ChemicalBook Product Catalog Analytical Chemistry Analysis reagents General Analytical Reagents (2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE

(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE

(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE Basic information
Product Name:(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE
Synonyms:(R)-(-)-2-HYDROXY-5,5-DIMETHYL-4-PHENYL-1,3,2-DIOXAPHOSPHORINANE 2-OXIDE;(R)-(-)-5,5-DIMETHYL-2-HYDROXY 4-PHENYL-1,3,2-DIOXAPHOS-PHORINANE-2-OXIDE;(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE;(2R,4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide;(R)-(-)-2-HYDROXY-5,5-DIMETHYL-4-PHENYL- 1,3,2-DIOXAPHOSPHORINANE 2-OXID 98%;(4r)-2-hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide;(R)-(-)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinane 2-oxide, (2R,4R)-5,5-Dimethyl-2-hydroxy-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide;(4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide 98%
CAS:98674-80-7
MF:C11H15O4P
MW:242.21
EINECS:
Product Categories:chiral
Mol File:98674-80-7.mol
(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE Structure
(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE Chemical Properties
Melting point 224-227 °C (lit.)
Boiling point 344.4±45.0 °C(Predicted)
density 1.27±0.1 g/cm3(Predicted)
storage temp. 2-8°C
pka1.28±0.60(Predicted)
optical activity[α]20/D 62°, c = 0.5 in methanol
BRN 4294714
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
F 10-21
MSDS Information
ProviderLanguage
SigmaAldrich English
(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE Usage And Synthesis
Uses(4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide can be used:
  • As a reactant in the phosphoalkoxylation of aromatic enones.
  • As a chiral resolving agent in the resolution of amino acids, amines, and amino alcohols.

(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE Preparation Products And Raw materials
(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE (S)-(-)-2-HYDROXY-4-(2-METHOXYPHENYL)-5,5-DIMETHYL-1,3,2-DIOXAPHOSPHORINANE 2-OXIDE (R)-(-)-PHENCYPHOS HYDRATE 2,2-DIMETHYL-1-PHENYL-1-PROPANOL (S)-(-)-4-(2-CHLOROPHENYL)-2-HYDROXY-5,5-DIMETHYL-1,3,2-DIOXAPHOSPHORINANE 2-OXIDE (S)-1-PHENYL-1,3-PROPANEDIOL NEOPENTYLBENZENE (S)-(-)-2-METHYL-1-PHENYL-1-PROPANOL 2,2-DIMETHYL-1-PHENYL-1,3-PROPANEDIOL, 9 7%
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