N-BUTYL METHYL ETHER

N-BUTYL METHYL ETHER Basic information
Product Name:N-BUTYL METHYL ETHER
Synonyms:Butyl methyl ether 99%;n-Butyl methly ether;BUTHYLMETHYLETHER;1-methoxy-butan;alpha-Methoxybutane;butane,1-methoxy-;Ether, butyl methyl;ether,butylmethyl
CAS:628-28-4
MF:C5H12O
MW:88.15
EINECS:211-033-7
Product Categories:Ethers;Organic Building Blocks;Oxygen Compounds;Building Blocks;C2 to C8;Chemical Synthesis;Organic Building Blocks;Oxygen Compounds
Mol File:628-28-4.mol
N-BUTYL METHYL ETHER Structure
N-BUTYL METHYL ETHER Chemical Properties
Melting point −115 °C(lit.)
Boiling point 70-71 °C(lit.)
density 0.744 g/mL at 25 °C(lit.)
vapor pressure 139 mm Hg ( 25 °C)
refractive index n20/D 1.374(lit.)
Fp 14 °F
form clear liquid
color Colorless to Almost colorless
BRN 1696931
LogP1.660
CAS DataBase Reference628-28-4(CAS DataBase Reference)
EPA Substance Registry SystemButane, 1-methoxy- (628-28-4)
Safety Information
Hazard Codes F
Risk Statements 11-19
Safety Statements 16-23
RIDADR UN 2350 3/PG 2
WGK Germany 3
RTECS KN5240000
10-23
HS Code 2909.30.6000
HazardClass 3.1
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
N-BUTYL METHYL ETHER Usage And Synthesis
General DescriptionA clear liquid. Flash point 95°F. Less dense than water and slightly soluble in water. Vapors heavier than air. May be toxic by inhalation or skin absorption and irritating to skin. Used as a gasoline additive.
Air & Water ReactionsHighly flammable. Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979 p.151-154, 164]. Less dense than water and slightly soluble in water.
Reactivity ProfileN-BUTYL METHYL ETHER can act as a base to form salts or addition compounds with strong acids. May react violently with strong oxidizing agents. Oxidizes readily in air. Relatively unreactive in other reactions, which typically involve the breaking of the carbon-oxygen bond.
Health HazardInhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control may cause pollution.
Fire HazardHIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Safety ProfilePoison by inhalation. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating vapors.
Purification MethodsDry it with CaSO4, pass it through an alumina column to remove peroxides, and fractionally distil it. [Beilstein 1 IV 1518.]
N-BUTYL METHYL ETHER Preparation Products And Raw materials
Preparation ProductsMachette
CHLOROFORMIC ACID N-OCTYL ESTER 2-Ethylhexyl chloroformate Ethyl 2-bromovalerate Ethyl 4,4,4-trifluoroacetoacetate Ethyl 2-bromohexanoate HEXYL CHLOROFORMATE 1-Bromobutane ETHYL HEPTAFLUOROBUTYRATE Ethyl 5-bromovalerate 4-Bromobutyl acetate Ethyl 4-bromobutyrate Heptafluorobutyric anhydride METHYL 4-FLUOROBENZOYLACETATE DL-Ethyl 2-bromobutyrate Ethyl 2-bromoheptanoate 3-(2-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER Methyl 5-bromovalerate Ethyl 6-bromohexanoate Methyl Butyl Ether

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