYLENE GLYCOL MONOMETHYL ETHER Basic information
Product Name:TRIETHYLENE GLYCOL MONOMETHYL ETHER
Synonyms:Triglycol monomethyl ether;TRIETHYLENE GLYCOL MONOMETHYL ETHER;2-(2-(2-methoxyethoxy)ethoxy)-ethano;2-[2-(2-methoxyethoxy)ethoxy]-ethano;3,6,9-Trioxa-1-decanol;Dowanol TMAT;dowanoltmat;Methoxytriethylene glycol
CAS:112-35-6
MF:C7H16O4
MW:164.2
EINECS:203-962-1
Product Categories:pharm intermediate;Hydroxy;Materials Science;Monofunctional PEGs;Poly(ethylene glycol) and Poly(ethylene oxide);Polymer Science;Ethylene Glycols & Monofunctional Ethylene Glycols;Monofunctional Ethylene Glycols;Polymers;peg
Mol File:112-35-6.mol
TRIETHYLENE GLYCOL MONOMETHYL ETHER Structure
TRIETHYLENE GLYCOL MONOMETHYL ETHER Chemical Properties
Melting point -45°C(lit.)
Boiling point 122 °C10 mm Hg(lit.)
density 1.026 g/mL at 25 °C(lit.)
vapor density 5.66 (vs air)
vapor pressure <0.01 mm Hg ( 20 °C)
refractive index n20/D 1.439(lit.)
Fp >230 °F
storage temp. Store below +30°C.
Water Solubility Completely miscible in water
pka14.36±0.10(Predicted)
form clear liquid
color Colorless
PH5-7 (H2O, 20℃)
BRN 1700198
InChIKeyJLGLQAWTXXGVEM-UHFFFAOYSA-N
LogP-1.12 at 20℃
CAS DataBase Reference112-35-6(CAS DataBase Reference)
NIST Chemistry ReferenceEthanol, 2-[2-(2-methoxyethoxy)ethoxy]-(112-35-6)
EPA Substance Registry SystemTriethylene glycol monomethyl ether (112-35-6)
Safety Information
Safety Statements 24/25-22
WGK Germany 1
RTECS KL6390000
10-23
Autoignition Temperature210 °C
HS Code 29094990
Hazardous Substances Data112-35-6(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 11850 mg/kg LD50 dermal Rabbit 7448 mg/kg
MSDS Information
ProviderLanguage
SigmaAldrich English
TRIETHYLENE GLYCOL MONOMETHYL ETHER Usage And Synthesis
Descriptionm-PEG3-alcohol is a PEG linker containing a hydroxyl group. The hydroxyl group enables further derivatization or replacement with other reactive functional groups. The hydrophilic PEG spacer increases solubility in aqueous media.
Chemical PropertiesColorless liquid.Soluble in water. Combustible.
UsesPlasticizer intermediate.
UsesTriethylene glycol monomethyl ether can be used as a reagent and solvent for applications such as:
  • modification of anthraquinone material for redox flow batteries
  • preparation of polymeric electrolyte for electrochemical devices,
  • formation of the binary system of polyethylene glycol for absorption of silica.

DefinitionChEBI: A hydroxypolyether that is the monomethyl ether derivative of triethylene glycol. Metabolite observed in cancer metabolism.
General DescriptionColorless odorless liquid.
Air & Water ReactionsEthers tend to form unstable peroxides when exposed to oxygen. Ethyl, isobutyl, ethyl tert-butyl, and ethyl tert-pentyl ether are particularly hazardous in this respect. Ether peroxides can sometimes be observed as clear crystals deposited on containers or along the surface of the liquid.
Reactivity ProfileEthers, such as TRIETHYLENE GLYCOL MONOMETHYL ETHER, can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
Health HazardNo appreciable hazard in ordinary handling or use.
Safety ProfileMildly toxic by ingestion and skincontact. A skin and eye irritant. Many glycol ethercompounds have dangerous human reproductive effects.Combustible when exposed to heat or flame. To fight fire,use alcohol foam, dry chemical. When heated todecomposit
TRIETHYLENE GLYCOL DIMETHYL ETHER ALPHA-D-CELLOBIOSE OCTAACETATE 2,6-DI-O-METHYL-BETA-CYCLODEXTRIN TOMATINE BETA-GENTIOBIOSE OCTAACETATE PENTA(ETHYLENE GLYCOL) DI-P-TOLUENESULFONATE Dibenzo-24-crown-8 TRIMETHYL-BETA-CYCLODEXTRIN Dicyclohexano-24-crown-8 18-Crown-6 1,1-DIMETHYLSILA-17-CROWN-6 BIS[(12-CROWN-4)METHYL] DODECYLMETHYLMALONATE BIS[(BENZO-15-CROWN-5)-15-YLMETHYL] PIMELATE HEPTAETHYLENE GLYCOL Triethylene glycol dimethacrylate 12-Crown-4 Hexaethylene glycol 15-Crown-5

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